<i>SN</i>-Donor Methylthioanilines and Copper(II) Complexes: Synthesis, Spectral Properties, and<i> In Vitro</i> Antimicrobial Activity

<table class="fixed-width table-group" id="tab2"><tr><td><table class="table"><colgroup><col style="width:6.58em"/><col style="width:3.48em"/><col style="width:3.41em"/></colgroup><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td class="align_left">Compound</td><td class="align_center"><i>g</i><sub>⊥</sub></td><td class="align_center"><i>g</i><sub>∥</sub></td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td class="align_left"><svg height="11.439pt" id="M50" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M290 -163V-135C183 -126 181 -122 181 -44V583C181 662 184 666 290 675V703H120V-163H290Z"></path></g></svg>Cu(L1)Cl<sub>2</sub><svg height="11.439pt" id="M51" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M226 -163V703H56V676C162 667 165 662 165 584V-43C165 -122 162 -126 56 -136V-163H226Z"></path></g></svg></td><td class="align_center">2.108</td><td class="align_center">2.293</td></tr><tr><td class="align_left"><svg height="11.439pt" id="M52" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M290 -163V-135C183 -126 181 -122 181 -44V583C181 662 184 666 290 675V703H120V-163H290Z"></path></g></svg>Cu(L2)Cl<sub>2</sub><svg height="11.439pt" id="M53" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M226 -163V703H56V676C162 667 165 662 165 584V-43C165 -122 162 -126 56 -136V-163H226Z"></path></g></svg></td><td class="align_center">2.129</td><td class="align_center">2.256</td></tr><tr><td class="align_left"><svg height="11.439pt" id="M54" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M290 -163V-135C183 -126 181 -122 181 -44V583C181 662 184 666 290 675V703H120V-163H290Z"></path></g></svg>Cu(L3)Cl<sub>2</sub><svg height="11.439pt" id="M55" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M226 -163V703H56V676C162 667 165 662 165 584V-43C165 -122 162 -126 56 -136V-163H226Z"></path></g></svg></td><td class="align_center">2.052</td><td class="align_center">2.142</td></tr><tr><td class="align_left"><svg height="11.439pt" id="M56" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M290 -163V-135C183 -126 181 -122 181 -44V583C181 662 184 666 290 675V703H120V-163H290Z"></path></g></svg>Cu(L4)<sub>2</sub>Cl<sub>2</sub><svg height="11.439pt" id="M57" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 4.60146 11.439" width="4.60146pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M226 -163V703H56V676C162 667 165 662 165 584V-43C165 -122 162 -126 56 -136V-163H226Z"></path></g></svg></td><td class="align_center">2.066</td><td class="align_center">2.215</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>EPR parameters for copper(II) complexes.</div>

Heteroatom Chemistry

tab2

Table 2

Table 2: <i>SN</i>-Donor Methylthioanilines and Copper(II) Complexes: Synthesis, Spectral Properties, and<i> In Vitro</i> Antimicrobial Activity 

Heteroatom Chemistry

SN-Donor Methylthioanilines and Copper(II) Complexes: Synthesis, Spectral Properties, and In Vitro Antimicrobial Activity

Table 2