Bioinorganic Chemistry and Applications / 2010 / Article / Tab 2

Research Article

Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole

Table 2

Crystal data and structure refinement details for complexes 1–4.

1; 293 K2; 120 K3; 120 K4; 120 K

Empirical formulaC50H50AgCl2NOP2S2C63H64AgClO0.5P3C63H63AgIP3C84H84Ag4I4P4
Fw985.71065.41147.82156.5
Temperature (K)293(2)120(2)120(2)120(2)
Cryst. SystemTriclinicOrthorhombicMonoclinicTetragonal
Space groupP1Pna21C2/cI41/a
a, Å11.226(4)20.2646(4)22.7429(10)24.0727(2)
b, Å13.659(5)26.0074(5)11.0093(3)24.0727(2)
c, Å18.227(7)10.5020(2)44.8281(18)13.8592(2)
, deg98.97(3)909090
, deg98.08(3)90102.9780(10)90
, deg113.97(4)909090
V, Å 32457.4(16)5534.86(19)10937.5(7)8031.34(15)
Z4484
, g cm-31.3321.2791.3941.783
, mm−10.70.51.12.6
R, wR2 [I > 2σ(I)],0.0458, 0.12790.0598, 0.10730.0723, 0.20640.0299, 0.0773

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