Research Article
Corrosion Inhibition Effect of 4-Hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] Benzohydrazide on Mild Steel in Hydrochloric Acid Solution
Table 1
Tafel polarization results for the corrosion of mild steel in 1 M HCl in the absence and presence of inhibitor at different temperatures.
| Temp. (°C) | Conc. of HIBH (mM) | (mV/SCE) | (mV dec−1) | (mV dec−1) | (mA cm−2) | CR (mmy−1) | % IE |
| 30 | 0 | | 73.1 | 73.1 | 1.894 | 11.74 | — | 0.01 | | 65.0 | 73.8 | 0.534 | 3.31 | 71.7 | 0.025 | | 69.2 | 99.8 | 0.486 | 3.01 | 74.3 | 0.05 | | 68.9 | 112.3 | 0.374 | 2.45 | 80.2 | 0.1 | | 73.5 | 119.3 | 0.269 | 1.67 | 85.7 | 0.2 | | 78.2 | 113.4 | 0.240 | 1.49 | 87.3 | 0.4 | | 76.6 | 102.4 | 0.206 | 1.28 | 89.1 | 0.6 | | 73.2 | 102.7 | 0.183 | 1.13 | 90.3 | 0.8 | | 78.8 | 115.7 | 0.161 | 1.00 | 91.4 |
| 40 | 0 | | 68.7 | 60.9 | 3.352 | 20.78 | — | 0.01 | | 71.2 | 79.4 | 0.780 | 4.83 | 76.7 | 0.025 | | 76.3 | 98.5 | 0.641 | 3.98 | 80.8 | 0.05 | | 75.5 | 100.1 | 0.572 | 3.55 | 82.9 | 0.1 | | 77.9 | 102.3 | 0.467 | 2.90 | 86.0 | 0.2 | | 75.5 | 109.0 | 0.402 | 2.49 | 87.9 | 0.4 | | 72.5 | 101.7 | 0.394 | 2.44 | 88.3 | 0.6 | | 71.4 | 103.2 | 0.360 | 2.23 | 89.2 | 0.8 | | 74.1 | 102.2 | 0.224 | 1.39 | 93.3 |
| 50 | 0 | | 61.3 | 57.8 | 6.458 | 40.03 | — | 0.01 | | 55.9 | 78.2 | 1.417 | 8.80 | 78.0 | 0.025 | | 72.6 | 82.5 | 1.104 | 6.88 | 82.9 | 0.05 | | 70.5 | 95.4 | 0.994 | 6.14 | 84.6 | 0.1 | | 64.9 | 95.4 | 0.900 | 5.58 | 86.1 | 0.2 | | 71.8 | 98.1 | 0.720 | 4.47 | 88.8 | 0.4 | | 77.3 | 97.0 | 0.622 | 3.85 | 90.3 | 0.6 | | 78.0 | 105.8 | 0.567 | 3.52 | 91.2 | 0.8 | | 77.5 | 105.0 | 0.389 | 2.41 | 93.9 |
| 60 | 0 | | 54.3 | 52.5 | 12.43 | 77.0 | — | 0.01 | | 53.4 | 66.9 | 2.650 | 16.4 | 78.6 | 0.025 | | 55.3 | 72.5 | 2.356 | 14.6 | 81.0 | 0.05 | | 59.0 | 83.6 | 1.850 | 11.4 | 85.1 | 0.1 | | 55.9 | 93.8 | 1.693 | 10.4 | 86.4 | 0.2 | | 58.4 | 94.8 | 1.310 | 8.20 | 89.4 | 0.4 | | 53.9 | 92.0 | 1.224 | 7.58 | 90.2 | 0.6 | | 67.9 | 93.7 | 1.081 | 6.74 | 91.3 | 0.8 | | 64.9 | 96.0 | 0.710 | 4.45 | 94.2 |
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