Bioinorganic Chemistry and Applications / 2013 / Article / Tab 1 / Research Article
Synthesis, Characterization, Antimicrobial, DNA Cleavage, and Antioxidant Studies of Some Metal Complexes Derived from Schiff Base Containing Indole and Quinoline Moieties Table 1 Physical, analytical, magnetic susceptibility, and molar conductance data of ligand HL and its complexes.
Compounds Molecular formula Mol. Wt. M.P (°C) (Yield in %) Elemental analysis (%) Calcd (Found) Mag. moment µeff (B.M) Molar cond (µM ) ohm−1 cm2 mol−1 Colour M C H N Cl
HL C25 H17 O2 N4 Cl 440 314 (65) — 68.10 (68.25) 3.85 (3.91) 12.71 (12.89) 8.05 (8.12) — — Yellow Cu complex [Cu(C50 H32 O4 N8 Cl2 )]H2 O 959.54 >340 (70) 6.61 (6.71) 62.46 (62.59) 3.53 (3.32) 11.66 (11.74) 7.39 (7.21) 1.79 31 Green Co complex [Co(C50 H32 O4 N8 Cl2 )]H2 O 954.93 >340 (77) 6.16 (6.26) 62.76 (62.92) 3.55 (3.82) 11.71 (11.86) 7.42 (7.62) 5.01 24 Brown Ni complex [Ni(C50 H32 O4 N8 Cl2 )]H2 O 954.69 >340 (79) 6.14 (6.19) 62.78 (62.92) 3.55 (3.69) 11.71 (11.91) 7.42 (7.59) 2.90 27 Brown Zn complex [Zn(C25 H16 O2 N4 Cl) (Cl)]H2 O 557.40 >340 (69) 11.71 (11.62) 53.72 (53.99) 3.22 (3.35) 10.02 (10.19) 12.71 (12.89) — 49 Light yellow Cd complex [Cd(C25 H16 O2 N4 Cl) (Cl)]H2 O 604.41 >340 (71) 18.56 (18.65) 49.55 (49.71) 2.97 (2.81) 9.24 (9.35) 11.72 (11.90) — 60 Pale yellow Hg complex [Hg(C25 H16 O2 N4 Cl) (Cl)] 674.59 330 (68) 29.69 (29.75) 44.40 (44.61) 2.36 (2.42) 8.28 (8.36) 10.50 (10.66) — 50 Light Yellow
HL = ligand.