Characteristics of Organic Matter Pores and the Relationship with Current Pressure System of Lower Silurian Longmaxi Shales in Dingshan Field, Southern Sichuan, China

Cao, Qian; Jiang, Ke; Wen, Zhentao; Wang, Xingzhi; Qi, Minghui; Yin, Zhongshan

doi:https://doi.org/10.1155/2021/9967479

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Abstract Introduction Methods Results Discussion Conclusions Data Availability Conflicts of Interest Acknowledgments References Copyright Related Articles

Research Article | Open Access

Volume 2021 | Article ID 9967479 | https://doi.org/10.1155/2021/9967479

Characteristics of Organic Matter Pores and the Relationship with Current Pressure System of Lower Silurian Longmaxi Shales in Dingshan Field, Southern Sichuan, China

Qian Cao,^1,2,3Ke Jiang ,⁴Zhentao Wen,⁵Xingzhi Wang,¹Minghui Qi,^2,3and Zhongshan Yin^2,3

Academic Editor: Andrea Brogi

Received24 Mar 2021

Revised31 Jul 2021

Accepted08 Sept 2021

Published08 Oct 2021

Abstract

Organic matter pores (OMP) provide significant storage space for hydrocarbons in lower Silurian Longmaxi shales in the Dingshan field of southern Sichuan, China. The distributions of organic matter and the different OMP structure parameters were characterized through Ar-ion polishing, scanning electron microscopy (SEM), and image analysis software for shale samples of different wells. The research results indicated that organic matter has been divided into two categories based on its occurrence, location, and its relationship with authigenic minerals: organic matter in situ and migrated organic matter. OMP for organic matter in situ are mainly micropores mostly arranged isolatedly, while in migrated organic matter pores show larger sizes and higher roundness. The development of OMP in samples is predominantly controlled by the formation pressure. The existence of overpressure alleviated the stress on the rock skeleton, causing the compaction of some migrated organic matters to lag or decrease. This played a positive role in protecting the development of pores in the interior and edge of the rock skeleton, and it can also induce the development of microfractures in shale. The protective effect of formation pressure on organic pores was provided for understanding the exploration and exploitation of Longmaxi shales in the study area.

1. Introduction

In recent years, investigations on the pore type, pore size, and pore structure characteristic parameters of mud shale have been conducted providing significant achievements under an increasing interest in unconventional hydrocarbons [1–3]. Previous studies on organic-rich shales, such as Barnett, Woodford, Marcellus, and Wufeng-Longmaxi shales, have found that porosity in organic matter represents a significant fraction of the reservoir space [4–6]. The formation and evolution of organic matter pores play an important role in the storage and migration of oil and gas in shale reservoirs, increasing the specific surface area and pore volume of shale providing storage space for shale gas [6–8].

As reported in literature, the in situ organic matter represents the original organic matter and its alteration products. The occurrence of solid bitumen is generally regarded as the secondary product from oil-prone kerogen by thermal degradation and hydrocarbon generation, that is, bitumen and hydrocarbon can be generated in a source rock and then migrated to another [9]. During the process of thermal maturation, kerogen is broken down to bitumen [4, 10–13]. Jacob [14] proposed the concept of “migrabitumen” for the first time. He claimed that migrabitumen (“solid petroleum bitumen”), as a high viscosity fluid, is often distributed in rocks in a dispersive or blocky way, and its morphology largely depended on the shape of the cavity that is occupied by migrabitumen. Organic petrologists have proposed to classify organic matter in shale rocks according to its distribution characteristics, such as occurrence, distribution location, reflectivity, fluorescence, and its relationship with authigenic minerals [15–20]. According to the contact relationship between organic matter and minerals in the mud shale, Zhao et al. [21] and Loucks et al. [3] put forward the petrography logo for distinguishing the migrated solid organic matter and the organic matter in situ (including kerogen and some solid bitumens/pyrobitumens) in marine mud shale. And Liu et al. [22], Bai et al. [23], Zhang et al. [24], and Mastalerz et al. [25] demonstrated that the organic matter observed under SEM is primarily distributed around autogenous silicates or grows with clay minerals. With the morphology, internal structure, and distribution of organic matter, Zhang et al. [6] recognized bitumen, spherical kerogen, algal debris, bacteria-like organic matter, and graphite.

