Preparation and Thermogravimetric and Antimicrobial Investigation of Cd (II) and Sn (II) Adducts of Mercaptopyridine, Amino Triazole Derivatives, and Mercaptothiazoline Organic Ligand Moieties

Table 5

Major infrared bands (cm⁻¹) for 2mcp and its Cd(II) and Sn(II) adducts.

2mcp	CdCl2-(2mcp)	CdCl2-2(2mcp)	SnCl2-(2mcp)	SnCl2-2(2mcp)	Assignments
—	3458 ms, br	3448 ms, br	3421 ms, br	3423 ms, br	ν(OH); H2O
	3196 ms	3172 ms	3216 ms	3073 vw
	3126 ms		3135 w
	3087 s
2709 mw	—	—	—	—	ν(SH)
2537 mw
1576 vs	1602 vs	1585 vs	1582 vs	1578 vs	Ring breathing bands
1504 s	1517 s	1513 s	1550 sh	1551 sh
1446 ms	1443 s	1443 s	1517 s	1438 vs
1418 s	1378 s	1370 s	1438 vs	1366 w
			1360 s
1275 ms	1262 s	1252 s	1259 vs	1262 s	ν(C=N); aromatic
1246 ms	1160 ms	1163 s	1155 w, sh	1179 vw	δ(C-H); in-plane bend
1188 vs
1145 vs	1134 vs	1132 vs	1131 s	1136 s	ν(C-S); C – SH
1102 vw	1111 vw	1109 vw	1080 ms	1081 ms

s = strong; w = weak; m = medium; sh = shoulder; v = very; br = broad; ν = stretching; δ = bending.