Research Article

Identification of Two Types of Metallogenic Fluids in the Ultra-Large Huize Pb–Zn Deposit, SW China

Table 3

Characteristics of the two fluid types in the Huize Pb–Zn deposit, SW China.

Fluid AFluid BMixed fluid

SourceDeepBrine water from atmospheric Precipitation leaching the host rockMixed A and B
Salinity<10 wt% NaCl>20 wt% NaCl2–23 wt% NaCl
pH<3.6>65–8
CO2AbundantAbundantFirst increased, then decreased
70 ppmNoNo
HSNoSulfate strata reductionPrecipitated as sulfides
Pb, Zn complexCl-complexLittle or noneSulfide precipitation
δ13C
δD
δ18O
PropertyAcid oxidationNeutral-alkaline and reducingNear neutral
Corresponding major mineralsBarite and sphalerite in I stageCalcite in IV stageGalena, sphalerite in II and III stages