Core-Shell Columns in High-Performance Liquid Chromatography: Food Analysis Applications

Table 1

Literature comparison to the proposed method for the determination of biogenic amines (adapted from [54]).

Apparatus, derivatization agent	Biogenic amines	Analytical column, flow	Run time (min)	Time per analyte (min)	Solvent consumption (mL)	Matrix	Ref.
HPLC-FD; Dansyl-Cl	MEA, ETA, AGM, -PEA, PUT, CAD, HIS, IS, SER, TYM, SPD, SPM	Kinetex C18; 100 × 4.6 mm 2.6 µm; Φ = 0.6 mL/min	13	1.1	7.8	Wine, fruit nectar	[54]
HPLC-FD; AccQ-Fluor™; Reagent Kit	PUT, CAD, HIS, IS, TYM	Kinetex PFP; 100 × 4.6 mm 2.6 μm; Φ = 0.8 mL/min	25	5	20	Wine	[52]
HPLC-UV; Dansyl-Cl	AGM, -PEA, PUT, CAD, HIS, IS, TRYP, TYM, SPD, SPM	Chrompack Hypersil C18; 250 × 3.0 mm 5 µm; Φ = 1 mL/min	29	2.9	29	Fish	[66]
HPLC-UV; Dansyl-Cl	CAD, PUT, HIS, TYR, TRYP, PHE, IS, SPD, SPM, MEA, ETA	C18 Supelco Discovery; 150 × 2.1 mm 5 µm; Φ = 0.4 mL/min	30	2.7	12	Wine	[67]
HPLC-FD; Dansyl-Cl	CAD, PUT, HIS, TYR, TRYP, AGM, ISO, MEA, ETA	C18. Luna; 250 × 4.6 mm 5 µm; Φ = 1 mL/min	35	3.9	35	Wine	[68]
Ion pair HPLC; OPA	SPD, SPM, PUT, AGM, SYN, TYM, OCT, HIS, SER, CAD, TRYP, -PEA	Bondapak C18; 300 × 3.9 mm 10 µm; Φ = 0.7 mL/min	71	5.9	50	Orange juice	[69]
HPLC-UV; Dansyl-Cl	AGM, -PEA, PUT, CAD, HIS, IS, TRYP, TYM, SPD, SPM	Zorbax Eclipse C18; 50 × 4.6 mm 1.8 µm; Φ = 1 mL/min	12	1.2	12	Fish	[70]
UHPLC-UV; Dansyl-Cl	TRYP, -PEA, PUT, CAD, HIS, IS, TYM, SPD, SPM	Zorbax Eclipse C18; 50 × 4.6 mm 1.8 µm; Φ = 1 mL/min	12	1.3	12	Meat, cheese, mushrooms	[71]
UHPLC FD; OPA	OC, DO, TYR, PUT, SER, CAD, HIS, AGM, -PEA, SPD, TRYP, SPM	Acquity UPLC BEH; 50 × 4.6 mm 1.7 µm; Φ = 0.8 mL/min	7	0.6	5.6	Wine, fish, cheese, dry sausages	[57]

OPA, o-phthalaldehyde; SPD, spermidine; SPM, spermine; PUT, putrescine; AGM, agmatine; SYN, synephrine; TYM, tyramine; OCT, octopamine; CAD, cadaverine; HIS, histamine; SER, serotonin; TRYP, tryptamine; ETA, ethylamine; MEA, methylamine; HIS, histamine; -PEA, -phenylethylamine; DO, dopamine; ISO, isopropylamine; IS, internal standard.