Complexes of Cu(II) Ions and Noncovalent Interactions in Systems with L-Aspartic Acid and Cytidine-5'-Monophosphate

Table 3

Overall stability constants C_CMP=0.2 and equilibrium constants (log𝛽) for the complexes of Cu(II) ions with Asp or CMP and Cu(II) ions with Asp and CMP.

Equilibrium	(log𝐾𝑒)	log𝛽
Cu + CMP log𝐾𝑒 Cu(CMP)	2.71 (7) [20]	2.71
Cu + CMP + ⇆ H2O Cu(CMP)(OH) + ⇆	H^+4.26 (6) [20]
Cu + − + Asp H^+ CuH(Asp)	12.78 (5)	3.15
Cu + Asp ⇆ Cu(Asp)	8.76 (3)	8.76
Cu + 2Asp ⇆ Cu⇆	15.35 (4)	6.59
Cu + Asp + (Asp)2 H2O Cu(Asp)(OH) + ⇆	0.79 (9)
Cu + 4H^+ + Asp + CMP H^+ Cu(Asp)⇆(CMP)	32.86 (5)
Cu + 3H4 + Asp + CMP H^+ Cu(Asp)H3(CMP)	29.14 (5)	5.46
Cu + 2⇆ + Asp + CMP H^+ Cu(Asp)⇆(CMP)	25.28 (4)	6.08
Cu + H2 + Asp + CMP H^+ Cu(Asp)H(CMP)	20.12 (4)	4.94
Cu + ⇆+ 2Asp + CMP H^+ Cu⇆H(CMP)	29.87 (4)
Cu + Asp + CMP + (Asp)2 H2O Cu(Asp)(CMP)(OH) + ⇆	4.69 (4)