Research Article
Hydrochemistry and Isotope Hydrology for Groundwater Sustainability of the Coastal Multilayered Aquifer System (Zhanjiang, China)
Table 1
Hydrochemical data of groundwater in the multilayered aquifer system of Zhanjiang.
| Sample number | Aquifer | Sampling time | Ca2+ | Mg2+ | Na+ | K+ | | Cl− | | | SiO2 | TDS | pH | | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (mg/L) | (°C) |
| Q1 | Unconfined aquifer | Mar 2009 | 17.86 | 6.91 | 31.24 | 6.45 | 13.42 | 49.77 | 35.64 | 45 | 12.93 | 216.32 | 5.3 | 23 | Q2 | 15.4 | 70.67 | 17.74 | 45.63 | 5.98 | 183.35 | 58.26 | 100 | 10.49 | 532.23 | 5.06 | 26 | Q3 | 12.91 | 5.71 | 51.38 | 6.59 | 171.16 | 19.21 | 14.26 | 0.5 | 25.65 | 222.45 | 7.55 | 23 | Q4 | 77.37 | 23.75 | 46.58 | 146.6 | 206.86 | 111.77 | 160.47 | 95 | 13.92 | 783.93 | 8.14 | 22 | Q5 | 52.58 | 6 | 27.12 | 13.68 | 145.84 | 32.29 | 29.73 | 40 | 8.92 | 283.76 | 7.03 | 25 | Q6 | 105.15 | 15.64 | 101.81 | 41.68 | 324.44 | 154.56 | 85.59 | 32.5 | 10.91 | 710.27 | 7.27 | 22 | Q7 | 18.36 | 8.42 | 28.26 | 1.4 | | 40.16 | 67.77 | 30 | 11.05 | 207.7 | 4.08 | 23 |
| Q1 | Unconfined aquifer | Mar 2010 | 13.89 | 6.32 | 29.93 | 7.19 | 9.39 | 50.16 | 34.49 | 12.5 | 12.93 | 202.04 | 5 | 23 | Q2 | 41.66 | 21.65 | 105.21 | 14.93 | 5.39 | 193.66 | 116.52 | 55 | 8.75 | 563.74 | 4.87 | 27 | Q3 | 27.78 | 1.8 | 26.17 | 13.06 | 52.54 | 34.24 | 30.93 | 30 | 9.65 | 200.06 | 6.43 | 26 | Q4 | 70.42 | 19.55 | 37.78 | 22.63 | 195.57 | 88.16 | 26.13 | 75 | 8.37 | 453.44 | 8.25 | 22 | Q5 | 25.54 | 4.81 | 46.13 | 14.34 | 118.26 | 28.25 | 36.84 | 40 | 9.34 | 264.51 | 7.15 | 22 | Q6 | 76.39 | 23.75 | 93.39 | 120.75 | 131.38 | 186.75 | 172.38 | 80 | 3.93 | 823.39 | 6.72 | 22 | Q7 | 15.37 | 8.13 | 20.82 | 1.77 | | 29.1 | 74.88 | 2 | 11.17 | 164.34 | 4 | 25 | Q8 | 9.42 | 8.81 | 10.06 | 3.39 | 69.33 | 8.44 | 19.34 | 5 | 9.62 | 149 | 5.52 | 23 |
| Q1 | Unconfined aquifer | Mar 2011 | 13.21 | 7.4 | 32.03 | 8.09 | | 53.39 | 46.88 | 35 | 13.43 | 213.4 | 4.36 | 22 | Q2 | 43.51 | 22.82 | 105.67 | 17.54 | 5.34 | 203.94 | 60.9 | 120 | 15.26 | 593.6 | 4.65 | 25 | Q3 | 28.84 | 4.45 | 21.27 | 13.73 | 54.25 | 27.12 | 44.52 | 32.5 | 9.11 | 208.86 | 6.26 | 23 | Q4 | 33.57 | 8.51 | 6.54 | 23.22 | 142.37 | 10.48 | 30.02 | 2 | 11.81 | 200.16 | 7.15 | 25 | Q5 | 29.82 | 16.2 | 16.2 | 13.53 | 110.09 | 17.74 | 45.59 | 18 | 15.46 | 187.8 | 6.89 | 23 | Q6 | 74.29 | 21.04 | 78.99 | 15.84 | 162.68 | 137.4 | 115.99 | 50 | 3.83 | 579.21 | 7.01 | 21 | Q7 | 16.61 | 7.7 | 19.69 | 1.82 | | 28.89 | 70.27 | 10 | 10 | 166.04 | 4.1 | 26 |