The classification and influencing factors of different organic pores in shale are complex, and no unified understanding had been achieved. The pores located in organic matter is further divided based on maceral type, including biological pores, gas pores, bitumen spherical pores, mold pores, bubble-like organic pores, and honeycomb organic pores [22–24]. Researchers had found that the development of organic matter pores was affected by organic matter contents, organic matter types, thermal evolution degrees, organic matter occurrence states, mineral compositions, diagenesis, and formation pressure coefficient [3, 4, 26–30]. At present, the effect of thermal evolution degree of organic matter on the development of organic pores is mainly studied [31–36]. Yang et al. [37] studied the organic pores of the lower Silurian Longmaxi formation shale with different thermal maturities in Sichuan Basin and pointed out that, for the organic matter of the same macular component, the number of organic matter pores in the samples shows a monotonically increasing trend with the increase of maturity. Meanwhile, the stage of late high maturity to early overmaturity is the main periods for the development of organic pores in the Longmaxi shale formation. However, exploration and development in different areas of southern Sichuan proved that the number and morphology of pores in rich organic matter shales in the lower Longmaxi formation are greatly different from the stage of late high maturity to early overmaturity [34], and the understanding of the differential development characteristics and controlling factors of organic matter pores under different preservation conditions is not clear, which is urgent to carry out related research. In this study, different organic matter types and pore distribution characteristics such as pore size distribution, shape coefficient, and fractal dimension, were quantitatively characterized by Ar-ion polishing and field emission scanning electron microscopy (FE-SEM) and were then combined with energy spectrum analysis and image analysis technology. Based on this, the influence of formation pressure on the pore structure development of organic matter in shale was analyzed in the study area.

2. Samples and Methods

2.1. Geological Setting

Dingshan field is located at the junction of Qijiang of Chongqing and Xishui and Tongzi of Guizhou and is structurally located in the southeast of a fold belt in eastern Sichuan and the northwest of the Qiyueshan fault zone. It has experienced tectonic uplift and burial during the Caledonian period that led to folding and faulting in Yanshan-Himalayan.

Dingshan tectonics is mainly influenced by the Yanshan and middle Himalayan movements. After the late Himalayan movement, tectonic compression and uplift denudation dominated, and folds and faults developed in the whole study area. Because of the influence of Huayingshan fault, Qiyueshan fault, and Daloushan fault, the present structure of Dingshan field is a troughed fold composed of a series of NE and NNE trending high and steep anticlines and fault zones [38], and the overall shape on the plane is NE-SW nose-shaped anticline (Figure 1). The bedding of the northwest flank of the fracture back slope is steeply dipping, with stratigraphic dips mostly above 15°, and is cut by the Qiyueshan fault and associated fractures; the bedding of the northeast flank is relatively gentle, with stratigraphic dips mostly 10-15° (Figure 1) [39, 40]. The target strata of shale gas exploration in this area are the upper Ordovician Wufeng shales and the lower Silurian Longmaxi shales. Influenced by tectonic and two global transgressions during the upper Ordovician to the lower Silurian, the Sichuan Basin and its periphery formed a NE-opening shallow shelf sedimentary palaeogeographic pattern [41].

Figure 1

(a) Tectonic distribution of Sichuan Basin (I: low gentle tectonic of North Sichuan; II: low steep tectonic of West Sichuan; III: gentle tectonic of Middle Sichuan; IV: high steep tectonic of East Sichuan; V: low steep tectonic of Southwest Sichuan; VI: low steep tectonic of South Sichuan; GF1: Weirong gas field; GF2: Weiyuan gas field; GF3: Changning gas field; GF4: Zhaotong gas field; GF5: Fuling gas field). (b) Buried depth map and sampling location of Longmaxi shales in Dingshan field. (c) The formations and sampling target (according to Lu et al. [42] and Zhu [43] modified).

The strata in the study area are composed of Sinian, Cambrian, Ordovician, Silurian, Permian, Jurassic, Cretaceous, Paleogene, and Quaternary, among which the top of Sinian Dengying and Silurian and Permian Maokou have suffered different degrees of denudation due to the tectonic uplift [44]. The Sinian–middle Triassic is composed of marine deposits, while the upper Triassic–Eocene is composed of continental clastic rocks. The whole Wufeng-Longmaxi shales were deposited in the favorable sedimentary facies zone of the deep-water shelf, and the lithology is dominated by gray-black and black carbonaceous mudstone or/and shale with rich organic matter, which is the main shale gas enrichment zone in the study area.

