Detarium microcarpum, Guiera senegalensis, and Cassia siamea Induce Apoptosis and Cell Cycle Arrest and Inhibit Metastasis on MCF7 Breast Cancer Cells

Table 2

The probable compounds found in the plant extracts as identified by LC/TOF/MS.

Number	Retention time (min)	Molecular; formula	Experimental m/z	Calculated m/z	Error; (ppm)	Proposed compound	Medicinal plant
1	1.975	C20H20O8	388.1158	387.1080	-6.2	Serpyllin	CSME, DMAE
2	9.363	C27H30O13	562.1686	561.1608	-44.2	6,8-Di-c-rhamnosylapigenin	DMAE
3	10.531	C21H30O10	442.1839	441.1761	-86.6	Lusitanicoside	CSME
4	13.520	C18H36O5	332.2563	331.2484	-84.2	Phloionolic acid	CSME, DMAE, & GSAE
5	17.573	C24H40O2	360.3028	359.2950	-113.0	Tetracosatetraenoic acid n-6	CSME, DMAE, & GSAE
6	24.463	C15H22O4	266.1518	265.1440	0.8	Cumanin	CSME, GSM
7	1.946	C22H28O6	388.1886	387.1808	-104.4	Cyclomammein	DMM
8	2.160	C24H24O5	392.1624	391.1545	-38.6	Calabaxanthone	DMM
9	7.294	C22H18O7	394.1053	393.0974	-47.3	Justicidin A	DMM
10	8.789	C20H20O8	388.1158	387.1080	-98.9	Demethylnobiletin	DMM
11	1.952	C22H18O6	378.1103	377.1025		Jamaicin	GSM
12	3.773	C21H22O4	338.1518	337.1346	-98.8	Gancaonin X	GSM
13	7.398	C22H18O5	362.1154	361.1076	-43.2	Isorhamnetin	GSAE, GSM
14	8.609	C35H28O22	800.1072	799.1029	-0.4	1,3,4,5-Tetra-O-galloylquinic acid	GSAE, GSM
15	8.965	C30H16O8	504.0845	503.0767	6.2	Hypericin	GSM
16	18.351	C37H60O12	696.4085	695.4007	-1.3	Glucosyl passiflorate	GSM
17	2.320	C18H18O7	346.1053	345.0974	-57.1	Amorphaquinone	DMAE
18	3.145	C7H6O5	170.0215	169.0137	-21.9	Gallic acid	DMAE, GSAE
19	5.958	C27H30O14	578.1636	577.1557	-39.3	Violanthin	DMAE
20	7.272	C17H24O9	372.1420	371.1342	-107.8	Syringin	DMAE
21	7.414	C20H16O5	336.0998	335.0919	-52.5	Isoderrone	DMAE
22	8.025	C30H26O12	578.1424	577.1346	-1.0	Procyanidin B3	DMAE
23	8.767	C20H16O5	336.0998	335.0919	-53.7	Alpinumisoflavone	DMAE
24	9.803	C30H26O11	562.1475	561.1397	-8.0	Epifisetinidol-(4beta->8)-catechin	DMAE
25	24.437	C26H44O2	388.3341	387.3263	-104.3	3-Hydroxy-1-phenyl-1-eicosanone	DMAE
26	2.589	C18H16O7	344.0896	343.0818	-42.6	Eupatorin	GSAE
27	4.240	C21H20O14	496.0853	495.0775	-7.5	3,4-Di-O-galloylquinic acid	GSAE
28	4.582	C18H10O6	322.0477	321.0399	-53.9	7,7-Dihydroxy-6,8′-bicoumarin	GSAE
29	5.436	C7H6O4	154.0266	153.0188	-30.7	2,3-Dihydroxybenzoic acid	GSAE
30	7.042	C22H20O10	444.1056	443.0978	-82.6	Rothindin	GSAE
31	10.929	C24H24O11	488.1319	487.1240	-73.3	Trifolirhizin-6′-monoacetate	GSAE
32	24.460	C26H44O2	388.3341	387.3263	-106.4	3-Hydroxy-1-phenylicosan-1-one	GSAE

Detarium microcarpum methanol extract (DMME), Cassia siamea methanol extract (CSME), Guiera senegalensis methanol extract (GSME), Detarium microcarpum aqueous extract (DMAE), and Guiera senegalensis aqueous extract (GSAE)