Synthesis, Characterization, Cytotoxic Activity, and Interactions with CT-DNA and BSA of Cationic Ruthenium(II) Complexes Containing Dppm and Quinoline Carboxylates

Table 1

Stern-Volmer quenching constant (, L·mol⁻¹), biomolecular quenching rate constant (, L·mol⁻¹·s⁻¹), binding constant (, L·mol⁻¹), the number of binding sites (), and ΔG⁰ (KJ·mol⁻¹), ΔH⁰ (KJ·mol⁻¹), and ΔS⁰ (J·mol⁻¹·K) values for the complex-BSA system at different temperatures.

						ΔG^0	ΔH^0	ΔS^0
		(×10^5)	(×10^13)	(×10^5)
1	300	0.77	1.10	4.77	1.2	−32.61	−87.78	−183.91
	310	0.75	1.10	1.53	1.0	−30.77
2	300	1.24	1.79	3.25	1.1	−31.65	−50.16	−61.70
	310	1.00	1.50	1.70	1.0	−31.04