Bioinorganic Chemistry and Applications / 2012 / Article / Tab 1 / Research Article
Synthesis, Characterization and In Vitro Antibacterial Studies of Organotin(IV) Complexes with 2-Hydroxyacetophenone-2-methylphenylthiosemicarbazone (
H
2
d
a
m
p
t
) Table 1 Summary of crystal data and structure refinement parameters for ligand (1).
Compound H2 dampt (1 ) Empirical formula C16 H17 N3 OS Formula weight 299.39 Temperature (K) 100 (2) Wavelength (Å) 0.71073 Crystal system Monoclinic Space group P 21 /cUnit cell dimensions a (Å) 14.6966(8) b (Å) 7.3586(4) c (Å) 14.0926(8) α (°) 90.00 β (°) 94.358(5) γ (°) 90.00 Volume (Å3 ) 1519.66(15) Z 4 Calculated density (mg/m3) 1.309 Radiation type λ (Å) Mo K
a F (000) 632 Crystal size (mm) 0.30 × 0.1 × 0.05 Crystal colour Light-yellow Scan range θ (°) 2.8–29.3 Absorption coefficient (μ ) (mm-1) 0.225 Max. and min. transm 1.00 and 0.419 Goodness of fit on F2 0.995 Data/restrains/ parameters 3375/3/201 Final R indices [I > 2σ (I)]
= 0.0599,
= 0.1324R indices (all data)
= 0.110,
= 0.1738