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International Journal of Chemical Engineering
Volume 2015, Article ID 874340, 7 pages
Research Article

Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue

School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China

Received 20 July 2015; Revised 8 September 2015; Accepted 10 September 2015

Academic Editor: Donald L. Feke

Copyright © 2015 Mei-Ling Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The manganese complex of methionine hydroxy analogue was synthesized with methionine hydroxy analogue and manganese chloride as main raw materials. The composition and structure of the complex were characterized by elemental analyses, infrared spectra, and X-ray powder diffraction. The formula of the complex was Mn(C5H9O3S)2. The experimental results indicated that the manganese ion was, respectively, coordinated by the carboxylic and hydroxyl oxygen atoms from the methionine hydroxy analogue ligand. The crystal structure of the complex belonged to monoclinic system with the lattice parameters of = 1.2775 nm, = 1.5764 nm, = 1.5764 nm, and = 94.06°. The thermal decomposition process of the complex was studied by thermogravimetry and differential thermal analysis. The decomposition of the complex has taken place above 200°C. The residue was mainly manganese sulfide, and the experimental and calculated percentage mass loss was also given. The parameters of thermal decomposition kinetics for the complex, such as activation energy, reaction order, and preexponential factor, were calculated by using Kissinger, Flynn-Wall-Ozawa, and Freeman-Carroll methods, and the kinetic equations of the thermal decomposition were obtained.