Anxiolytic Effect of Alcohol-Water Extracted Suanzaoren-Wuweizi Herb-Pair by Regulating ECS-BDNF-ERK Signaling Pathway Expression in Acute Restraint Stress Male Rats

Table 1

UPLC-LTQ Orbitrap MS of SWHP.

No.	Ion mode	tR (min)	Molecular weight (m/z)	Molecular formula	Fragment ions (m/z)	Chemical compound
1	Negative	4.59	191.01906	C6H8O7	172,130,128,110,86	Citric acid/isocitrate
2	Negative	9.85	191.019	C6H8O7	172,130,128,110	Citric acid/isocitrate
3	Negative	10.4	205.03429	C7H10O7	173,143,131,111	6-Methyl citrate
4	Negative	14.35	219.04974	C8H12O7	173,157,143,131,111	1,5-Dimethylcitrate
5	Negative	34.93	342.16934	C20H24NO4	297,282,265,237	Zizyphusine
6	Negative	73.59	543.22198	C29H36O10	525,499,481,445	Lancifodilactone C
7	Positive	73.71	501.34177	C28H36O8	455,437	Tigloylgomisin H or aegeloygomisin H
8	Positive	81.64	531.25757	C29H38O9	495,453,425	Angeloygomisin Q
9	Positive	84.94	389.19424	C22H29O6	374,358,342,319	Gomisin J
10	Positive	87.41	515.22632	C28H34O9	469,385,355	Tigloylgomisin P
11	Negative	87.41	401.1593	C22H26O7	354,284,270,257,255,242	3′,4′-Dimethoxybenzoicacid-(3″,4″-dimethoxyphenyl)-methyl-3-oxobutyl ester
12	Positive	87.94	523.22839	C30H34O8	508,493,477,386,315	Benzoylgomisin H
13	Positive	88.36	391.21078	C22H30O6	359,327,289,237,235,205,166	Pregomisin
14	Positive	90.06	523.22894	C30H34O8	493,386,315	Benzoylgomisin H isomer
15	Positive	91.75	387.17938	C22H26O6	372,358,357,356,355,313	Gomisin L2
16	Positive	94.95	403.31021	C23H30O6	388,372,371,340,333,302,301	Schisanhenol
17	Positive	95.41	403.21021	C23H30O6	388,372,371,356,340,333,301	Gomisin K1
18	Negative	96.74	537.20831	C30H34O9	415,385,371	Gomisin G
19	Positive	97.99	403.21021	C23H30O6	388,372,371,356,340,333,301	Gomisin K2
20	Positive	98.66	515.22552	C28H34O9	469,385,355,343,323	Schisantherin B or schisantherin C
21	Positive	99.73	515.22595	C28H34O9	385,355,316	Gomisin E
22	Positive	100.21	387.17983	C22H26O6	355,325,317	Gomisin M1
23	Positive	101.04	387.17896	C22H26O6	355,325,317	Gomisin M2
24	Negative	102.99	485.32553	C30H45O5	439,423	Ceanothic acid
25	Positive	103.65	417.22552	C24H32O6	402,386,370,347,316	Schisandrin A
26	Positive	105.69	401.19507	C23H28O6	386,371,370,331,300	Schisandrin B
27	Positive	106.25	33.117	C20H26O4	300,299,286	Meso-dihydroguaiaretic acid
28	Positive	106.40	401.19485	C23H28O6	386,371,370,331,300	Schisandrin B
29	Positive	107.65	385.16333	C22H24O6	370,355,315,284	Schisandrin C
30	Negative	113.6	279.2319	C18H32O2	261,259,243,83	9,12-Linoleic acid