Geochemical Signature of Magmatic-Hydrothermal Fluids Exsolved from the Beauvoir Rare-Metal Granite (Massif Central, France): Insights from LA-ICPMS Analysis of Primary Fluid Inclusions
Table 2
Salinity calculated from microthermometric data for the L1- and L2-types fluid inclusions in the H2O-NaCl system [43] and H2O-NaCl-LiCl system [44].
Host-mineral
Size μm
Microthermometry
Salinity in H2O-NaCl system
Salinity in H2O-NaCl-LiCl system
FI-type
Sample
FI n°
ice
Hl
[NaCl] (1)
[NaCl] (2)
[NaCl]
[LiCl]
[Na]
[Li]
Na/Li
°C
°C
°C
°C
wt.% eq
wt.% eq
wt.%
wt.%
wt.%
wt.%
ratio
Beauvoir granite
L1-type
B1-125a
A4
Toz
14
−78
−37.1
275
491
—
36.3
26.5
12.5
10.4
2.0
5.1
L1-type
B1-379a
A6a
Qtz
23
−73
−37.8
~280
530
34.2
—
26.1
12.9
10.3
2.1
4.9
L1-type
B1-379a
A6b
Qtz
17
−73
−34.8
~280
527
31.9
—
27.1
11.4
10.7
1.9
5.7
L1-type
B1-379a
A6c
Qtz
19
−69
−35.8
~280
515
32.6
—
26.6
11.4
10.5
1.9
5.6
L1-type
B1-379a
9a
Qtz
20
−66
−34.0
282
540
—
36.8
28.5
10.5
11.2
1.7
6.5
L1-type
B1-379c
5b
Toz
10
−56
−39.9
~280
600
36.0
—
24.9
13.1
9.8
2.1
4.6
L1-type
B1-379c
6j
Toz
20
−70
−36.1
~280
578
32.9
—
26.9
12.1
10.6
2.0
5.3
L2-type
B1-125a
11
Qtz
25
−72
−38.1
404
525
—
47.9
41.6
10.4
16.4
1.7
9.6
L2-type
B1-379a
7a
Qtz
30
−73
−39.9
406
402
—
48.1
41.9
11.1
16.5
1.8
9.0
L2-type
B1-379c
21
Qtz
20
−60
−29.0
354
529
—
42.8
37.8
7.2
14.9
1.2
12.6
La Bosse stockwork
L1-type
ECH-X2b
44a
Qtz
16
−80
−29.9
~280
422
28.6
—
30.8
8.2
12.1
1.3
9.0
L1-type
ECH-X2b
44b
Qtz
10
—
−30.0
~280
377
28.7
—
31.6
8.4
12.4
1.4
9.0
L2-type
ECH-X2b
42
Qtz
15
−81.0
−41.8
~280
428
37.8
—
25.6
14.4
10.1
2.4
4.3
Salinity in the H2O-NaCl system was calculated using the ice-melting temperature (1) and the halite dissolution temperature (2); value; —: not determined.