2.2. Sampling Materials

In this study, seven wells (D1 to D7) in the Dingshan field were studied (Figure 1 and Table 1). Among them, wells D1 and D3 are close to the Qiyueshan fault, located in the southeast of the Dingshan area near the edge of the Sichuan Basin (Figure 1(b)), with a burial depth of Longmaxi shales of about 2000-3000 m. Wells D2 and D4-D7 are far away from the Qiyueshan fault, located in the northwest of the Dingshan field close to the inner side of the Sichuan Basin, at a depth of more than 3000 m [45]. At present, the interpretation of shale gas well drilling in the study area showed that shales with are concentrated at the bottom of Wufeng-Longmaxi formation, with a continuous thickness over than 30 m in each well [40, 46]. Seven shale samples from the bottom of Longmaxi shales across wells D1 to D7 were collected in the Dingshan field.

2.3. Methods

Organic carbon content is measured by using the RJXWK-1 carbon-sulfur analyzer according to the total organic carbon (TOC) test standard in sedimentary rocks (GB/T 19145-2003). Firstly, the samples are ground until the particle size is less than 0.2 mm, and samples of 0.01-1.00 g are weighed and put into a porcelain crucible. Then, slowly add excessive dilute hydrochloric acid solution (the volume of dilute hydrochloric acid is bigger than 3 mL and must completely cover the sample), and heat it in a water bath (temperature controlled at 60-80°C). Note: the sample dissolution time must be more than 2 hours until the reaction is complete. Finally, the acid-treated samples are placed in the porcelain crucible on the suction strainer and washed to neutral with distilled water. The porcelain crucible containing the samples is dried and burned in a high-temperature oxygen stream to convert the total organic carbon into carbon dioxide. The total organic carbon content is determined by an infrared detector.

The thermal maturity of organic matter is measured through the Axio Scope A1 polarized light microscope with MSP400 spectrophotometer according to the vitrinite reflectance test standard in sedimentary rocks (SY/T 5124-2012). In the test, samples were first crushed to 0.5~1.0 mm in size, and 10~20 g is taken for reserve by shrinkage method.

Put about 5 g of samples and epoxy resin into a round mold with a diameter of 25 mm in a ratio of 1 : 1, stir evenly and add epoxy resin to it after a little curing to a height of about 12 mm, and take out the light sheet for testing after 24 h. According to the actual reflectivity of the samples, the standard samples of Yttrium Aluminum Garnet (), Gadolinium Gallium Garnet (), Cubic Zirconia (), and Diamond () were used for calibration before the test.

The types of organic matter were determined under light microscope observations and fluorescence according to the method of kerogen maceral identification and classification (SY/T 5125-2014).

Organic matter pores were investigated by Ar-ion polishing, FE-SEM, and energy spectrum analysis. The analysis instruments are American Gaton (polishing), ZEISS sigma 300 (scanning electron microscopy, SEM), and Bruker Quantax 200 (energy dispersive spectroscopy, EDS). The resolution is 0.8 nm (15 keV) in the secondary electron mode and 0.6 nm (15 keV) in the transmission electron mode for ZEISS sigma 300. Samples are firstly cut vertical to the shale bedding into , and the selected polishing surface is polished by Ar-ion and observed by SEM. Pore parameters such as diameter, shape coefficient, and fractal dimension were analyzed by means of ImageJ image software.

Fillippone formula is a formation pressure calculation method independent of normal compaction trend line proposed by W.R. Fillippone based on seismic, well logging and drilling data in the Gulf of Mexico and other areas, which is . is the pore pressure in formation, MPa; is the formation acoustic velocity when the rock rigidity is close to zero, which is approximate to the pore fluid velocity, m/s; is the P-wave velocity when the rock porosity is close to zero, m/s; is the seismic velocity of the layer, m/s; and is the overburden pressure, MPa.

3. Results

3.1. Geochemical Characteristics

The TOC of the test samples is bigger than 3.5%, with relatively high TOC content. Under optical microscope, the organic macerals are solid bitumen, mineral-bituminous groundmass, some animal debris, and algae (Figure 2). The solid bitumen shows clear morphology, but the mineral-bituminous groundmass itself has no fixed morphology and mostly cogrowing with inorganic minerals to form symbiote (Figures 2(a)–2(d)). Combined with the transmission electron microscope (TEM) observation, the animal debris in the samples mainly included graptolites and foraminifera, which were partially degraded in the deposition stage and partially transformed into amorphous dispersed organic matter and retained (Figures 2(c)–2(f)). Some graptolite debris are distributed in rock matrix, and the particle size is larger than solid bitumen (Figures 2(c) and 2(d)).

