Research Article

SN-Donor Methylthioanilines and Copper(II) Complexes: Synthesis, Spectral Properties, and In Vitro Antimicrobial Activity

Table 1

1H and 13C chemical shifts (δ) for substituted-6-(methylthio)aniline ligands in ppm.

LigandsC1C2H, C3H, C4H, C5H, C6H, C7H 8H, C9

(L1)--------6.84 d6.83 t6.64 d----2.43 s3.81 s3.83 s
134.90125.46115.04122.45112.29147.1718.80----55.36
(L2)--------7.11 d7.09 t6.61 d----2.42 s3.57 s2.15 s
143.20122.84128.33115.25131.77125.1218.55----17.04
(L3)--------7.26 d6.68 t7.07 d----2.41 s3.97 s----
141.32119.41129.06116.16130.05126.5818.42--------
(L4)--------7.42 d6.66 t7.11 d----2.40 s4.02 s----
142.55126.91129.89115.97133.18109.3118.57--------

s singlet; d doublet; t triplet.