| Z1 | Middle confined aquifer | Mar 2009 | 7.43 | 3.32 | 11.43 | 10.04 | 61.02 | 12.23 | 2.4 | 0.1 | 23.69 | 113.88 | 6.7 | 28 | Z2 | 3.47 | 1.2 | 7.56 | 1.8 | 5.98 | 12.23 | 8.31 | 3 | 14.62 | 64.31 | 5.4 | 27 | Z3 | 7.24 | 3.61 | 3.97 | 7.28 | 46.13 | 2.62 | 13.06 | | 41.83 | 109.88 | 6.49 | 30 | Z4 | 4.47 | 4.51 | 20.02 | 8.01 | 22.33 | 27.93 | 26.13 | | 29.09 | 136.88 | 6.1 | 27 | Z5 | 10.9 | 6.32 | 11.42 | 6.43 | 80.36 | 10.49 | 4.75 | 0.3 | 43.35 | 138.67 | 6.78 | 28 | Z6 | 4.57 | 4.81 | 8.14 | 4.62 | 5.45 | 13.08 | 36.09 | | 27.57 | 132.44 | 5.36 | 27 | Z7 | 6.49 | 4.81 | 7.94 | 4.62 | 58.56 | 6.1 | 7.11 | 1.5 | 35.08 | 110.47 | 6.4 | 28 | Z8 | 2.48 | 3.91 | 5.35 | 3.66 | 7.44 | 7.87 | 23.77 | | 24.42 | 76.46 | 5.55 | 26 | Z9 | 7.94 | 6.01 | 8.87 | 1.45 | 68.46 | 5.25 | 2.4 | 0.1 | 29.31 | 97.49 | 7.34 | 27 | Z10 | 8.44 | 7.22 | 12.62 | 9.36 | 44.67 | 28.82 | 19.02 | | 23.68 | 144.74 | 6.25 | 28 | Z11 | 7.43 | 2.71 | 20.63 | 6.09 | 93.79 | 6.98 | 1.2 | 0.2 | 27.16 | 120.72 | 7.19 | 29.5 |
| Z1 | Middle confined aquifer | Mar 2010 | 9.92 | 3.61 | 13.67 | 9.01 | 56.4 | 26.05 | 5.96 | | 13.28 | 125.48 | 6.69 | 26 | Z2 | 2.48 | 1.51 | 6.96 | 2.53 | 5.86 | 8.58 | 12.82 | 2 | 16.52 | 68.53 | 5.65 | 28 | Z3 | 3.97 | 2.41 | 7.98 | 8.61 | 47.46 | 4.29 | 5.96 | | 43.28 | 110.46 | 6.59 | 29 | Z4 | 3.47 | 3.32 | 18.71 | 6.78 | | 38.04 | 22.57 | 0.1 | 25.3 | 124.5 | 4.15 | 27 | Z5 | 11.91 | 5.42 | 13.39 | 6.73 | 77.37 | 9.5 | 15.47 | | 38.34 | 143.7 | 6.8 | 29 | Z6 | 4.97 | 4.2 | 8.65 | 4.62 | 5.86 | 13.83 | 34.24 | | 28.01 | 119.25 | 5.55 | 27 | Z7 | 9.42 | 5.12 | 7.51 | 4.32 | 61.56 | 6.69 | 13.06 | 0.3 | 39.73 | 124.62 | 6.6 | 25 | Z8 | 2.97 | 2.41 | 6.16 | 4.48 | 7.32 | 9.43 | 19.02 | 0.1 | 24.75 | 74.6 | 5.59 | 27 | Z9 | 8.44 | 5.71 | 9.14 | 1.63 | 67.12 | 4.32 | 7.11 | 0.3 | 40.19 | 110.79 | 6.95 | 26 | Z10 | 9.92 | 7.22 | 14.81 | 10 | 52.24 | 31.69 | 11.91 | 0.1 | 22.23 | 146.77 | 6.52 | 27 | Z11 | 7.43 | 2.41 | 20.39 | 6.75 | 93.42 | 5.99 | 1.2 | 0.2 | 26.88 | 119.44 | 7.05 | 30 | Z12 | 9.13 | 8.11 | 6.23 | 5.9 | 58.22 | 10.2 | 22.1 | | 26.84 | 138 | 6.67 | 29 | Z13 | 8.46 | 6.72 | 6.44 | 4.21 | 53.37 | 8.99 | 18.06 | | 30.89 | 149 | 6.34 | 28 | Z14 | 5.8 | 4.04 | 9.88 | 2.74 | 35.61 | 10.74 | 16.94 | | 29.42 | 150 | 6.44 | 28 |