(a)

(b)

(c)

(d)

(e)

(f)

The vitrinite reflectivities (Ro, %) of seven samples were measured after sample preparation. The organic matter observed under the microscope is mainly bitumen, and the bitumen distributed in the clay mineral is greatly affected by mineral interference during measurement. Therefore, the bitumen with granular or angular shape distributed in the pore or mineral particle edge is selected, and the random reflectivity value (Rb, %) of this kind of bitumen is tested (Figure 3 and Table 2). The results show that the random reflectance of this kind of bitumen is mainly distributed in the range of 2.54%~2.97% (total number of measuring ), and vitrinite reflectance equivalence values were calculated according to different conversion formulas proposed in literatures [14, 47–50]. The thermal evolution degree (Ro, %) of organic matter of the seven samples is mostly distributed in the range of 2.22%-2.55%, depicting the (over-) mature stage of hydrocarbon generation.

3.2. Characteristics of Organic Matter

SEM observation has shown that micropores in the shale reservoir of Longmaxi shales for different organic matters have quite different distribution morphology and pore development characteristics. Based on the petrological and morphological distribution characteristics of different organic matters which were distributed in the matrix or independently, we proposed that organic matter can be divided into two categories: organic matter in situ and migrated organic matter. Most of the organic matter in situ is distributed in the shale matrix in blocks, and some of the organic matter is distributed in a curved shape. Besides, organic matter in situ is composed of algae, acritarchs, and plant debris (Figure 4), which are closely bound with mineral matrix. Pores were found in organic matters in situ, mostly in the form of isolated and randomly distributed pores (Figure 4(f)), some of them connected.

(a)

(b)

(c)

(d)

(e)

(f)

The morphology of migrated organic matter (i.e., solid bitumen) is irregular and is mostly cogrown within the matrix mineral filling between the mineral edges of silicates, clay minerals, or pyrite. Minerals and migrated organic matter are mixed, without clear boundary. Because of the strong plasticity of organic matter, part of migrated organic matter is strongly compacted during diagenesis, and its morphology is primarily determined by the distribution morphology of surrounding symbiotic minerals. Clay minerals have small particle size and poor crystal morphology; thus, the organic matter cogrowing with the clay minerals mainly developed in their intercrystalline pores and some of the organic matter is bent and deformed along with the clay minerals. Lu et al. [28, 51] studied the influence of clay minerals in shale on the occurrence state of organic matter and pointed out that the increase of clay mineral content, such as illite, positively correlates with the increase of organic matter storage space and the development of organic matter pores (Figures 5(a), 5(b), and 5(f)). The pore size of organic matter pores in the clay mineral lattice is large, and some of them were connected to form a series of pores which were mainly approximately elliptical, irregular, and cucurbitaceous (Figures 5(a) and 5(f)). Moreover, under microscopic observation, the main occurrence types of pyrite in the test samples were banded, framboidal, and cubic. The organic matter developed between the crystals in framboidal pyrite or at the edge of framboidal pyrite (Figures 5(c) and 5(d)). Organic matter pores are mostly approximately elliptical and irregular and partially connected to each other.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 5

Characteristic of migrated organic matter and their organic matter pores in Longmaxi formation shale in Dingshan field under SEM. (a, b) Migrated organic matter and its organic matter pores between silicate particles. (c) Migrated organic matter and its organic matter pores in the intercrystalline pores between pyrite monocrystals. (d) Migrated organic matter and its organic matter pores in the interparticle pores between framboidal pyrite and surrounding minerals. (e) Migrated organic matter and its organic matter pores between particles. (f) Migrated organic matter and its organic matter pores in the interparticle pores between clay minerals.

3.3. Characteristics of Organic Matter Pore Development in Different Wells

Not all organic matter has pores. As the carrier of organic pores, organic matter has various pore characteristics. Based on the above analysis, the mechanisms that led to pore development in different organofacies were different. To more accurately analyze these differences, a large number of SEM images were processed and analyzed. Pore numbers, median pore diameter, shape coefficient, and fractal dimension [33] were used to quantitatively characterize pores in different organic matter types (Table 3).

