Bioinorganic Chemistry and Applications / 2014 / Article / Tab 1 / Research Article
Synthesis, Spectroscopic, Molecular Structure, and Antibacterial Studies of Dibutyltin(IV) Schiff Base Complexes Derived from Phenylalanine, Isoleucine, and Glycine Table 1 Analytical and physical data of the organotin(IV) complexes.
C. number Reactants Molar ratio
Products & colour
M.P.
°C (d) Yield (%) Elemental analysis found (calcd.)
Mol. Wt. Found (Calcd.) Metal Ligands %Sn %C %H %N Bu2 Sn(L1 )2 Bu2 SnO C17 H14 N2 O3 1 : 2 C42 H44 N4 O6 Sn Red 164 94 14.35(14.49) 61.30(61.55) 5.44(5.41) 6.72(6.84) 824.55(819.53) Bu2 Sn(L2 )2 Bu2 SnO C14 H16 N2 O3 1 : 2 C36 H48 N4 O6 Sn Red 262 79.14 15.84(15.80) 57.50(57.54) 6.38(6.44) 7.56(7.46) 742.19(751.50) Bu2 Sn(L3 )2 Bu2 SnO C10 H8 N2 O3 1 : 2 C28 H32 N4 O6 Sn Red 174 76.81 18.43(18.57) 52.45(52.61) 5.00(5.05) 8.65(8.76) 630.88(639.29) Bu2 Sn(L4 )2 Bu2 SnO C17 H13 ClN2 O3 1 : 2 C42 H42 Cl2 N4 O6 Sn Dark brown 210 72.39 13.03(13.36) 56.84(56.78) 4.73(4.76) 6.39(6.31) 872.54(888.42) Bu2 Sn(L5 )2 Bu2 SnO C14 H15 ClN2 O3 1 : 2 C36 H46 Cl2 N4 O6 Sn Light brown 270 68.29 14.34(14.47) 52.59(52.71) 5.60(5.65) 6.70(6.83) 831.57(820.38) Bu2 Sn(L6 )2 Bu2 SnO C10 H7 ClN2 O3 1 : 2 C28 H30 Cl2 N4 O6 Sn Dark brown 180–184 71.72 16.84(16.76) 47.41(47.49) 4.25(4.27) 7.85(7.91) 716.67(708.18)