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Bioinorganic Chemistry and Applications
Volume 2011, Article ID 483101, 6 pages
http://dx.doi.org/10.1155/2011/483101
Research Article

Synthesis, Characterization, Theoretical Crystal Structure, and Antibacterial Activities of Some Transition Metal Complexes of the Thiosemicarbazone (Z)-2-(pyrrolidin-2-ylidene)hydrazinecarbothioamide

1Biotechnology Division, Applied Science Department, University of Technology, Baghdad 10066, Iraq
2Department of Chemical and Processing Engineering, Faculty of Engineering and Built Environment, University of Kebangsaan Malaysia, Bangi, Selangor 43600, Malaysia
3Chemistry Department, College of Science, Al Koofa University, Al Koofa 54003, Iraq

Received 1 April 2011; Accepted 3 June 2011

Academic Editor: Lorenzo Pellerito

Copyright © 2011 Ahmed A. Al-Amiery et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. S. Casas, M. S. García-Tasende, and J. Sordo, “Main group metal complexes of semicarbazones and thiosemicarbazones. A structural review,” Coordination Chemistry Reviews, vol. 209, no. 1, pp. 197–261, 2000. View at Publisher · View at Google Scholar · View at Scopus
  2. D. Mishra, S. Naskar, M. G.B. Drew, and S. K. Chattopadhyay, “Synthesis, spectroscopic and redox properties of some ruthenium(II) thiosemicarbazone complexes: structural description of four of these complexes,” Inorganica Chimica Acta, vol. 359, no. 2, pp. 585–592, 2006. View at Publisher · View at Google Scholar
  3. I. Kizilcikli, B. Ülküseven, Y. Daşdemir, and B. Akkurt, “Zn(II) and Pd(II) complexes of thiosemicarbazone-S-alkyl esters derived from 2/3-formylpyridine,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 34, no. 4, pp. 653–665, 2004. View at Google Scholar · View at Scopus
  4. N. K. Singh, S. B. Singh, and A. Shrivastav, “Spectral, magnetic and biological studies of l,4-dibenzoyl-3-thiosemicarbazide complexes with some first row transition metal ions,” Proceedings of the Indian Academy of Sciences, vol. 113, no. 4, pp. 257–273, 2001. View at Google Scholar · View at Scopus
  5. O. E. Offiong and S. Martelli, “Stereochemistry and antitumour activity of platinum metal complexes of 2-acetylpyridine thiosemicarbazones,” Transition Metal Chemistry, vol. 22, no. 3, pp. 263–269, 1997. View at Google Scholar · View at Scopus
  6. E. Labisbal, K. D. Haslow, A. Sousa-Pedrares, J. Valdés-Martínez, S. Hernández-Ortega, and D. X. West, “Copper(II) and nickel(II) complexes of 5-methyl-2-hydroxyacetophenone N(4)-substituted thiosemicarbazones,” Polyhedron, vol. 22, no. 20, pp. 2831–2837, 2003. View at Google Scholar · View at Scopus
  7. R. V. Singh, N. Fahmi, and M. K. Biyala, “Coordination behavior and biopotency of N and S/O donor ligands with their Palladium(II) and Platinum(II) complexes,” Journal of the Iranian Chemical Society, vol. 2, no. 1, pp. 40–46, 2005. View at Google Scholar
  8. S. Chandra, Sangeetika, and A. Rathi, “Magnetic and spectral studies on copper(II) complexes of N-O and N-S donor ligands,” Journal of Saudi Chemical Society, vol. 5, no. 2, pp. 175–182, 2001. View at Google Scholar
  9. N. Raman, A. Kulandaisamy, A. Shunmugasundaram, and K. Jeyasubramanian, “Synthesis, spectral, redox and antimicrobial activities of Schiff base complexes derived from 1-phenyl-2,3-dimethyl-4-aminopyrazol-5-one and acetoacetanilide,” Transition Metal Chemistry, vol. 26, no. 1-2, pp. 131–135, 2001. View at Publisher · View at Google Scholar · View at Scopus
  10. N. Raman, A. Kulandaisamyand, and K. Jeyasubramanian, “Synthesis, spectral, redox, and antimicrobial activity of Schiff base transition metal(II) complexes derived from 4-aminoantipyrine and benzil,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 32, no. 9, pp. 1583–1610, 2002. View at Publisher · View at Google Scholar
  11. L. Singh, D. K. Sharma, U. Singh, and A. Kumar, “Synthesis and spectral studies of Cu(II) coordination compounds of 4[N-(cinnamalidene) amino] antipyrine semicarbazone,” Asian Journal of Chemistry, vol. 16, no. 2, pp. 577–580, 2004. View at Google Scholar · View at Scopus
  12. N. Raman, C. Thangaraja, and S. Johnsonraja, “Synthesis, spectral characterization, redox and antimicrobial activity of Schiff base transition metal(II) complexes derived from 4-aminoantipyrine and 3-salicylideneacetylacetone,” Central European Journal of Chemistry, vol. 3, no. 3, pp. 537–555, 2005. View at Google Scholar · View at Scopus
  13. A. L. Banty, The Antimicrobial Susceptibility Test; Principles and Practice, Lea and Febiger, Philadelphia, Pa, USA, 1979.
  14. R. K. Agarwal and S. Prasad, “Synthesis and spectral investigations of some platinum metals ions coordination compounds of 4[N-(furan-2′-carboxalidene)amino]antipyrine thiosemicarbazone and 4[N-(3,4,5-trimethoxybenzalidene) amino]antipyrine thiosemicarbazone,” Turkish Journal of Chemistry, vol. 29, no. 3, pp. 289–297, 2005. View at Google Scholar · View at Scopus
  15. S. Chandra and R. Kumar, “Synthesis and spectral studies on mononuclear complexes of chromium(III) and manganese(II) with 12-membered tetradentate N2O2, N2S2 and N4 donor macrocyclic ligands,” Transition Metal Chemistry, vol. 29, no. 3, pp. 269–275, 2004. View at Publisher · View at Google Scholar
  16. S. Chandra and K. B. Pandeya, “Oxovanadium(IV) complexes of cyclohexanone semicarbazone and cyclohexanone thiosemicarbazone,” Transition Metal Chemistry, vol. 6, no. 2, pp. 110–113, 1981. View at Publisher · View at Google Scholar · View at Scopus
  17. V. Reddy, N. Patil, T. Reddy, and S. D. Angadi, “Synthesis, characterization and biological activities of Cu(II), Co(II), Ni(II), Mn(II) and Fe(III) complexes with Schiff base derived from 3-(4-chlorophenoxymethyl)-4-amino-5-mercapto-1,2,4-triazole,” E-Journal of Chemistry, vol. 5, no. 3, pp. 529–538, 2008. View at Google Scholar · View at Scopus
  18. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, New York, NY, USA, 1984.
  19. A. Wissner, D. M. Berger, D. H. Boschelli et al., “4-anilino-6,7-dialkoxyquinoline-3-carbonitrile inhibitors of epidermal growth factor receptor kinase and their bioisosteric relationship to the 4-anilino-6,7-dialkoxyquinazoline inhibitors,” Journal of Medicinal Chemistry, vol. 43, no. 17, pp. 3244–3256, 2000. View at Publisher · View at Google Scholar · View at Scopus