Evidence-Based Complementary and Alternative Medicine / 2015 / Article / Tab 1 / Research Article
Auraptene, a Major Compound of Supercritical Fluid Extract of Phalsak (Citrus Hassaku Hort ex Tanaka), Induces Apoptosis through the Suppression of mTOR Pathways in Human Gastric Cancer SNU-1 Cells Table 1 Identification of compounds present in supercritical fluid extract of phalsak fruit by GC-MS.
Name RT Peel Flesh 8.031 0.34 — 2-Octenal 9.764 — 0.49 Linalool 10.957 0.69 0.85 p-Menth-1-en-8-ol, (S)-(−)- 13.776 1.39 0.41 2,4-Dimethylbenzaldehyde 14.529 — 0.42 2-Ethylcyclohexanone 15.299 — 0.34 (E)-2-Decenal 15.777 — 0.21 16.057 0.22 — (E,E)-2,4-Decadienal 16.727 1.43 0.98 Octadecyl vinyl ether 17.885 — 0.13 Citronellyl acetate 18.321 0.28 — 2,4-Dimethyl-5-oxo-heptanal 18.350 — 0.87 Undec-2-enal 18.654 — 0.28 Geranyl acetate 19.164 — 0.22 β -cubebene19.517 0.39 — Decylacetate 19.853 0.27 — Limonen-10-yl acetate 19.999 0.18 — trans-Caryophyllene 20.373 0.10 — Perilla acetate 20.646 0.13 — (E)-Geranylacetone 21.049 0.16 0.16 3,7-Dimethyloct-1-en-3,7-diol 21.146 0.52 — Oleic acid 21.889 — 0.47 2,4-Di-tert-butylphenol 22.610 0.28 0.4 Sesquisabinene hydrate 22.857 0.16 — 23.026 0.81 — Dihydroactinidiolide 23.315 0.2 0.12 Lauric acid 23.822 0.38 0.33 Nerolidol 23.885 0.12 — (−)-Caryophyllene oxide 24.645 0.40 0.17 Diisobutylamine 25.236 — 0.18 Spathulenol 25.681 — 0.21 27.172 0.13 — Duvatriendiol 27.916 0.20 — Myristic acid 28.487 0.28 — 6-Tridecen-6-al 28.556 0.25 — (−)-Loliolide 28.989 0.26 — N-Butylbenzenesulfonamide 29.256 0.13 0.24 Nootkatone 29.93 5.83 0.15 Platambin 30.964 0.12 — Leden alkohol 31.551 0.25 — Farnesyl acetone A 31.922 0.31 — Methyl palmitate 31.974 — 0.53 Heptadecene-(8)-carbonic acid-(1) 32.349 0.37 — 2-hydroxycyclopentadecan-1-one 32.433 — 1.79 Palmitic acid 32.830 4.56 — Pentadecylic acid 33.024 — 10.77 Ethyl palmitate 33.360 — 0.11 Pentadecanoic acid, 14-bromo- 34.216 — 0.2 cis- Octadec-9-enal 34.360 — 0.29 6-Tridecen-6-al 34.730 0.36
— Manool 34.985 — 0.37 n-Nonadecane 35.381 — 1.48 Methyl oleate 35.575 0.23 — Methyl linoleate 36.248 3.61 — Heptadecene-(8)-carbonic acid-(1) 36.403 3.46 — Oleic acid 36.599 — 20.79 Methyldiethylborane 36.631 1.23 — N-Hentetracontanol-1 37.985 — 0.45 n-Hexatriacontane 39.026 2.43 — 3-Methylheptadecane 40.266 1.53 — n-Hexatriacontane 42.212 1.91 — n-Tetracosane 43.068 — 0.69 Auraptene 44.453 20.77 — 2,2-Dimethyl-3-(3-methyl-5-phenylsulfanyl-pent-3-enyl)-oxirane 45.903 3.98 — Lycopersen 46.323 1.97 0.18 trans-Caryophyllene 48.047 0.22 — 3-Adamantan-1-yl-2-amino-propionic acid 49.247 — 0.23 49.721 0.84 — Vitamin E 49.755 — 0.21 4′,5,6,7,8-Pentamethoxyflavone 50.677 1.29 — 51.344 3.51 2.14 Stigmasterol 51.768 1.80 0.67 Obtusifoliol 52.290 0.43 0.3 24- 52.678 — 3.51 Clionasterol 52.714 6.34 — Fucosterol 52.910 — 0.24 3,3′,4′,5,5′,7,8-Heptamethoxyflavone 53.036 2.33 — 9,19-Cyclolanost-24-en-3-ol, acetate 55.050 — 0.13 Friedelan-3-one 57.061 0.31 —
2 extract of fruit compounds tentatively identified based on retention index and elution order as well as the fragmentation pattern described in the literature.
