Research Article
Rapid Screening and Structural Characterization of Antioxidants from the Extract of Selaginella doederleinii Hieron with DPPH-UPLC-Q-TOF/MS Method
Table 3
Identification of 9 biflavonoids from Selaginella doederleinii by UPLC/Q-TOF MS/MS.
| Peak number | tR (min) | Measured (M+H)+ | Calculated | ESI-MS/MS | Formula | Identification |
| 1 | 5.25 | 539.0956 | 538.0899 | 539 [M+H]+ 421 [M+H-C8H6O]+ 403 [M+H-C8H6O-H2O]+ 377 [M+H-C9H6O3]+ 153 [C7H4O4]+ 121 [C7H6O2]+ | C30H18O10 | Amentoflavone |
| 2 | 6.19 | 539.0977 | 538.0899 | 539 [M+H]+ 413 [M+H-C6H4O3]+ 387 [M+H-C7H4O4]+ 270 [M+H-C15H9O5]+ | C30H18O10 | Robustaflavone |
| 3 | 7.28 | 553.1110 | 552.1056 | 553 [M+H]+ 435 [M+H-C8H6O]+ 403 [M+H-C8H6O-CH3OH]+ 391 [M+H-C9H6O3]+ 297 [M+H-C8H6O-C2H2O-C3O2-CO]+ 153 [C7H4O4]+ 121 [C7H6O2]+ | C31H20O10 | Bilobetin |
| 4 | 8.32 | 553.1127 | 552.1056 | 553 [M+H]+ 427 [M+H-C6H4O3]+ 401 [M+H-C7H4O4]+ 270 [M+H-C15H9O5]+ | C31H20O10 | 4′-Methoxy robustaflavone |
| 5 | 8.81 | 553.1086 | 552.1056 | 553 [M+H]+ 421 [M+H-C9H8O]+ 403 [M+H-C9H8O-H2O]+ 377 [M+H-C10H8O3]+ 153 [C7H4O4]+ 135 [C8H8O2]+ | C31H20O10 | Podocarpusflavone A |
| 6 | 9.27 | 539.0963 | 538.0899 | 539 [M+H]+ 286 [M+H-C15H9O4]+ 270 [M+H-C15H9O5]+ 257 [M+H-C15H9O4-CO]+ 242 [M+H-C15H9O5-CO]+ | C30H18O10 | Hinokiflavone |
| 7 | 10.92 | 567.1273 | 566.1212 | 567 [M+H]+ 449 [M+H-C8H6O]+ 417 [M+H-C8H6O-CH3OH]+ 405 [M+H-C9H6O3]+ 167 [C8H6O4]+ 121 [C7H6O2]+ | C32H22O10 | Ginkgetin |
| 8 | 11.47 | 567.1283 | 566.1212 | 567 [M+H]+ 435 [M+H-C9H8O]+ 417 [M+H-C9H8O-H2O]+ 391 [M+H-C10H8O3]+ 167 [C8H6O4]+ 135 [C8H8O2]+ | C32H22O10 | Putraflavone |
| 9 | 14.92 | 581.1434 | 580.1369 | 581 [M+H]+ 449 [M+H-C9H8O]+ 417 [M+H-C9H8O-CH3OH]+ 405 [M+H-C10H8O3]+ 167 [C8H6O4]+ 135 [C8H8O2]+ | C33H24O10 | Heveaflavone |
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