| Z1 | Middle confined aquifer | Mar 2011 | 8.32 | 4.43 | 10.91 | 10.14 | 61.14 | 18.36 | 7.01 | | 18.02 | 126.48 | 6.7 | 26 | Z2 | 3.43 | 1.48 | 8.91 | 2.93 | | 13.12 | 9.37 | 15 | 17.91 | 73.4 | 4.38 | 24 | Z4 | 4.89 | 3.56 | 21.82 | 8.16 | 16.29 | 35.88 | 22.24 | 0.1 | 37.21 | 145.36 | 5.78 | 27.5 | Z5 | 9.78 | 8.3 | 11.64 | 7.37 | 86.77 | 10.49 | 14.07 | | 46.38 | 155.88 | 6.66 | 29 | Z6 | 4.24 | 5.93 | 8.24 | 5.68 | 7.52 | 14.36 | 38.18 | 0.1 | 39.64 | 151.46 | 5.62 | 25 | Z7 | 22.48 | 3.85 | 6.26 | 4.74 | 92.2 | 7.87 | 12.87 | | 43.85 | 155.07 | 6.8 | 26 | Z8 | 2.44 | 4.74 | 7.63 | 4.54 | 8.12 | 13.12 | 24.59 | | 26.7 | 89.65 | 5.52 | 25 | Z9 | 7.82 | 5.64 | 9.58 | 1.88 | 67.79 | 3.51 | 7.01 | 1 | 48.13 | 119.08 | 6.83 | 27 | Z10 | 22 | 10.07 | 24.12 | 4.27 | 35.27 | 72.64 | 21.09 | 5 | 10.9 | 252.94 | 6.37 | 25 | Z11 | 4.41 | 2.07 | 18.43 | 5.53 | 67.79 | 8.76 | 4.71 | | 54.11 | 136.02 | 6.94 | 30 |
| S1 | Deep confined aquifer | Mar 2009 | 2.97 | 2.11 | 10.82 | 11.99 | 49.12 | 5.25 | 7.11 | 0.3 | 26.9 | 100.69 | 6.51 | 32 | S2 | 3.47 | 3.01 | 9.32 | 12.34 | 55.04 | 1.74 | 13.06 | | 25.91 | 101.03 | 6.4 | 32 | S3 | 4.47 | 4.51 | 19.51 | 10.76 | 92.26 | 3.51 | 7.11 | | 32.95 | 131.77 | 6.99 | 32 | S4 | 10.33 | 4.2 | 4.67 | 8.09 | 65.47 | 4.36 | 2.4 | 0.2 | 46.16 | 117.82 | 6.84 | 32.5 | S5 | 2.97 | 2.41 | 6.96 | 10.17 | 49.28 | 2.62 | 5.26 | 1 | 40.95 | 131.82 | 6.56 | 30 | S6 | 6.45 | 3.61 | 8.66 | 9.81 | 67 | 3.51 | 8.31 | | 45.94 | 127 | 6.74 | 30 | S7 | 36.21 | 3.9 | 25.25 | 14.67 | 69.56 | 37.54 | 51.1 | 3 | 9.89 | 239.1 | 6.3 | 33 | S8 | 9.92 | 4.51 | 14.71 | 7.04 | 90.8 | 4.36 | 1.2 | 4 | 34.39 | 126.22 | 7.15 | 31 | S9 | 22.81 | 9.93 | 44.18 | 45.49 | 247.07 | 28.82 | 11.91 | | 26.26 | 323.46 | 6.14 | 31 | S10 | 22.87 | 5.41 | 12.4 | 10.97 | 132.47 | 6.1 | 1.2 | 0.3 | 31.03 | 159.68 | 7.3 | 31 | S11 | 4.97 | 3.6 | 11.7 | 10.15 | 64.01 | 2.62 | 10.71 | 0.5 | 54.93 | 135.68 | 6.7 | 32.5 | S12 | 4.97 | 3.3 | 7.1 | 10 | 53.58 | 0.89 | 13.06 | | 50.26 | 124.01 | 6.48 | 32 |
