Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole

Table 2

Crystal data and structure refinement details for complexes 1–4.

	1; 293 K	2; 120 K	3; 120 K	4; 120 K
Empirical formula	C50H50AgCl2NOP2S2	C63H64AgClO0.5P3	C63H63AgIP3	C84H84Ag4I4P4
Fw	985.7	1065.4	1147.8	2156.5
Temperature (K)	293(2)	120(2)	120(2)	120(2)
Cryst. System	Triclinic	Orthorhombic	Monoclinic	Tetragonal
Space group	P1	Pna21	C2/c	I41/a
a, Å	11.226(4)	20.2646(4)	22.7429(10)	24.0727(2)
b, Å	13.659(5)	26.0074(5)	11.0093(3)	24.0727(2)
c, Å	18.227(7)	10.5020(2)	44.8281(18)	13.8592(2)
𝛼, deg	98.97(3)	90	90	90
𝛽, deg	98.08(3)	90	102.9780(10)	90
𝛾, deg	113.97(4)	90	90	90
V, Å^3	2457.4(16)	5534.86(19)	10937.5(7)	8031.34(15)
Z	4	4	8	4
𝜌calcd, g cm^-3	1.332	1.279	1.394	1.783
𝜇, mm^−1	0.7	0.5	1.1	2.6
R, wR2 [I > 2σ(I)],	0.0458, 0.1279	0.0598, 0.1073	0.0723, 0.2064	0.0299, 0.0773