Research Article

Ultra High-Mass Resolution Paper Spray by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

Table 2

PPG standards identified using paper spray mass spectrometry. The PPG mass spectrum was obtained with excitation and detection frequency range of 1.5 MHz.

PPGExperimental m/z Theoretical m/z Mass measurement error (Δppm)Mass resolving power (M/ΔM50%)[C3O2H7(C3H6O)nC6H13O2+Na]+

1666.171971666.17200−0.0222686
1724.212241724.21386−0.9423629
1782.257811782.255731.1723817
1840.298291840.297600.3723808
1898.341131898.339460.8823139
1956.379921956.38133−0.7222968
2014.419372014.42319−1.9022638
2072.468492072.465051.6621991
2130.500882130.50692−2.8421503
2188.553702188.548782.2520679
2246.592192246.590650.6919685
2304.631822304.63254−0.3117868
2362.673702362.67438−0.2916365