The pore diameter is defined as equivalent circle diameter. The equivalent circular diameter of narrow-long irregular pores can be expressed as . and are the length and width of pore, respectively.

The shape coefficient is expressed as . and are the area and perimeter of pore cross section, respectively. If the shape coefficient is 1, it means that the object is round.

The distribution ratio () of different types of organic matter is defined as the percentage of organic matter distribution area and total area on the SEM image. ; is the sectional area of organic matter and is the total area of the sample observed in the SEM image.

The fractal dimension is determined by the relationship between the pore number and pore size () of different size pores in the sample. According to the fractal theory, when the pore size distribution in porous media has fractal characteristics, the relationship between the pore number and pore size () exists as follows: . is the maximum pore size, is the probability density function of pore size distribution, is constant, and is the fractal dimension.

The pore size, shape coefficient, and fractal dimension of organic matter pores in different samples are shown in Table 3 and Figure 6. The results outline that pores in wells D1 and D3 are mainly micropores and mesopores, with a relatively small size, mainly within the range from 5 to 50 nm. Pores are primarily irregular and partially slit, with a mean shape coefficient of 0.674 and 0.554, respectively. In wells D2 and D4 to D7, the organic matter pores are mainly mesopores, with a pore size mainly between 8 nm and 80 nm. Pores are mainly round and elliptical, with a mean shape coefficient larger than 0.801.

The linear slope of the plot vs. is utilized to calculate the fractal dimension, which mainly ranged from 1.1 to 1.8 (Figure 7). In the SEM image, the distribution ratio of migrated organic matter is calculated as the percentage of organic matter distribution area and total area. From the relationship between the fractal dimension and the migrated organic matter contents, it could be observed that the higher the migrated organic matter contents, the more developed the organic matter pores, the more complex the pore morphology, and the higher the fractal dimension (Figure 8).

4. Discussion

Seven samples selected in this study are located in the same tectonic and have the same geological conditions. They are all in the deep-water shelf sedimentary environment, and the TOC contents are mostly above 3.5%. The brittle mineral contents (quartz + feldspar) are between 40% and 55% (Table 1). The main types of organic matter are sapropelic, with the thermal evolution of overmature (). The organic matter generally produces a lot of hydrocarbon and has similar geological evolution process. However, the porosity of different samples varies greatly. The average porosity of wells D2 and D4-D7 is relatively high, with an average of 5.49%, but the porosities of wells D1 and D3 are significantly reduced, with the porosity of 4.02% and 4.13%, respectively. Meanwhile, there are some differences in the number, size, and morphology of organic pores in different wells, which may be caused by the difference of formation pressure in different areas. So the influences of tectonic movement and formation pressure on the development of organic matter pores are mainly analyzed.

4.1. Formation Pressure Characteristic

Chen [52] pointed out that the formation pressure of Longmaxi shales in the study area was mainly affected by tectonic compression and fault distribution. Dingshan field is located in the transition from the trough-type fold belt in the west of Hunan and Hubei to the barrier-type fold belt in the east of Sichuan, which is a thrust nappe tectonic belt controlled by the Qiyueshan fault. Qiyueshan fault as the largest concealed basement fault in the Dingshan field, which is along the NE-trending to distribution, and after the basement thrusting of compresso-shear, remolding of Guizhou plate, and differential uplifting in Himalayan, the basement thrust occurred under the NE-trending thrust and formed strong fold deformation in Yanshanian. Qiyueshan fault plays a decisive role in the tectonic framework of the study area, cutting through the Silurian shale and its roof and floor and controlling the scale of fracture development [43]. According to the analysis of burial history and hydrocarbon generation history of wells D1 and D2 (Figure 9) [53], the Longmaxi formation shale showed rapid depositing during the middle-late Silurian. In Devonian to Carboniferous, it is continuously uplifted, but the uplifted amplitude is small and the buried depth is shallow, and after reaching the hydrocarbon generation threshold in early Devonian, it is always in the low maturity stage. After the early Permian, with the rapid increase of depositing rate, the burial depth and maturity of shale increased rapidly. In the early Triassic, the shale reached the peak of oil generation. In the early Jurassic, the shale rapidly entered the dry gas stage. In the early Cretaceous, with the burial depth reaching the maximum, the formation pressure reached the peak. The fluid compaction coupling model is selected to simulate the pressure evolution [54], and after the pressure in the Longmaxi formation shale reached the maximum in the late Cretaceous, the formation pressure decreased in different degree due to the influence of three stages of tectonic uplift (including rapid uplift from early Cretaceous to the end of late Cretaceous, slow uplift from the end of late Cretaceous to Oligocene, and rapid uplift since Oligocene) and denudation and the development of Qiyueshan fault zone.

