The Anti-Inflammatory Effect of Smilax china L. Extract on LPS-Stimulated THP-1 via Downregulation of MAPK and NF-κB Signaling Pathway

Table 3

UPLC-QTOF-MS/MS information of 20 compounds.

No.	t/min	[M-H]-1 (m/z)	Fragment ion (m/z)	Formula	Name
1	4.004	329.0896	269, 191, 167	C14H18O9	2-Methyl-5-hydroxybenzoic acid-3-O-β-D-Glucoside
2	4.378	353.0908	191, 161, 241	C16H18O	Chlorogenic acid
3	4.920	179.0350	171, 135	C9H8O4	Caffeic acid
4	5.827	449.1109	287, 259, 153	C21H22O11	2,7,4-Trihydroxydihydroflavone-5-O-β-D-glucoside
5	6.845	449.1124	287, 269, 153	C21H22O11	7,4-Dihydroxydihydroflavonol-5-O-β-D-glucoside
6	8.041	449.1138	287, 269, 259	C21H22O11	7,4′-Dihydroxydihydroflavonol-7-O-β-D-glucoside
7	11.076	303.0528	285, 177, 153	C15H12O7	Taxifolin
8	11.806	389.1274	242, 227	C20H22O8	Polydatin
9	12.806	243.0671	174, 159, 130	C14H12O4	Piceatannol
10	13.689	243.0672	201, 174, 130	C14H12O4	Oxyresveratrol
11	15.248	449.1119	303, 285, 241	C21H22O11	Astilbin
12	17.284	609.1505	484, 301, 220	C27H30O16	Rutin
13	17.759	227.0718	185, 164, 143	C14H12O3	Resveratrol
14	19.438	433.1172	369, 269, 225	C21H22O10	Engeletin
15	20.354	447.0956	301, 255, 179	C21H21O11	Quercitrin
16	28.393	285.0408	218, 195, 151	C15H10O6	Kaempferide
17	30.886	301.0359	254, 186, 118	C15H10O7	Quercetin
18	30.970	1061.5500	1107, 915, 641	C52H86O22	Methylprotodioscin
19	31.021	1047.5370	1093, 901, 597	C51H84O22	Protodioscin
20	31.928	1029.5290	1075, 541, 883	C51H82O21	Pseudoprotodioscin