Research Article

The First Metal Complexes of 4,6-diamino-1-hydro-5-hydroxy-pyrimidine-2-thione: Preparation, Physical and Spectroscopic Studies, and Preliminary Antimicrobial Properties

Figure 1

Schematic structures proposed for the neutral complexes 15, 7, 10 and for the cations of complexes 6, 8, 9. Lattice H 2 O molecules and counterions have been omitted for clarity. However, N O and N N represent the ligands L and phen, respectively. The N and O donor atoms of L are the amino nitrogen of the position 6 (most probably) and the deprotonated oxygen of the position 5 of the pyrimidine ring; M = M o, W; M = R h , Ir.
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