Research Article

Synthesis, Spectroscopic, Molecular Structure, and Antibacterial Studies of Dibutyltin(IV) Schiff Base Complexes Derived from Phenylalanine, Isoleucine, and Glycine

Table 1

Analytical and physical data of the organotin(IV) complexes.

C. numberReactantsMolar ratio Products & colour M.P. °C (d)Yield (%)Elemental analysis found (calcd.) Mol. Wt.
Found (Calcd.)
MetalLigands%Sn%C%H%N

Bu2Sn(L1)2Bu2SnOC17H14N2O31 : 2C42H44N4O6Sn
Red
1649414.35(14.49)61.30(61.55)5.44(5.41)6.72(6.84)824.55(819.53)

Bu2Sn(L2)2Bu2SnOC14H16N2O31 : 2C36H48N4O6Sn
Red
26279.1415.84(15.80)57.50(57.54)6.38(6.44)7.56(7.46)742.19(751.50)

Bu2Sn(L3)2Bu2SnOC10H8N2O31 : 2C28H32N4O6Sn
Red
17476.8118.43(18.57)52.45(52.61)5.00(5.05)8.65(8.76)630.88(639.29)

Bu2Sn(L4)2Bu2SnOC17H13ClN2O31 : 2C42H42Cl2N4O6Sn
Dark brown
21072.3913.03(13.36)56.84(56.78)4.73(4.76)6.39(6.31)872.54(888.42)

Bu2Sn(L5)2Bu2SnOC14H15ClN2O31 : 2C36H46Cl2N4O6Sn
Light brown
27068.2914.34(14.47)52.59(52.71)5.60(5.65)6.70(6.83)831.57(820.38)

Bu2Sn(L6)2Bu2SnOC10H7ClN2O31 : 2C28H30Cl2N4O6Sn
Dark brown
180–18471.7216.84(16.76)47.41(47.49)4.25(4.27)7.85(7.91)716.67(708.18)