Research Article
Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes
Table 1
Crystal data, structure refinement for [Zn(L–H)2(H2O)2][Zn(L–H)2(H2O)(MeOH)]H2O.
| | Empirical formula | C24.25H23O12.25Zn |
| | Formula weight | 575.80 | | Temperature | 150(2) K | | Wavelength | 0.68840 Å | | Crystal system | Monoclinic | | Space group | C2 | | Unit cell dimensions | a = 15.274(7) Å, = 90° | | b = 8.812(4) Å, = 97.664(4)° | | c = 39.525(18) Å, = 90°. | | Volume | 5272(4) Å3 | | Z | 8 | | Density (calculated) | 1.451 Mg/m3 | | Absorption coefficient | 0.994 mm-1 | | F(000) | 2372 | | Crystal size | 0.16 0.10 0.02 mm3 | | Crystal description | colourless plate | | Theta range for data collection | 2.59 to 25.00°. | | Index ranges | −18 18, −10 10, −48l48 | | Reflections collected | 14618 | | Independent reflections | 8420 [(int) = 0.0388] | | Completeness to theta = 25.00° | 83.4 % | | Absorption correction | Semi-empirical from equivalents | | Max. and min. transmission | 0.9804 and 0.8571 | | Refinement method | Full-matrix least-squares on F2 | | Data/restraints/parameters | 8420/696/704 | | Goodness-of-fit on | 1.132 | | Final indices [I 2 sigma (I)] | = 0.0895, = 0.2373 | | indices (all data) | = 0.0928, = 0.2396 | | Absolute structure parameter | 0.17(2) | | Largest diff. peak and hole | 1.905 and −0.959 e.Å-3 |
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