Research Article
Biological and Spectral Studies of Newly Synthesized Triazole Schiff Bases and Their Si(IV), Sn(IV) Complexes
Table 4
C13 NMR chemical shifts of the ligands and their metal complexes.
| Compound | C1 | C2 | C3 | C4 | C5 | C6 | C7 | C8 | C9 | C10 | M–CH3 |
| HL1(BTMMT) | 124.05 | 135.85 | 139.06 | 143.92 | 166.42 | 153.51 | 157.32 | 15.67 | — | — | — | Me2SiCl(L1) | 131.77 | 132.39 | 137.24 | 137.94 | 183.07 | 138.32 | 156.08 | 9.5 | — | — | 18.11 | Me2Si(L1)2 | 116.70 | 132.06 | 133.60 | 141.23 | 160.96 | 147.79 | 149.04 | 11.32 | — | — | 28.22 | Me2SnCl(L1) | 120.65 | 132.03 | 132.98 | 142.52 | 162.54 | 147.89 | 148.26 | 11.65 | — | — | 30.11 | Me2Sn(L1)2 | 116.03 | 131.94 | 132.82 | 141.82 | 161.23 | 147.33 | 147.58 | 11.37 | — | — | 32.11 | HL2(BTMPT) | 120.15 | 131.09 | 134.59 | 138.97 | 162.23 | 152.73 | 152.92 | 13.69 | 19.29 | 26.91 | — | Me2SiCl(L2) | 119.30 | 131.84 | 135.64 | 139.04 | 183.06 | 154.32 | 156.02 | 13.76 | 19.44 | 26.81 | 18.23 | Me2Si(L2)2 | 128.18 | 129.28 | 131.98 | 141.72 | 161.81 | 153.26 | 154.25 | 14.58 | 19.02 | 25.95 | 24.66 | Me2SnCl(L2) | 126.23 | 128.56 | 131.23 | 140.58 | 162.48 | 152.56 | 154.85 | 14.23 | 18.65 | 26.42 | 31.32 | Me2Sn(L2)2 | 124.26 | 130.45 | 132.05 | 141.62 | 161.98 | 153.26 | 154.26 | 14.42 | 18.87 | 26.86 | 32.00 | HL3(BTIMT) | 124.18 | 135.96 | 139.22 | 143.95 | 160.79 | 157.86 | 157.26 | 30.27 | 24.44 | 24.44 | — | Me2SiCl(L3) | 118.67 | 132.03 | 135.82 | 139.08 | 161.95 | 154.71 | 154.98 | 25.56 | 19.79 | 19.79 | 19.12 | Me2Si(L3)2 | 120.42 | 129.45 | 133.25 | 138.55 | 160.78 | 152.53 | 151.25 | 28.45 | 20.25 | 22.76 | 29.10 | Me2SnCl(L3) | 122.62 | 128.46 | 132.46 | 139.42 | 161.86 | 153.24 | 154.25 | 27.56 | 19.45 | 24.57 | 29.88 | Me2Sn(L3)2 | 124.56 | 130.54 | 135.03 | 141.21 | 162.46 | 154.48 | 153.24 | 28.89 | 21.22 | 26.43 | 31.89 |
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