The distances between different wells and Qiyueshan fault and the fracture degree and the denudation degree of strata are different. By analyzing the development of Longmaxi formation shale in the Dingshan field, Zhong [55] pointed out that since the Yanshanian tectonic movement, the region of wells D1 to D3 near the Qiyueshan fault has been uplifted for a long time (about 85 Ma) and a large uplift height (about 2800 m), and the sealing capability of fractures and faults is poor. However, the region of wells D2 to D7 far away from the Qiyueshan fault has a low degree of tectonic reconstruction and good sealing capability of fractures and faults. Generally, the larger the fault displacement, the more developed the nearby fractures and the greater the degree of formation pressure relief [56]. The variation of uplift-denudation period and denudation thickness will have a significant influence on the physical properties of shale reservoirs, hydrocarbon generation and expulsion behavior, and the formation and maintenance of overpressure state [57].

From Figure 10, wells D1 and D3 are located in the southern section of Dingshan fault-nose anticline, 8.5 km and 14.7 km away from Qiyueshan fault, respectively, and the fault displacement near well D1 is large, generally more than 100 m, and high-angle fractures are developed (Figures 1 and 10). Wells D2 and D4 are located in the slope zone and syncline of Dingshan structure, with relatively stable structure, 17.4 km and 13.1 km away from the outcropping denuded area of Longmaxi shales and 23.3 km and 25 km away from Qiyueshan fault. The fault displacement around well D2 is relatively small, generally less than 60 m. They are less influenced by the superposition of tectonic stress and only form NW-SE trending fractures, with no high-angle fractures in the roof [43, 46].

Fillippone formula is employed to predict the present pressure of Longmaxi shales by using pseudoacoustic seismic inversion [40]. Results indicated that the pressure coefficient gradually increased from southeast to northwest. Pressure coefficient refers to the ratio of original formation pressure to hydrostatic column pressure, based on the data collected from shut-in pressure buildup test of wells D1 to D5 in Dingshan field (Table 4 and Figure 10). In the shut-in pressure recovery calculation of well D2, the pressure at the converted formation depth of 4398 m is 80.80 MPa, and the pressure coefficient is 1.82. It indicates that the pressure systems of shale reservoir in wells D1 and D3 are normal, but are high-ultrahigh pressure system (the formation pressure coefficient is greater than 1.2) in wells D2, D4, and D5.

4.2. Influence of Pressure System on Organic Matter Pore Characteristics

By comparing the pressure coefficient and gas production of some shale gas reservoirs (Table 5), it is shown that the pressure coefficient positively correlates with shale gas production [58–60]. There is a certain correlation between gas content and fluid pressure coefficient of shale reservoir, that is, the greater the pressure coefficient is, the greater the gas production is.

As an important part of shale pore system, organic matter pores are formed in the process of shale hydrocarbon generation and evolution. They are the traces left by shale gas generation, diffusion, and accumulation and also the embodiment of gas generation and storage capacity of shale reservoir. Taking thermal maturity (Ro, %) as the main classification index, the evolution of organic matter pores in shale can be divided into four stages, including im- and low-maturity stage (), mature stage (), high- and overmaturity stage (), and metamorphic stage () [61, 62]. Crude oil is formed by early pyrolysis of kerogen in the im- and low-maturity stage and mature stage. With the increase of thermal evolution degree, part of the residual crude oil in the shale cracked into natural gas with the rise of temperature and pressure, and the generated natural gas initially existed in the form of tiny gas cores. With the continuous cracking and separation of the light components in the crude oil, the crude oil began to be transformed into bitumen, and the amount of cracking gas increased, accompanied by the formation of a large number of organic pores. The morphology of organic pores is from the initial formation of microcracks in the organic matter, to the formation of round or elliptical honeycomb pores, and then to the interconnection of honeycomb pores to form aggregates. That is to say, without the influence of formation pressure, with the increase of thermal evolution degree, organic pores are mostly round or elliptical and part of them is interconnected.

