Research Article

Synthesis, Characterization, Theoretical Crystal Structure, and Antibacterial Activities of Some Transition Metal Complexes of the Thiosemicarbazone (Z)-2-(pyrrolidin-2-ylidene)hydrazinecarbothioamide

Table 1

Conductivity, colors, and elemental analysis data of the complexes.

NO.ComplexYield %M.P. °CAnalysis: Found (cal.) %M : LColorΩm ohm−1
cm2 mol−1
MetalCHN

C1Co(C5H10N4S)2Cl275Over 30013.21 (12.7)24.91 (26.4)4.52 (4.22)24.11 (24.87)1 : 2Dark brown30
C2Ni(C5H10N4S)2Cl260Over 30013.16 (12.65)23.93 (25.12)4.52 (4.12)25.12 (24.16)1 : 2Light green65
C3Cu(C5H10N4S)2Cl27726014.09 (13.39)23.64 (25.94)4.47 (4.30)23.85 (24.43)1 : 2Green30