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Bioinorganic Chemistry and Applications
Volume 2010 (2010), Article ID 848130, 8 pages
http://dx.doi.org/10.1155/2010/848130
Research Article

Coordination Polymer: Synthesis, Spectral Characterization and Thermal Behaviour of Starch-Urea Based Biodegradable Polymer and Its Polymer Metal Complexes

1Materials Research laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025, India
2Department of Chemistry, King Saud University, Riyadh 1145, Saudi Arabia

Received 18 February 2009; Revised 19 July 2009; Accepted 30 March 2010

Academic Editor: Dimitris Kessisoglou

Copyright © 2010 Ashraf Malik et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. J. F. Carvalho, A. E. Job, N. Alves, A. A. S. Curvelo, and A. Gandini, “Thermoplastic starch/natural rubber blends,” Carbohydrate Polymers, vol. 53, no. 1, pp. 95–99, 2003. View at Publisher · View at Google Scholar · View at Scopus
  2. B. Chen and J. R. G. Evans, “Thermoplastic starch-clay nanocomposites and their characteristics,” Carbohydrate Polymers, vol. 61, no. 4, pp. 455–463, 2005. View at Publisher · View at Google Scholar
  3. A. A. Shah, F. Hasan, A. Hameed, and S. Ahmed, “Biological degradation of plastics: a comprehensive review,” Biotechnology Advances, vol. 26, no. 3, pp. 246–265, 2008. View at Publisher · View at Google Scholar
  4. S. Bhattarjee, L. Besra, and B. P. Singh, “Effect of additives on the microstructure of porous alumina,” Journol of European Ceramic Society, vol. 27, no. 1, pp. 47–52, 2007. View at Publisher · View at Google Scholar
  5. S. S. Umare, A. S. Chandure, and R. A. Pandey, “Synthesis, characterization and biodegradable studies of 1,3-propanediol based polyesters,” Polymer Degradation and Stability, vol. 92, no. 3, pp. 464–474, 2007. View at Publisher · View at Google Scholar
  6. M. Movveale, R. Scaffaro, A. Maio, and F. P. La Mantia, “Effect of adding wood flour to the physical properties of a biodegradable polymer,” Applied Science and Manufacturing, vol. 39, no. 3, pp. 503–513, 2008. View at Publisher · View at Google Scholar
  7. N. Tzankova Dintcheva and F. P. La Mantia, “Durability of a starch-based biodegradable polymer,” Polymer Degradation and Stability, vol. 92, no. 4, pp. 630–634, 2007. View at Publisher · View at Google Scholar
  8. J. Delville, C. Joly, P. Dole, and C. Bliard, “Influence of photocrosslinking on the retrogradation of wheat starch based films,” Carbohydrate Polymers, vol. 53, no. 4, pp. 373–381, 2003. View at Publisher · View at Google Scholar · View at Scopus
  9. M. S. El-Kurdi, Y. I. Hong, J. J. Stankus, L. Soletti, W. R. Wagner, and D. A. Vorp, “Transient elastic support for vein grafts using a constricting microfibrillar polymer wrap,” Biomaterials, vol. 29, no. 22, pp. 3213–3220, 2008. View at Publisher · View at Google Scholar
  10. M. S. Kaasgard and F. C. Krebs, “Biodegradable polymer solar cells,” Solar Energy Materials and Solar Cells, vol. 92, no. 7, pp. 805–813, 2008. View at Publisher · View at Google Scholar
  11. T. J. Sill and H. A. Von Recum, “Electrospinning: applications in drug delivery and tissue engineering,” Biomaterials, vol. 29, no. 13, pp. 1989–2006, 2008. View at Publisher · View at Google Scholar
  12. L. Klouda and A. G. Mikos, “Thermoresponsive hydrogels in biomedical applications,” European Journol of Pharmaceutics and Biopharmaceutics, vol. 68, no. 1, pp. 34–45, 2008. View at Publisher · View at Google Scholar
  13. B. Piekarska-Bartozewicz and A. Temeriusz, “A new method for the synthesis of ureido sugars,” Carbohydrate Research, vol. 203, no. 2, pp. 302–330, 1990. View at Publisher · View at Google Scholar
  14. M. Ávalos, R. Babiano, P. Cintas et al., “Synthesis of sugar isocyanates and their application to the formation of ureido-linked disaccharides,” European Journal of Organic Chemistry, vol. 3, pp. 657–671, 2006. View at Google Scholar
  15. R. M. D. Soares, F. F. Scremin, and V. Soldi, “Thermal stability of biodegradable films based on soy protein and corn starch,” Macromolecular Symposia, vol. 229, no. 1, pp. 258–265, 2005. View at Publisher · View at Google Scholar
  16. H. Mart, “Oligo-ortho-chloroazomethinephenol and its metal complexes: synthesis, characterization, antimicrobial and thermal properties,” Journal of Macromolecular Science, Part A, vol. 42, no. 9, pp. 1197–1206, 2005. View at Publisher · View at Google Scholar
  17. C. L. Pan, J. Q. Xu, Y. Sun et al., “First transition metal coordination compound supported on metal—oxygen cluster with bicapped quasi-Keggin structure: [Cu(en)2(H2O)]4[Cu(en)2]3.5[PMoVI8VIV6O42Cu(en)(1, 10'-phen)]3·14H2O,” Inorganic Chemistry Communication, vol. 6, no. 3, pp. 233–237, 2003. View at Publisher · View at Google Scholar
  18. M. Barikani and M. Mohammadi, “Synthesis and characterization of starch-modified polyurethane,” Carbohydrate Polymer, vol. 68, no. 4, pp. 773–780, 2007. View at Publisher · View at Google Scholar
  19. Y. S. Kang, J. H. Son, I. C. Hwang, and K. H. Ahn, “Synthesis of a bis(oxazoline)-N-carboxylate ligand and its Zn(II) complex that shows C-HCI hydrogen bonding,” Polyhedron, vol. 25, no. 15, pp. 3025–3031, 2006. View at Publisher · View at Google Scholar
  20. F. Delval, G. Crini, S. Bertini, C. Filiatre, and G. Torri, “Preparation, characterization and sorption properties of crosslinked starch-based exchangers,” Carbohydrate Polymers, vol. 60, no. 1, pp. 67–75, 2005. View at Publisher · View at Google Scholar
  21. R. Jayasekara, I. Harding, I. Bowater, G. B. Y. Christie, and G. T. Lonegram, “Biodegradation by composting of surface modified starch and PVA blended films,” Journol of Polymer and the Envirronment, vol. 11, no. 2, pp. 49–56, 2003. View at Google Scholar
  22. A. Syamal, D. Kumar, A. K. Singh, P. K. Gupta, and L. K. Jaipal Sharma, Indian Journal of Chemistry A, vol. 41, p. 1385, 2003.
  23. N. Nishat, M. M. Rahisuddin, M. M. Hag, and V. Kumar, “Synthesis, characterization and antimicrobial activity studies of N-N'-tetracarboxydiethyloxamide ligand and its metal(II) complexes,” Journal of Coordination Chemistry, vol. 59, no. 15, pp. 1729–1738, 2006. View at Publisher · View at Google Scholar
  24. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, The Netherlands, 2nd edition, 1984.
  25. D. Kivelson and R. Neiman, “ESR studies on the bonding in copper complexes,” The Journal of Chemical Physics, vol. 35, pp. 149–155, 1985. View at Publisher · View at Google Scholar
  26. G. Pritchard, in Plastics and the Environment, A. L. Andrady, Ed., pp. 432–435, London, UK, 1998.