Report on the Medicinal Use of Eleven Lamiaceae Species in Lebanon and Rationalization of Their Antimicrobial Potential by Examination of the Chemical Composition and Antimicrobial Activity of Their Essential Oils
Table 4
Composition of the essential oils of the eleven Lamiaceae species.
Coridothymus capitatus
Lavandula angustifolia
Lavandula stoechas
Mentha spicata subsp. condensata
Origanum syriacum
Rosmarinus officinalis
Salvia fruticosa
Satureja cuneifolia
Satureja thymbra
Thymbra spicata
Vitex agnus-castus
Flowering tops EO
Flowering tops EO
Flowering tops EO
Flowering tops EO
Flowering tops EO
Leaves EO
Leaves EO
Leaves EO
Flowering tops EO
Leaves EO
Flowering tops EO
EOs yields (%)
1.3
2.3
0.9
0.8
1.3
0.6
2.4
2.1
2.5
4.1
0.3
Compound ID
929
1035
α-Thujene
, MS, CoGC
0.5
0.2
t
t
1.0
0.1
t
0.8
1.3
1.5
0.1
938
1076
α-Pinene
, MS, CoGC
0.3
0.7
2.2
0.2
0.5
5.4
2.6
0.3
1.2
0.5
7.1
953
1076
Camphene
, MS, CoGC
0.2
0.5
0.6
0.1
0.1
1.7
0.9
0.1
0.4
0.1
t
973
1132
Sabinene
, MS, CoGC
—
—
0.1
—
—
0.1
—
—
—
—
—
975
1312
1-Octene-3-ol
, MS
0.3
0.3
—
—
0.5
—
0.2
0.1
0.2
0.2
—
980
1118
β-Pinene
, MS, CoGC
0.1
0.4
0.3
—
0.1
1.9
1.5
0.1
0.4
0.1
4.4
993
1174
Myrcene
, MS, CoGC
0.8
0.4
0.2
0.3
0.9
0.9
1.3
0.7
1.1
0.9
1.0
1005
1188
α-Phellandrene
, MS, CoGC
0.2
0.1
t
0.1
0.2
—
0.1
—
0.6
0.1
0.6
1013
1159
δ-3-Carene
, MS
0.1
0.3
—
—
0.1
t
—
t
—
0.1
—
1013
1188
α-Terpinene
, MS, CoGC
1.0
—
0.2
t
1.6
0.4
0.1
1.4
1.0
1.2
0.1
1025
1280
p-Cymene
, MS, CoGC
9.0
—
—
0.1
6.9
—
—
4.1
21.7
12.2
—
1030
1203
Limonene
, MS, CoGC
—
—
—
1.0
—
—
—
—
—
—
—
1034
1213
Eucalyptol
, MS, CoGC
—
8.6
9.5
—
—
21.5
57.3
—
—
—
20.5
1045
1269
cis-β-Ocimene
, MS
t
2.3
—
—
t
—
—
t
—
t
—
1050
1253
trans-β-Ocimene
, MS
t
0.3
t
t
0.1
t
t
0.1
0.1
t
0.9
1057
1255
γ-Terpinene
, MS, CoGC
4.0
0.2
0.1
t
7.6
0.9
0.2
13.3
11.1
11.6
0.2
1058
1556
cis-Sabinene hydrate
, MS
0.5
0.1
—
1.2
0.4
0.2
0.1
0.2
0.2
0.2
0.1
1086
1265
α-Terpinolene
, MS
0.3
0.4
—
0.1
0.1
0.7
0.1
t
0.1
0.1
0.1
1079
1401
α-Fenchone
, MS
—
—
36.2
—
—
—
—
—
—
—
—
1098
1553
Linalool
, MS
0.7
45.8
—
—
0.2
—
—
0.1
0.9
0.1
0.3
1105
1430
α-Thujone
, MS
—
—
—
—
—
—
1.0
—
—
—
—
1115
1449
β-Thujone
, MS, CoGC
—
—
—
—
—
—
0.9
—
—
—
—
1116
1584
α-Fenchol
, MS
—
—
0.7
—
—
—
—
—
—
—
—
1117
—
trans-p-Menth-2-en-1-ol
, MS
0.1
—
—
—
—
0.2
—
—
t
t
—
1138
1475
Menthone
, MS
—
—
—
5.1
—
—
—
—
—
—
—
1145
1532
Camphor
, MS, CoGC
—
11.2
18.0
—
—
15.0
4.8
—
—
—
—
1167
1719
Borneol
, MS, CoGC
0.8
7.5
0.1
—
0.1
7.9
2.1
t
0.3
0.1
—
1176
1611
Terpinen-4-ol
, MS
1.0
5.8
0.2
1.7
0.2
1.0
0.5
0.2
0.2
0.3
0.3
1182
1864
p-Cymen-8-ol
, MS
—
—
0.2
—
—
—
—
—
—
—
—
1189
1706
α-Terpineol
, MS
0.2
—
0.3
0.2
0.1
3.1
4.2
0.2
0.1
0.1
0.7
1193
1648
Myrtenal
, MS
—
—
0.2
—
—
—
—
—
—
—
—
1196
1804
Myrtenol
, MS, CoGC
—
—
0.4
—
—
—
0.1
—
—
—
—
1215
1772
Citronellol
, MS
—
—
—
—
—
—
—
—
—
—
t
1217
1725
Verbenone
, MS
—
—
0.3
—
—
11.8
—
—
—
—
—
1217
1845
trans-Carveol
, MS
—
t
—
—
—
0.1
t
—
—
—
—
1227
1698
Myrtenyl acetate
, MS
—
—
1.0
t
—
0.2
—
—
—
—
—
1233
1662
Pulegone
