Research Article
Effect of Piperidin-4-ones on the Corrosion Inhibition of Mild Steel in 1 N H2SO4
Table 5
Polarization parameters for mild steel in 1 N H2SO4 in the absence and presence of different concentrations of variously substituted piperidin-4-ones.
| Inhibitor | Concentration (10−3 M) | − (mV vs SCE) | (mA/cm2) | (mV/dec) | (mV/dec) | Corrosion rate (mmpy) | Inhibition efficiency (%) |
| — | Blank | 467 | 12.85 | 171 | 250 | 292.24 | Nil |
| (01) | 0.4 | 454 | 04.37 | 133 | 250 | 099.25 | 66.03 | 1 | 462 | 03.03 | 133 | 225 | 068.82 | 76.44 | 2 | 456 | 02.53 | 116 | 225 | 057.51 | 80.32 |
| (02) | 0.4 | 476 | 06.25 | 170 | 229 | 142.15 | 51.35 | 1 | 471 | 03.83 | 155 | 221 | 087.04 | 70.21 | 2 | 465 | 03.55 | 145 | 229 | 080.67 | 72.39 |
| (03) | 0.4 | 472 | 08.04 | 162 | 266 | 182.70 | 37.47 | 1 | 467 | 06.03 | 145 | 250 | 137.00 | 53.11 | 2 | 479 | 04.33 | 125 | 225 | 098.34 | 66.34 |
| (04) | 0.4 | 445 | 10.09 | 154 | 291 | 229.47 | 21.46 | 1 | 476 | 07.80 | 180 | 266 | 177.31 | 39.31 | 2 | 477 | 05.92 | 145 | 250 | 134.50 | 53.96 |
| (05) | 0.4 | 456 | 08.71 | 133 | 250 | 198.03 | 32.22 | 1 | 458 | 07.05 | 155 | 266 | 160.23 | 45.16 | 2 | 475 | 05.70 | 145 | 208 | 129.58 | 55.65 |
| (06) | 0.4 | 476 | 07.23 | 142 | 250 | 164.34 | 43.75 | 1 | 463 | 05.12 | 142 | 250 | 116.34 | 60.18 | 2 | 469 | 03.87 | 154 | 238 | 088.05 | 69.86 |
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