Research Article
Trace Elements and Minerals in Fumarolic Sulfur: The Case of Ebeko Volcano, Kuriles
Table 2
Concentrations of trace elements in fumarolic sulfur from Ebeko.
| Sample | Location | K | Ca | Mn | Fe | Ti | Ga | Ge | Y | Zr | Sr | Rb | Nb | Th | U | Ni | | ppm | |
| s-1 | July field | 2000 | 1900 | l.d. | 140 | 60 | 7.0 | 4.5 | 1.6 | 1.2 | 2.2 | 1.2 | l.d. | l.d. | l.d. | 16 | | s-1/a | 1400 | 1400 | l.d. | 400 | 50 | 6.5 | 3.04 | 1.8 | 2.1 | 7.6 | 1.2 | 0.37 | l.d. | l.d. | 15 | | s-2 | 2000 | 1500 | l.d. | 70 | l.d. | 5.6 | 5.34 | 0.99 | 1.5 | 1.5 | 0.75 | 0.31 | l.d. | l.d. | 14 | | s-3 | 1800 | 1300 | l.d. | 80 | l.d. | 6.7 | 4.6 | 1.05 | 0.42 | 1.8 | 0.63 | 0.2 | l.d. | l.d. | 13 | | s-4 | 2100 | 1900 | l.d. | 100 | 40 | 6.9 | 5.8 | 1.02 | l.d. | 2.1 | 0.64 | 0.43 | l.d. | l.d. | 18 | | s-5 | 900 | 1400 | l.d. | 100 | 70 | 6.4 | 5.1 | 0.9 | 0.44 | 1.7 | 1.4 | 0.37 | l.d. | l.d. | 17 | | s-6 | 2300 | 1800 | l.d. | 60 | 60 | 7.3 | 4.02 | 1.07 | 0.59 | 1.7 | 0.93 | l.d. | l.d. | l.d. | 19 | | s-7 | 1500 | 1500 | l.d. | 70 | 60 | 6.5 | 4.3 | 1.1 | 0.35 | 1.8 | 0.55 | 0.22 | l.d. | l.d. | 15 | | s-8 | 2600 | 1900 | l.d. | 240 | 70 | 6.6 | 5.1 | 1.2 | 1.4 | 3.06 | 1.09 | 0.4 | l.d. | l.d. | 13 | | s-9 | 2000 | 2000 | l.d. | 90 | l.d. | 5.8 | 5.0 | 1.1 | 0.64 | 1.8 | 0.75 | 0.22 | l.d. | l.d. | 15 | | s-10 | 2200 | 1400 | l.d. | 100 | 40 | 5.9 | 4.3 | 1.05 | 0.85 | 1.6 | 0.63 | 0.31 | l.d. | l.d. | 13 | | E-3 | NE field | 2900 | 800 | 50 | 2100 | 2700 | 2.9 | 0.85 | 3.4 | 78 | 130 | 7.4 | 2.2 | 2.1 | 1.8 | 2.3 | | E-6 | 2300 | 780 | 80 | 3200 | 2600 | 3.8 | 1.0 | 2.2 | 100 | 19 | 3.4 | 2.5 | 1.6 | 0.97 | 4.3 | | E-5 | 1800 | 350 | 10 | 440 | 580 | 2.1 | 0.054 | 0.58 | 15 | 3.0 | 1.6 | 0.60 | 1.5 | 0.89 | 1.7 | | E-7 | 1800 | 360 | 50 | 5500 | 1600 | 2.7 | 0.44 | 0.76 | 47 | 7.3 | 2.2 | 2.8 | 1.3 | 0.89 | 4.4 | | E-9/1 | 2000 | 410 | l.d. | 110 | l.d. | 3.0 | 0.92 | 0.19 | 0.65 | 1.5 | 1.3 | 0.15 | 1.3 | 1.2 | 4.3 | | E-9/2 | 1800 | 730 | 30 | 900 | l.d. | 2.7 | l.d. | 1.1 | 3.8 | 5.7 | 2.7 | 0.24 | 1.3 | 1.3 | 5.5 | | E-8/2 | South field | 2100 | 690 | 40 | 7600 | 1800 | 2.7 | 0.31 | 1.7 | 50 | 18 | 5.0 | 3.1 | 1.2 | 1.2 | 6.9 | | E-8/3 | 1700 | 780 | 60 | 34000 | 10000 | 1.3 | 1.8 | 6.1 | 240 | 8.7 | 4.7 | 7.8 | 4.6 | 0.76 | 13 | | E-11 | 1300 | 470 | 20 | 3400 | 380 | 2.1 | 0.16 | 0.43 | 14 | 1.3 | 1.1 | 0.72 | 1.3 | 0.97 | 5.8 | | E-12 | 2600 | 1700 | 110 | 5700 | 390 | 2.2 | 1.1 | 3.8 | 36 | 21 | 8.5 | 0.80 | 1.3 | 0.88 | 6.6 | | E-16/1 | SE field | 1800 | 540 | l.d. | 140 | l.d. | 2.2 | 1.3 | l.d. | 0.25 | 0.83 | 1.3 | 0.10 | 1.3 | 0.92 | 2.8 | | E-16/2 | 2200 | 400 | l.d. | 40 | l.d. | 1.8 | 0.11 | l.d. | l.d. | 0.77 | 0.9 | 0.13 | 1.2 | 0.88 | 2.4 | | E-17/1 | 2000 | 570 | l.d. | 110 | l.d. | 1.9 | 0.25 | 0.16 | 1.1 | 1.1 | 1.4 | 0.13 | 1.2 | 1.1 | 5.6 | | E-17/3 | 2100 | 370 | l.d. | 70 | l.d. | 2.1 | 0.63 | 0.25 | 0.21 | 0.80 | 1.1 | 0.16 | 1.2 | 1.2 | 4.9 | | E-17/4 | 2000 | 470 | 20 | 580 | l.d. | 1.8 | 0.71 | 0.55 | 4.0 | 5.0 | 2.1 | 0.21 | 1.2 | 1.1 | 1.3 | | E-18 | 1600 | 280 | 10 | 120 | l.d. | 1.9 | 0.37 | 0.24 | 0.34 | 0.86 | 0.95 | 0.21 | 1.3 | 1.2 | 4.3 | | E-19 | 1800 | 330 | l.d. | 40 | l.d. | 2.0 | 0.72 | l.d. | l.d. | 0.82 | 1.0 | 0.16 | 1.3 | 1.2 | 1.9 | | E-20 | 2000 | 670 | 30 | 5000 | l.d. | 2.3 | 0.66 | 0.47 | 5.9 | 1.3 | 1.4 | 0.17 | 1.4 | 0.77 | 6.6 | | E-21 | 1800 | 500 | l.d. | 1000 | l.d. | 1.8 | 0.62 | 0.27 | 10 | 0.30 | 1.1 | 0.32 | 1.3 | 0.95 | 3.4 | |
| Sample | Location | Cu | Zn | Ag | Cd | Pb | Cr | V | Mo | Sn | As | Se | Sb | Te | Br | I | Hg | ppm |
| s-1 | July field | 27 | 71 | 1.1 | 0.84 | 4.7 | 67 | l.d. | l.d. | 0.26 | l.d. | 15 | l.d. | 0.78 | 1.3 | 0.76 | l.d. | s-1/a | 27 | 53 | 0.87 | 0.73 | 4.2 | 23 | l.d. | 0.23 | l.d. | l.d. | 0.93 | 0.25 | l.d. | l.d. | 0.33 | l.d. | s-2 | 25 | 53 | 0.6 | 0.7 | 24 | 7.2 | 12 | l.d. | 0.26 | 66 | 440 | l.d. | 140 | 6.0 | 20 | l.d. | s-3 | 25 | 52 | 0.73 | 0.46 | 7.0 | 12 | l.d. | l.d. | l.d. | l.d. | 150 | l.d. | 11 | 1.8 | 3.5 | l.d. | s-4 | 31 | 74 | 0.94 | 0.83 | 16 | 11 | l.d. | 0.21 | 0.26 | 1.8 | 304 | 0.39 | 40 | 5.4 | 4.9 | l.d. | s-5 | 28 | 56 | 0.7 | 0.66 | 6.4 | 16 | 18 | 0.23 | 0.31 | l.d. | 260 | l.d. | 46 | 16 | 4.4 | l.d. | s-6 | 22 | 52 | 0.77 | 0.6 | 4.7 | 27 | l.d. | l.d. | l.d. | l.d. | 200 | l.d. | 28 | 1.05 | 1.3 | l.d. | s-7 | 28 | 49 | 0.6 | 0.48 | 3.9 | 12 | 7.1 | l.d. | l.d. | l.d. | 99 | 0.27 | 14 | 1.4 | 1.2 | l.d. | s-8 | 28 | 52 | 0.75 | 0.59 | 7.2 | 24 | l.d. | 0.26 | l.d. | l.d. | 160 | 0.36 | 9.1 | 0.97 | 2.1 | l.d. | s-9 | 24 | 49 | 0.74 | 0.61 | 3.1 | 18 | l.d. | l.d. | 