Bioinorganic Chemistry and Applications / 2010 / Article / Tab 5

Research Article

Hydrogen-Bonded Networks Based on Cobalt(II), Nickel(II), and Zinc(II) Complexes of N,N'-Diethylurea

Table 5

Selected bond lengths ( ) and angles (°) for 4.

Zn–O( )2.108(3)N(11)–C(13)1.330(6)
Zn–O(11)2.107(3)C(13)–N(12)1.328(6)
Zn–O(21)2.111(3)N(12)–C(14)1.470(9)
O( )–C(3)1.265(5)C(14)–C(15)1.313(12)
O(11)–C(13)1.263(5)C(21)–C(22)1.208(14)
O(21)–C(23)1.279(5)C(22)–N(21)1.469(7)
C( )–C(2)1.485(10)N(21)–C(23)1.315(7)
C(2)–N( )1.457(6)C(23)–N(22)1.328(6)
N( )–C(3)1.331(6)N(22)–C(24)1.437(9)
C(3)–N(2)1.337(6)C(24)–C(25)1.496(10)
N(2)–C(4)1.452(8)Cl–O(34)1.29(2)
C(4)–C(5)1.431(10)Cl–O(32)1.318(12)
C(11)–C(12)1.510(9)Cl–O(31)1.402(13)
C(12)–N(11)1.461(6)Cl–O(33)1.440(16)

O(11)#1–Zn–O(11)180.0(2)C(3)–N(2)–C(4)124.0(5)
O(11)#1–Zn–O( )#192.91(13)C(5)–C(4)–N(2)113.5(7)
O(11)–Zn–O( )#187.09(13)N(11)–C(12)–C(11)109.7(5)
O(11)#1–Zn–O( )87.09(13)C(13)–N(11)–C(12)124.8(4)
O(11)–Zn–O( )92.91(13)O(11)–C(13)–N(12)119.8(4)
O( )#1–Zn–O( )180.00O(11)–C(13)–N(11)121.5(4)
O(11)#1–Zn–O(21)92.83(12)N(12)–C(13)–N(11)118.7(4)
O(11)–Zn–O(21)87.17(12)C(13)–N(12)–C(14)123.6(5)
O( )#1–Zn–O(21)93.04(12)C(15)–C(14)–N(12)116.1(8)
O( )–Zn–O(21)86.96(12)C(21)–C(22)–N(21)121.2(8)
O(11)#1–Zn–O(21)#187.17(12)C(23)–N(21)–C(22)128.4(5)
O(11)–Zn–O(21)#192.83(12)O(21)–C(23)–N(21)121.3(4)
O( )#1–Zn–O(21)#186.96(12)O(21)–C(23)–N(22)119.2(5)
O( )–Zn–O(21)#193.04(12)N(21)–C(23)–N(22)119.4(4)
O(21)–Zn–O(21)#1180.00(18)C(23)–N(22)–C(24)124.9(5)
C(3)–O( )–Zn129.5(3)N(22)–C(24)–C(25)112.6(7)
C(13)–O(11)–Zn129.6(3)O(34)–Cl–O(32)122.9(10)
C(23)–O(21)–Zn128.7(3)O(34)–Cl–O(31)124.7(11)
N( )–C(2)–C( )109.9(5)O(32)–Cl–O(31)109.2(7)
C(3)–N( )–C(2)126.0(4)O(34)–Cl–O(33)85.0(9)
O( )–C(3)–N( )120.6(4)O(32)–Cl–O(33)106.6(8)
O( )–C(3)–N(2)120.5(4)O(31)–Cl–O(33)97.5(8)
N( )–C(3)–N(2)118.9(4)

Symmetry transformation used to generate equivalent atoms: #1 , , .

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