Research Article
Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine
Table 3
Structural parameters, bond length (°A), and angles (°) of the [Cu2(L2)2(H2O)4]complex.
| | | Parameters | | | Bond lengths (°A) | Bond angles (°) |
| Cu(136)–O(138)
Cu(135)–O(137)
O(134)–Cu(135)
O(129)–Cu(135)
O(129)–Cu(136)
N(125)–Cu(136)
O(116)–Cu(136)
O(110)–Cu(136)
O(105)–Cu(136)
O(105)–Cu(135)
N(101)–Cu(135)
O(92)–Cu(135)
Cu(50)–O(52)
Cu(49)–O(51)
O(48)–Cu(49)
C(47)–O(48)
C(46)–H(82)
C(46)–C(47)
C(45)–H(81)
C(45)–C(46)
C(44)–H(80)
C(44)–C(45)
O(43)–Cu(49)
O(43)–Cu(50)
O(30)–Cu(50)
C(29)–C(37)
C(28)–N(39)
C(28)–C(29)
C(27)–O(30)
C(27)–C(28)
N(26)–C(31)
N(26)–C(27)
N(25)–C(38) | 1.5230
1.5230
2.0400
2.3621
1.9129
2.3774
1.8092
1.3403
1.8419
1.7708
1.3875
1.5551
1.5228
1.5227
2.0398
1.4033
1.1000
1.0149
1.1000
1.1328
1.1000
1.0148
2.3617
1.9130
1.8090
1.0468
1.0144
1.1317
1.1265
0.9997
0.9735
1.0636
0.9597 | O(19)–Cu(50)–O(52)–H(85)
O(19)–Cu(50)–O(52)–H(86)
O(24)–Cu(50)–O(52)–H(85)
O(24)–Cu(50)–O(52)–H(86)
O(30)–Cu(50)–O(52)–H(85)
O(30)–Cu(50)–O(52)–H(86)
N(39)–Cu(50)–O(52)–H(85)
N(39)–Cu(50)–O(52)–H(86)
O(43)–Cu(50)–O(52)–H(85)
O(43)–Cu(50)–O(52)–H(86)
O(6)–Cu(49)–O(51)–H(83)
O(6)–Cu(49)–O(51)–H(84)
N(15)–Cu(49)–O(51)–H(83)
N(15)–Cu(49)–O(51)–H(84)
O(19)–Cu(49)–O(51)–H(83)
O(19)–Cu(49)–O(51)–H(84)
O(43)–Cu(49)–O(51)–H(83)
O(43)–Cu(49)–O(51)–H(84)
O(48)–Cu(49)–O(51)–H(83)
O(48)–Cu(49)–O(51)–H(84)
C(47)–O(48)–Cu(49)–O(6)
C(47)–O(48)–Cu(49)–N(15)
C(47)–O(48)–Cu(49)–O(19)
C(47)–O(48)–Cu(49)–O(43)
C(47)–O(48)–Cu(49)–O(51)
Cu(50)–O(43)–Cu(49)–O(48)
Cu(50)–O(43)–Cu(49)–O(51)
C(42)–O(43)–Cu(50)–O(19)
C(42)–O(43)–Cu(50)–O(24)
C(42)–O(43)–Cu(50)–O(30)
C(42)–O(43)–Cu(50)–N(39)
C(42)–O(43)–Cu(50)–O(52)
Cu(49)–O(43)–Cu(50)–O(19)
Cu(49)–O(43)–Cu(50)–O(24)
Cu(49)–O(43)–Cu(50)–O(30) | 179.9998
−0.0001
174.1519
−5.8480
−40.8405
139.1596
9.7808
−170.2191
−3.4183
176.5818
−179.9999
0.0011
−122.7109
57.2900
41.5484
−138.4507
37.5946
−142.4044
37.5946
142.4044
−155.1509
−34.7220
55.8245
52.8179
−127.1821
180.000
180.000
−150.107
−143.209
66.7882
18.0306
32.7885
−2.8955
4.0021
−146.00 |
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