Bioinorganic Chemistry and Applications / 2010 / Article / Tab 1

Research Article

Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole

Table 1

Selected bond lengths ( ) and angles (deg) for compounds 1–3 with e.s.d.’s in parentheses in comparison with those found in [10, 30].

1 at 293(2)  K2 at 120 K[AgCl(TPTP)3]3 at 120 K[AgI(TPTP)3] (polymorph of 3)[AgI(TPTP)3] (polymorph of 3)
at 293 K [10]at 140 K [10]at 293 K [10]
Bond Distances (Å)Bond Distances (Å)Bond Distances (Å)Bond Distances (Å)Bond Distances (Å)Bond Distances (Å)

Ag1–P12.4357(18)Ag1–P12.5159(13)Ag1–P12.5566(12)Ag1–P12.511(2)Ag1–P12.5208(15)Ag1–P12.5294(17)
Ag1–P22.5013(16)Ag1–P22.5438(13)Ag1–P22.5347(11)Ag1–P22.518(2)Ag1–P22.5453(15)Ag1–P22.558(2)
Ag1-S322.6486(16)Ag1-P32.5342(14)Ag1-P32.5609(11)Ag1-P32.504(2)Ag1-P32.5444(13)Ag1-P32.5529(17)
Ag1-Cl42.6736(13)Ag1-Cl12.6109(13)Ag1-Cl12.6186(17)Ag1-I12.8359(8)Ag1-I12.8736(6)Ag1-I12.8655(9)
C32-S321.666(4)
C32-N331.345(5)
N33-H331.0323

Bond Angles (°)Bond Angles (°)Bond Angles (°)Bond Angles (°)Bond Angles (°)Bond Angles (°)

P1-Ag1–P2129.05(5)P1-Ag1-P3115.56(5)P1-Ag1-P3108.40(4)P3-Ag1–P1111.40(7)I1-Ag1–P1101.55(4)I1-Ag1–P1102.37(5)
P1-Ag1-S32109.04(5)P1-Ag1–P2118.85(4)P2-Ag1–P1115.89(4)P3-Ag1–P2114.32(8)I1-Ag1–P2112.12(4)I1-Ag1–P2111.54(5)
P2-Ag1-S32103.91(6)P3-Ag1–P2108.03(4)P2-Ag1-P3118.22(4)P1-Ag1–P2112.77(7)I1-Ag1-P398.57(3)I1-Ag1-P399.44(5)
P1-Ag1-Cl4113.91(5)P1-Ag1-Cl1104.56(5)P1-Ag1-Cl1108.88(5)P3-Ag1-I1103.79(5)P1-Ag1–P2118.13(5)P1-Ag1–P2117.81(6)
P2-Ag1-Cl495.13(5)P3-Ag1-Cl1109.07(5)P3-Ag1-Cl199.54(5)P1-Ag1-I1101.52(6)P1-Ag1-P3111.87(5)P1-Ag1-P3111.94(6)
S32-Ag1-Cl4102.30(5)P2-Ag1-Cl199.04(5)P2-Ag1-Cl1104.17(5)P2-Ag1-I1111.95(6)P2-Ag1-P3112.31(5)P2-Ag1-P3111.77(6)

Article of the Year Award: Outstanding research contributions of 2020, as selected by our Chief Editors. Read the winning articles.