0.25 | l.d. | 97 | l.d. | 8.2 | 1.7 | 1.08 | l.d. | s-10 | 25 | 56 | 0.73 | 0.64 | 5.4 | 18 | l.d. | l.d. | 0.31 | l.d. | 160 | l.d. | 30 | 1.7 | 0.77 | l.d. | E-3 | NE field | 46 | 14 | 0.079 | 0.065 | 5.6 | l.d. | 28 | 1.7 | 1.6 | 3.2 | 1.4 | 2.1 | 0.84 | l.d. | 2.3 | 0.16 | E-5 | 9.3 | 9.7 | 0.18 | 0.082 | 2.4 | l.d. | 4.0 | 0.55 | 0.28 | 0.67 | 2.1 | 1.9 | 0.8 | 3.5 | 1.9 | 0.16 | E-6 | 68 | 15 | l.d. | 0.15 | 4.5 | 42 | 31 | 7.6 | 1.6 | 2.0 | 2.8 | 0.71 | 0.7 | 1.0 | 2.0 | l.d. | E-7 | 50 | 14 | 0.19 | 0.14 | 4.2 | 9.0 | 17 | 1.1 | 1.1 | 1.4 | 18 | 0.37 | 0.88 | 0.6 | 1.7 | l.d. | E-9/1 | 11 | 16 | 0.35 | 0.22 | 3.2 | l.d. | l.d. | 0.12 | 0.1 | 3.0 | 13 | 0.45 | 1.2 | 0.5 | 2.5 | 0.3 | E-9/2 | 11 | 17 | 0.16 | 0.14 | 3.3 | 7.0 | l.d. | l.d. | 0.13 | 1.1 | 7.1 | 0.16 | 0.78 | 0.94 | 2.0 | 0.7 | E-8/2 | South field | 66 | 18 | 0.12 | 0.16 | 4.7 | l.d. | 12 | 0.94 | 1.0 | 1.7 | 7.5 | 0.13 | 0.84 | l.d. | 2.1 | l.d. | E-8/3 | 600 | 12 | 0.85 | 0.099 | 11 | 3.5 | 110 | 8.9 | 7.9 | 19 | 20 | 5.1 | 33 | 9.4 | 7.7 | l.d. | E-11 | 81 | 13 | 0.16 | 0.072 | 4.0 | 15 | l.d. | 1.1 | 1.1 | 13 | 42 | 0.4 | 15 | 0.67 | 1.5 | 0.41 | E-12 | 21 | 19 | 0.11 | 0.13 | 6.3 | 23 | 3.6 | 1.3 | 0.98 | 12 | 58 | 5.0 | 0.99 | 3.7 | 5.6 | l.d. | E-16/1 | SE field | 8.3 | 19 | 0.16 | 0.12 | 5.8 | l.d. | l.d. | 0.41 | 0.11 | 49 | 47 | 0.4 | 5.2 | 22 | 3.6 | 0.15 | E-16/2 | 7.5 | 11 | 0.11 | 0.13 | 3.6 | l.d. | l.d. | l.d. | 0.18 | 180 | 41 | 10 | 3.5 | 2.5 | 3.9 | 2.2 | E-17/1 | 9.7 | 17 | 0.24 | 0.27 | 4.6 | l.d. | l.d. | 0.19 | 0.18 | 8.7 | 54 | 0.29 | 0.58 | 14 | 13 | 0.19 | E-17/3 | 9.3 | 13 | 0.14 | 3.9 | 4.2 | 3.9 | 7.2 | 0.15 | 0.17 | 2.6 | 26 | 0.12 | 0.34 | 2.7 | 3.7 | 0.15 | E-17/4 | 10 | 17 | 0.33 | 0.18 | 3.5 | 16 | l.d. | 0.54 | 0.24 | 68 | 21 | 68 | 0.56 | 3.0 | 13 | 2.1 | E-18 | 11 | 13 | 0.16 | 0.064 | 5.0 | 12 | 4.7 | 0.17 | 0.11 | 22 | 64 | 0.35 | 5.7 | 1.6 | 48 | 0.48 | E-19 | 7.9 | 13 | 0.13 | 0.28 | 5.2 | l.d. | l.d. | l.d. | 0.08 | 16 | 70 | 0.15 | 8.5 | 1.9 | 46 | l.d. | E-20 | 15 | 14 | 0.19 | 0.13 | 4.6 | 11 | l.d. | 0.94 | 0.5 | 73 | 45 | 1.5 | 11 | 0.52 | 2.0 | 0.22 | E-21 | 14 | 13 | 0.063 | 0.18 | 5.3 | 10 | 4.5 | 1.1 | 0.56 | 5.1 | 61 | 0.15 | 28 | 0.64 | 2.2 | 0.20 |
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l.d.: below limit of detection. |