International Journal of Chemical Engineering

Research Article

Catalyst Initiation in the Oscillatory Carbonylation Reaction

Table 1

Hypothetical reactions.
    Hypothetical reactions     Reaction rateModel
123456789101112
aCO→ [CO]++++++++++++
b→CO ++++++++++++
cPdI2 + CO + H2O → HPdI + HI + CO2 [PdI2][CO]++++++++++
dPdI2 + CO + H2O → IPdCOOH + HI [PdI2][CO]+
eIPdCOOH → HPdI + CO2 [IPdCOOH]+
fHPdI → HI + Pd [HPdI]+++++++++++
gPdI2 + CH3OH + CO → IPdCOOCH3 + HI [PdI2][CO]++++++++++
hIPdCOOCH3 + HI → PdI2 + CH3OH + CO [IPdCOOCH3][HI]++++++++++
iPd + PdI2→ Pd2I2 [Pd][PdI2]++++++++
jPdI2 + CO + H2O → HPdI + HI + CO2 [PdI2][H2O][Pd]+
kPdI2 + CO + H2O → HPdI + HI + CO2 [PdI2][H2O][HI]+
lPdI2 + CO + H2O → HPdI + HI + CO2 [PdI2][H2O][HPdI]+
mPdI2 + CO + H2O → HPdI + HI + CO2 [PdI2][H2O][Pd2I2]+
nHPdI → HI + Pd [HPdI][Pd]+
oHPdI → HI + Pd [HPdI][HI]+
pHPdI → HI + Pd [HPdI]2+
qHPdI → HI + Pd [HPdI][Pd2I2]+