Direct Analysis of Low-Volatile Molecular Marker Extract from Airborne Particulate Matter Using Sensitivity Correction Method
Table 3
Results of standard-spiked test.
Spiked mass
Determined mass
Offset
Recovery yield
Recovery ratio
(ng)
(ng)
(ng)
(%)
BaPd2
40.0
n.a.
n.a.
33 ± 7
n.a.
Cor
159.6
206 ± 15
46 ± 15
64 ± 22
1.91 ± 0.30
BgP
140.3
150 ± 3
10 ± 3
50 ± 13
1.50 ± 0.08
Ind
140.6
129 ± 2
14 ± 2
43 ± 12
1.29 ± 0.11
Db
140.6
140 ± 4
0 ± 4
46 ± 14
1.38 ± 0.14
BaP
140.1
134 ± 10
−6 ± 10
44 ± 10
1.33 ± 0.09
TrisHp
137.4
121 ± 9
16 ± 9
74 ± 11
1.24 ± 0.04
NorHp
39.2
44 ± 4
4 ± 4
90 ± 17
1.51 ± 0.10
abHp
137.4
135 ± 11
−2 ± 11
83 ± 14
1.39 ± 0.05
baHp
39.2
36 ± 3
−3 ± 3
78 ± 13
1.31 ± 0.06
C24d50
200.0
n.a.
n.a.
60 ± 8
n.a.
C20
198.8
185 ± 20
−14 ± 20
78 ± 12
1.31 ± 0.14
C21
151.2
149 ± 16
−2 ± 16
83 ± 13
1.40 ± 0.07
C22
274.4
245 ± 22
−30 ± 22
75 ± 10
1.26 ± 0.06
C23
168.0
173 ± 15
5 ± 15
87 ± 11
1.46 ± 0.02
C24
176.4
178 ± 14
1 ± 14
84 ± 12
1.42 ± 0.03
C25
123.2
133 ± 14
10 ± 14
92 ± 13
1.54 ± 0.02
C26
154.0
162 ± 15
8 ± 15
88 ± 13
1.48 ± 0.04
C27
123.2
170 ± 21
46 ± 21
118 ± 20
1.97 ± 0.10
C28
198.8
206 ± 17
7 ± 17
87 ± 14
1.45 ± 0.05
C29
135.8
193 ± 13
57 ± 13
117 ± 18
1.96 ± 0.05
C30
142.8
207 ± 18
64 ± 18
117 ± 20
1.96 ± 0.10
C31
168.0
190 ± 14
48 ± 14
97 ± 13
1.63 ± 0.03
C32
145.6
186 ± 13
40 ± 13
107 ± 13
1.79 ± 0.02
C33
137.2
198 ± 15
60 ± 13
123 ± 13
2.06 ± 0.06
C34
137.2
186 ± 27
48 ± 13
138 ± 10
2.33 ± 0.14
The mass determined by the internal standard method. Offset = determined mass – spiked mass. Recovery yields calculated using the C30d62 ISRC. The ratio of recovery yield of the substance to the recovery yield of the internal standard (BaPd2 for the PAHs and C24d50 for the rest of the compounds). Not applicable.
