Research Article
Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit
Table 3
Selected interatomic distances (Å) for complex (
2 2MeCN).
| | Bond Distances (Å) |
| | Mn1Mn2 | 3.133() | Mn3–O22 | 2.206(3) | | Mn2Mn6 | 2.8134(9) | Mn3–N1 | 2.263(4) | | Mn2Mn5 | 3.130() | Mn3–O12 | 2.317(3) | | Mn3Mn6 | 3.162() | Mn4–O6 | 2.124(3) | | Mn4Mn6 | 3.167() | Mn4–O20 | 2.131(3) | | Mn1–O1 | 2.121() | Mn4–O9 | 2.154(3) | | Mn1–O7 | 2.121(3) | Mn4–O23 | 2.186(3) | | Mn1–O3 | 2.145(3) | Mn4–N2 | 2.287(4) | | Mn1–O22 | 2.190(3) | Mn4–O8 | 2.302(3) | | Mn1–N3 | 2.250(5) | Mn5–O19 | 2.155(3) | | Mn1–O5 | 2.281(3) | Mn5–O18 | 2.158(3) | | Mn2–O22 | 1.872(3) | Mn5–O23 | 2.176(3) | | Mn2–O23 | 1.894(3) | Mn5–O11 | 2.197(3) | | Mn2–O17 | 1.936(3) | Mn5–O21 | 2.226(3) | | Mn2–O4 | 1.972(4) | Mn5–O14 | 2.237(4) | | Mn2–O5 | 2.239(3) | Mn6–O22 | 1.889(3) | | Mn2–O14 | 2.241(3) | Mn6–O23 | 1.893(3) | | Mn3–O2 | 2.127(4) | Mn6–O10 | 1.951(4) | | Mn3–O13 | 2.146(3) | Mn6–O16 | 1.954(3) | | Mn3–O15 | 2.151(3) | Mn6–O12 | 2.202(3) | | | Mn6–O8 | 2.232(3) |
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