| S1 | Deep confined aquifer | Mar 2010 | 2.97 | 2.11 | 10.89 | 13.56 | 54.4 | 5.99 | 8.31 | 0.1 | 27.16 | 110.74 | 6.64 | 31 | S2 | 2.97 | 2.11 | 7.39 | 13.4 | 52.33 | 3.44 | 5.96 | | 26.17 | 99.52 | 6.42 | 32 | S3 | 5.95 | 3.3 | 20.04 | 10.44 | 90.49 | 6.91 | 8.31 | 0.2 | 30.05 | 133.04 | 6.97 | 32 | S4 | 4.91 | 5.66 | 10.61 | 9.76 | 69.93 | 4.36 | 12.97 | 0.8 | 43.44 | 132.83 | 6.74 | 33 | S5 | 2.48 | 2.7 | 7.79 | 10.16 | 55.47 | 0.85 | 3.55 | 1 | 33.57 | 103.84 | 6.7 | 30 | S6 | 3.97 | 4.2 | 9.03 | 9.91 | 62.19 | 3.44 | 9.51 | 0.3 | 53.8 | 132.76 | 6.7 | 31 | S7 | 10.09 | 6.62 | 54.47 | 6.95 | 176.59 | 18.82 | 14.26 | 0.1 | 24.89 | 226.26 | 7.81 | 33 | S8 | 9.42 | 4.52 | 14.7 | 8.19 | 94.89 | 3.44 | 2.4 | 0.1 | 35.71 | 126.46 | 7.14 | 30 | S9 | 16.87 | 13.22 | 46.88 | 47.81 | 249.57 | 27.65 | 16.62 | | 25.24 | 325.98 | 6.12 | 32.5 | S10 | 12.55 | 8.72 | 15.87 | 4.73 | 97.82 | 17.3 | 8.31 | 0.3 | 48.76 | 170.26 | 6.72 | 31 | S11 | 12.37 | 2.71 | 3.97 | 12.32 | 67.12 | 3.47 | 7.11 | 0.2 | 52.93 | 133.09 | 6.87 | 31.5 | S12 | 5.95 | 3.61 | 9.74 | 9.97 | 67.59 | 4.29 | 8.31 | | 51.69 | 134.54 | 6.75 | 31 | S13 | 6.48 | 5.65 | 26.06 | 8.7 | 61.36 | 19.86 | 18.37 | | 32.23 | 214 | 6.68 | 30 | S14 | 7.53 | 5.19 | 23.17 | 14 | 127.83 | 2.54 | 6.88 | | 47.28 | 195 | 7.23 | 31 |
| S1 | Deep confined aquifer | Mar 2011 | 2.93 | 2.08 | 10.4 | 16.8 | 51.5 | 5.25 | 14.07 | | 34.44 | 120.82 | 6.58 | 32 | S2 | 2.44 | 3.56 | 7.37 | 12.25 | 53.25 | 3.51 | 8.37 | 0.3 | 29.68 | 102.04 | 6.42 | 32 | S3 | 9.78 | 3.26 | 19.71 | 10.28 | 98.97 | 7.02 | 8.21 | 0.2 | 46.66 | 161.08 | 7.12 | 32.5 | S4 | 4.89 | 4.74 | 10.65 | 9.48 | 81.34 | 4.36 | 1.15 | | 54.13 | 134.54 | 6.68 | 33 | S5 | 3.43 | 6.22 | 8.23 | 4.79 | 5.09 | 17.51 | 23.26 | 0.1 | 40.4 | 163.5 | 5.34 | 31 | S6 | 4.86 | 3.85 | 9.25 | 12.28 | 63.7 | 2.62 | 9.37 | | 60.03 | 140.22 | 6.73 | 31 | S7 | 53.35 | 7.41 | 12.71 | 7.37 | 147.79 | 28.89 | 12.87 | 11 | 23.12 | 231.54 | 7.66 | 33 | S8 | 14.24 | 5.03 | 9.78 | 10.35 | 98.97 | 3.51 | 5.86 | 4 | 46.76 | 150.36 | 6.99 | 31 | S9 | 14.67 | 13.63 | 46.12 | 4.85 | 221.33 | 21.5 | 7.01 | | 32.22 | 281.44 | 6 | 35 | S10 | 14.17 | 8.3 | 17.75 | 10.08 | 116.72 | 10.49 | 22.24 | 0.2 | 36.83 | 196.66 | 7.03 | 31 | S11 | 3.43 | 3.26 | 12.31 | 11.54 | 65.11 | 3.51 | 7.01 | 0.75 | 60.05 | 142.08 | 6.68 | 32 | S12 | 6.35 | 5.33 | 9.29 | 9.94 | 65.45 | 15.74 | 2.35 | 0.2 | 31.92 | 123.66 | 6.62 | 32 |
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