For example, in well D3, the Longmaxi formation is characterized by large denudation thickness and relatively close proximity to the Qiyueshan fault, so the Longmaxi formation is more prone to slip deformation and pressure unloading, and the pressure relief intensity is high (with the present formation pressure coefficient of 1.15). Also, organic matter and organic matter pores in shale are deformed and contracted under lateral stress extrusion and pressure unloading, and organic matter is mostly distributed in band. Although the number of pores in the organic matter is large, the pore size is relatively small, about 10-25 nm. The pore morphology is mostly long-narrow or oblate, and some organic pores gradually changed into oblate mesopores directionally (Figures 4(a) and 4(d)). These indicate that the organic pores suffer from strong compaction, causing the pore size to become smaller or even to disappear.

However, in well D7, the formation pressure evolution of Longmaxi formation is characterized by small denudation thickness, far away from Qiyueshan fault and low pressure relief intensity (the formation always maintains overpressure, and the present formation pressure coefficient is 1.58). Under SEM, a large number of banded, irregular, or lamellar organic matters were found between mineral particles. The organic matter pores in the triangular zone of some rigid mineral particles and the interlayer pores of some clay minerals developed. These organic matter pores were round or elliptical and partially irregular and slit (Figure 4(f)). Because of the protection of organic matter by inorganic minerals and other matrices, the morphology of organic matter pores is well protected, and some organic matter pores were large and interconnected. These indicate that the formation of overpressure hinders the normal compaction and preserves some organic pores with little morphological changes. Therefore, overpressure plays an important protective role in the preservation of organic matter pores in shale.

Shale gas is an unconventional resource that is generated and stored in the source rock without any migration. Shale gas forms in a physical-chemical system composed of inorganic minerals, organic matter, and formation fluids, which are associated with and mutually influenced by multiple processes [30]. In the process of diagenetic evolution, hydrocarbon generation from organic matter leads to the increase of pore fluid pressure in the formation, and with the increase of burial depth, the loading pressure of the overlying shale increases continuously. Under the influence of tectonic uplift, denudation, and fault, the loading pressure of the overlying shale changed, leading to the pressure relief of the shale reservoir in different degrees. Under the semiclosed environment, the strata are damaged greatly due to the influence of tectonic uplift and fault, and the overburden pressure of shale is greater than the pore fluid pressure, which leads to the compaction of organic matter and the change of morphology. The organic pores are compressed, the pore size decreases, and some pores even close and disappear (Figure 11(a)). However, under the closed environment, the strata are uplifted as a whole with little damage, and the overburden pressure of the shale is less than the pore fluid pressure, so part of the pressure formed during the cracking of organic matter can be maintained. The compaction of organic matter is small, and the morphology of organic pores is relatively round and the pore size is larger (Figure 11(b)), indicating that overpressure is an important protection for the preservation of organic matter pores in shale. Meanwhile, microfractures also develop under high formation pressure, which can increase the storage space of shale and also can lay a foundation for fracturing construction and artificial fracture expansion in the later stage.

(a) Semiclosed system

(b) Closed system

5. Conclusions

The following conclusions were drawn from this study: (1)Based on the petrological characteristics, genesis, and morphological distribution of different organic matters, the organic matter could be divided into two types: organic matter in situ and migrated organic matter. The migrated organic matter included solid bitumen that is found in interparticle pores of silicates, while the organic matter in situ is found in interparticle pores of clay minerals and pyrite(2)The pore size, shape coefficient, and fractal dimension are different for organic matter in situ or migrated organic matter and change with wells moving toward the Qiyueshan fault. In organic matter in situ, porosity is mainly represented by isolated micropores and a few mesopores. Affected by the plasticity of organic matter, pores in the organic matter in situ are complex in morphology but directional distribution(3)The development of organic pores in the Dingshan field is predominantly controlled by the formation pressure. Overpressure could mitigate the stress acting on the rock skeleton by reducing the compaction of interstitial migratory organic matter at the edge of minerals. The morphology of organic matter pores is almost round and the diameter of the pores is larger when the pressure coefficient is higher than 1.2, indicating that overpressure provided positive protection for the preservation of organic matter pores in shale. Besides, microfractures develop under high formation pressure, which can increase the shale storage space and also can lay a foundation for fracturing construction and artificial fracture expansion in the later stage

Data Availability

The data are attached to the article.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

This study is supported by the Central Government Guide Local Science and Technology Development Special Project of 2020 (No. 2020ZYD027).

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