Bioinorganic Chemistry and Applications

Research Article

Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates

Table 3

Mass spectral data of the Mn(II) ditolyldithiophosphates.
S. no. M. Wt. , relative intensities of the ions and assignment
1.673.6 M+ 673.6 (10) [{(o-CH3C6H4O)2PS2}2Mn]+;
M+ 364.3 (14) [{(o-CH3C6H4O)2PS2}Mn]+;
M+ 277.1 (45) [Mn(S2PO)2]+;
M+ 107.1 (59) [o-CH3C6H4O]−
5.853.8 M+ 853.8 (12) [{(p-CH3C6H4O)2PS2}2Mn · C12H8N2]+;
M+ 544.5 (18) [{(p-CH3C6H4O)2PS2}Mn · C12H8N2]+;
M+ 309.3 (56) [(p-CH3C6H4O)2PS2]−;
M+ 218.2 (67) [(p-CH3C6H4O)P(O)S2]−;
M+ 107.1 (70) [p-CH3C6H4O]−
8.991.6 M+ † 991.6 (15), 993.6 (9), 995.6 (5) [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · C12H8N2]+  
M+ † 788.4 (17), 790.4 (11), 792.4 (9) [{(p-Cl-m-CH3C6H3O)2PS2}Mn · C12H8N2]+;
M+ † 433.1 (21), 433.3 (14), 433.5 (10) [{(p-Cl-m-CH3C6H3O)2PS2}Mn]
M+ 277.2 (48) [(C6H3O)2PS2]−;
M+ 201.2 (56) [m-CH3C6H3OPS2]−;
M+ † 141.5 (60), 143.5 (32), 145.5 (17) [p-Cl-m-CH3C6H3O]−;
9.829.8 M+ 829.8 (7) [{(o-CH3C6H4O)2PS2}2Mn · C10H8N2]+;
M+ 520.4 (98) [{(o-CH3C6H4O)2PS2}Mn · C10H8N2]+;
M+ 364.3 (14) [{(o-CH3C6H4O)2PS2}Mn]+;
M+ 277.1 (7) [Mn(S2PO)2]+;
M+ 107.1 (20) [o-CH3C6H4O]−;
11.829.8 M+ 829.8 (8) [{(p-CH3C6H4O)2PS2}2Mn · C10H8N2]+;
M+ 520.4 (98) [{(p-CH3C6H4O)2PS2}Mn · C10H8N2]+;
M+ 364.3 (14) [{(p-CH3C6H4O)2PS2}Mn]+;
M+ 277.1 (7) [Mn(S2PO)2]+;
M+ 107.1 (20) [p-CH3C6H4O]−;
14.831.8 M+ 831.8 (7) [{(m-CH3C6H4O)2PS2}2Mn · 2C5H5N]+;
M+ 364.3 (98) [{(m-CH3C6H4O)2PS2}Mn]+;
M+ 309.3 (40) [(m-CH3C6H4O)2PS2]−;
M+ 202.5 (40) [m-CH3C6H4OPS2]−;
M+ 277.1 (7) [Mn(S2PO)2]+;
M+ 107.1 (20) [m-CH3C6H4O]−
16.969.6 M+ † 969.6 (12) 971.6 (8), 973.6 (3) [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · 2C5H5N]+;
M+ † 512.2 (18), 514.2 (11), 516.2 (6) [(p-Cl-m-CH3C6H3O)2PS2Mn · C5H5N]+; M+ 277.2 (45) [(C6H3O)2PS2]−;
M+ 201.2 (56) [m-CH3C6H3OPS2]−;
M+ † 141.5 (65), 143.5 (34), 145.5 (19) [p-Cl-m-CH3C6H3O]−;
M+ 106.1 (91) [m-CH3C6H3O]−;
17.1198.2 M+ 1198.2 (6) [{(o-CH3C6H4O)2PS2}2Mn · 2P(C6H5)3]+;
M+ 364.3 (10) [{(o-CH3C6H4O)2PS2}Mn]+;
M+ 202.2 (18) [o-CH3C6H4OPS2]−;
M+ 277.1 (7) [Mn(S2PO)2]+;
M+ 107.1 (20) [o-CH3C6H4O]−;
19.1198.2 M+ 1198.2 (8) [{(p-CH3C6H4O)2PS2}2Mn · 2P(C6H5)3]+;
M+ 364.3 (10) [{(p-CH3C6H4O)2PS2}Mn]+;
M+ 278.7 (98) [(p-C6H4O)2PS2]−;
M+ 202.2 (18) [p-CH3C6H4OPS2]−;
M+ 107.1 (20) [p-CH3C6H4O]−;
isotopic peaks.