, MS, CoGC
—
—
—
78.7
—
—
—
—
—
—
—
1235
1857
Geraniol
, MS, CoGC
0.1
—
—
—
—
0.1
—
—
—
—
0.1
1239
1607
Thymol methyl ether
, MS
1.0
—
—
—
—
—
—
—
—
—
—
1245
1975
Carvacrol methyl ether
, MS
0.7
—
—
—
0.1
—
—
1.4
0.1
t
—
1259
1665
Linalyl acetate
, MS
—
4.6
—
—
—
—
—
—
—
—
—
1284
1597
Bornyl acetate
, MS, CoGC
—
0.1
0.5
0.1
—
7.0
0.5
—
—
—
t
1293
2198
Thymol
, MS, CoGC
29.3
—
—
—
74.4
—
0.4
—
44.5
0.4
—
1299
2239
Carvacrol
, MS, CoGC
41.5
—
t
—
—
0.2
0.4
69.5
5.3
64.0
t
1333
1709
α-Terpinyl acetate
, MS
—
—
—
—
—
—
2.2
—
—
—
1.2
1343
1748
Piperitone
, MS
—
t
—
0.1
—
0.1
t
—
—
—
—
1353
2186
Eugenol
, MS, CoGC
0.1
—
—
—
t
0.2
t
t
0.1
t
—
1377
1497
α-Copaene
, MS,
—
—
1.1
—
—
—
—
t
—
—
—
1415
1612
β-Caryophyllene
, MS, CoGC
1.8
0.6
0.2
2.8
1.1
6.3
8.3
—
1.2
0.5
6.6
1437
1628
Aromadendrene
, MS
—
—
—
—
—
—
1.3
0.1
0.1
—
—
1452
1668
α-Humulene
, MS
—
—
0.2
0.1
0.1
2.6
1.5
—
—
—
0.2
1455
1689
β-Farnesene
, MS
0.1
—
—
0.3
—
—
—
—
—
—
16.1
1463
1661
Alloaromadendrene
, MS
0.1
—
0.3
—
—
—
—
—
—
—
—
1464
1685
γ-Gurjunene
, MS
t
—
0.2
—
—
—
0.1
t
—
—
1.2
1477
1726
Germacrene D
, MS
—
0.4
—
0.2
t
—
—
0.4
—
—
—
1487
1679
α-Amorphene
, MS
—
—
—
—
—
—
0.2
—
—
—
0.2
1491
1756
Bicyclogermacrene
, MS
—
—
—
0.4
—
—
—
0.6
—
—
11.8
1508
1741
β-Bisabolene
, MS
0.2
—
—
—
0.2
0.2
—
2.1
—
—
—
1526
1773
δ-Cadinene
, MS
0.1
—
1.8
t
0.1
—
0.3
0.1
t
t
0.3
1553
2076
α-Copaene-8-ol
, MS
—
—
4.7
—
—
—
—
—
—
—
—
1565
2057
Ledol
, MS,
—
—
—
—
—
—
—
—
—
—
1.9
1577
2008
Caryophyllene oxide
, MS, CoGC
0.8
0.3
1.4
0.6
0.3
0.7
0.8
—
2.0
0.8
—
1591
2104
Viridiflorol
, MS,
—
—
3.6
—
—
—
1.1
—
—
—
0.3
1625
2088
1-epi-Cubenol
, MS
—
—
1.8
—
—
—
—
—
—
—
—
1640
2188
τ-Cadinol
, MS
—
0.2
—
—
0.2
—
—
—
—
—
—
1642
2209
τ-Muurolol
, MS
—
—
1.8
—
t
—
—
t
—
—
—
1645
2145
Torreyol
, MS
—
—
1.2
—
—
—
—
—
—
—
—
1649
2256
α-Cadinol
, MS
—
—
—
—
—
—
—
—
—
—
0.3
1677
2256
Cadalene
, MS
—
—
0.6
—
—
—
—
—
—
—
—
1688
2229
α-Bisabolol
, MS, CoGC
—
0.1
—
—
t
—
—
0.1
—
—
0.2
1689
2276
Vulgarol B
, MS
—
—
—
—
—
—
—
—
—
—
4.7
1948
—
Cembrene A
, MS
—
—
—
—
—
—
—
—
—
—
2.8
1950
2603
Phytol
, MS
—
—
—
0.1
—
0.1
—
0.1
—
—
—
1974
2408
Sclarene
, MS
—
—
—
—
—
—
—
—
—
—
5.1
1987
2447
(E)-Geranyl linalool
, MS
—
—
—
—
—
—
—
—
—
—
3.1
Monoterpene hydrocarbons
17.0
5.9
3.7
3.1
19.6
12.3
6.9
21.1
39.2
28.6
14.6
Oxygenated monoterpenes
75.8
83.9
67.6
85.9
75.6
68.4
74.6
71.5
51.7
65.2
23.1
Sesquiterpene hydrocarbons
2.3
1
4.4
3.8
1.5
9.1
11.7
3.3
1.3
0.5
36.4
Oxygenated sesquiterpenes
0.8
0.6
15.1
0.6
0.5
0.7
1.9
0.1
2.0
0.8
7.4
Diterpene hydrocarbons
—
—
—
—
—
—
—
—
—
—
7.9
Oxygenated diterpenes
—
—
—
0.1
—
0.1
—
0.1
—
—
3.1
Total identified
95.9
91.4
90.8
93.5
97.2
90.6
95.1
96.1
94.2
95.1
92.5
Notes: Bold numbers indicate the percentages higher than 2% to show main components; t = trace, less than 0.05%. index on a HP-5MS column. index on an Innowax column; retention index identical to bibliography; MS: identification based on comparison of mass spectra. Co-GC: retention time identical to authentic compounds.