Hydrolysis of Methionine- and Histidine-Containing Peptides Promoted by Dinuclear Platinum(II) Complexes with Benzodiazines as Bridging Ligands: Influence of Ligand Structure on the Catalytic Ability of Platinum(II) Complexes

<div>Schematic drawing of the <i>N</i>-heterocycles used in this study (a) and the structures of dinuclear platinum(II) complexes <b>1–3</b> calculated at the M06-2X(PCM)/cc-pVTZ+LanL2TZ(f) level of theory. The numbering scheme of carbon atoms in <i>N</i>-heterocycles is in agreement with IUPAC recommendations for the fused ring system and does not match the one applied in the X-ray study of <b>1</b>.</div>

Bioinorganic Chemistry and Applications

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Figure 1

Figure 1: Hydrolysis of Methionine- and Histidine-Containing Peptides Promoted by Dinuclear Platinum(II) Complexes with Benzodiazines as Bridging Ligands: Influence of Ligand Structure on the Catalytic Ability of Platinum(II) Complexes 

Figure 1 | Hydrolysis of Methionine- and Histidine-Containing Peptides Promoted by Dinuclear Platinum(II) Complexes with Benzodiazines as Bridging Ligands: Influence of Ligand Structure on the Catalytic Ability of Platinum(II) Complexes 