Evidence-Based Complementary and Alternative Medicine / 2015 / Article / Tab 1 / Research Article
Auraptene, a Major Compound of Supercritical Fluid Extract of Phalsak (Citrus Hassaku Hort ex Tanaka), Induces Apoptosis through the Suppression of mTOR Pathways in Human Gastric Cancer SNU-1 Cells Table 1 Identification of compounds present in supercritical fluid extract of phalsak fruit by GC-MS.
Name RT Peel Flesh -myrcene8.031 0.34 — 2-Octenal 9.764 — 0.49 Linalool 10.957 0.69 0.85 p-Menth-1-en-8-ol, (S)-(−)- 13.776 1.39 0.41 2,4-Dimethylbenzaldehyde 14.529 — 0.42 2-Ethylcyclohexanone 15.299 — 0.34 (E)-2-Decenal 15.777 — 0.21 -Citral16.057 0.22 — (E,E)-2,4-Decadienal 16.727 1.43 0.98 Octadecyl vinyl ether 17.885 — 0.13 Citronellyl acetate 18.321 0.28 — 2,4-Dimethyl-5-oxo-heptanal 18.350 — 0.87 Undec-2-enal 18.654 — 0.28 Geranyl acetate 19.164 — 0.22 β -cubebene19.517 0.39 — Decylacetate 19.853 0.27 — Limonen-10-yl acetate 19.999 0.18 — trans-Caryophyllene 20.373 0.10 — Perilla acetate 20.646 0.13 — (E)-Geranylacetone 21.049 0.16 0.16 3,7-Dimethyloct-1-en-3,7-diol 21.146 0.52 — Oleic acid 21.889 — 0.47 2,4-Di-tert-butylphenol 22.610 0.28 0.4 Sesquisabinene hydrate 22.857 0.16 — -Cadinene23.026 0.81 — Dihydroactinidiolide 23.315 0.2 0.12 Lauric acid 23.822 0.38 0.33 Nerolidol 23.885 0.12 — (−)-Caryophyllene oxide 24.645 0.40 0.17 Diisobutylamine 25.236 — 0.18 Spathulenol 25.681 — 0.21 -sinensal27.172 0.13 — Duvatriendiol 27.916 0.20 — Myristic acid 28.487 0.28 — 6-Tridecen-6-al 28.556 0.25 — (−)-Loliolide 28.989 0.26 — N-Butylbenzenesulfonamide 29.256 0.13 0.24 Nootkatone 29.93 5.83 0.15 Platambin 30.964 0.12 — Leden alkohol 31.551 0.25 — Farnesyl acetone A 31.922 0.31 — Methyl palmitate 31.974 — 0.53 Heptadecene-(8)-carbonic acid-(1) 32.349 0.37 — 2-hydroxycyclopentadecan-1-one 32.433 — 1.79 Palmitic acid 32.830 4.56 — Pentadecylic acid 33.024 — 10.77 Ethyl palmitate 33.360 — 0.11 Pentadecanoic acid, 14-bromo- 34.216 — 0.2 cis- Octadec-9-enal 34.360 — 0.29 6-Tridecen-6-al 34.730 0.36
— Manool 34.985 — 0.37 n-Nonadecane 35.381 — 1.48 Methyl oleate 35.575 0.23 — Methyl linoleate 36.248 3.61 — Heptadecene-(8)-carbonic acid-(1) 36.403 3.46 — Oleic acid 36.599 — 20.79 Methyldiethylborane 36.631 1.23 — N-Hentetracontanol-1 37.985 — 0.45 n-Hexatriacontane 39.026 2.43 — 3-Methylheptadecane 40.266 1.53 — n-Hexatriacontane 42.212 1.91 — n-Tetracosane 43.068 — 0.69 Auraptene 44.453 20.77 — 2,2-Dimethyl-3-(3-methyl-5-phenylsulfanyl-pent-3-enyl)-oxirane 45.903 3.98 — Lycopersen 46.323 1.97 0.18 trans-Caryophyllene 48.047 0.22 — 3-Adamantan-1-yl-2-amino-propionic acid 49.247 — 0.23 -tocopheryl- -d-mannoside49.721 0.84 — Vitamin E 49.755 — 0.21 4′,5,6,7,8-Pentamethoxyflavone 50.677 1.29 — -5-Ergosterol51.344 3.51 2.14 Stigmasterol 51.768 1.80 0.67 Obtusifoliol 52.290 0.43 0.3 24- -Ethyl-5- -cholesten-3- -ol 52.678 — 3.51 Clionasterol 52.714 6.34 — Fucosterol 52.910 — 0.24 3,3′,4′,5,5′,7,8-Heptamethoxyflavone 53.036 2.33 — 9,19-Cyclolanost-24-en-3-ol, acetate 55.050 — 0.13 Friedelan-3-one 57.061 0.31 —
Supercritical CO2 extract of fruit compounds tentatively identified based on retention index and elution order as well as the fragmentation pattern described in the literature. Retention time. Relative peak area percentage (peak area relative to the total peak area %).