Review Article

Comparison of Water Defluoridation Using Different Techniques

Table 3

A comparison between the fluoride removal methods.

Process (name of the methods)Type of environmentRemoval performanceAdvantagesDisadvantagesRef.

Adsorption (exhaustive coffee grounds and iron sludge)GroundwaterIron sludge 62.92% and exhausted coffee grounds 56.67%Cheap and easily available adsorbentsLow removal efficiency[11]
Adsorption (porous starch loaded with common metal ions)Drinking waterMaximum adsorption capacity of porous starch with Zr (PS-Zr) of 25.41 mg/gUse of commercial scale-[82]
Adsorption (nepheline from alkali-hydrothermal)Aqueous solutionsMaximum adsorption capacity of 183 mg/gCheap adsorbentsHigh efficiency and adjustment of pH[83]
NF and ROGroundwaterFluoride rejection: 98% for RO and 90% for NFHigh efficiencyMembrane fouling, decreased membrane lifetime and chemical persistence, high capital operation and maintenance costs, and hazardous effluent generation[8, 22]
Ion exchange, membrane filtration, and ECAqueous solutions90%–95%, 99%, and 85.5%High efficiencyCostly techniques, production of waste, and recommended for small community systems[2]
Adsorption (purolite A520E resin)Aqueous environments64.6%Good stability and flexibilityExpensive processes[84]
NFGroundwater98%High efficiencyHigh capital and running and maintenance costs[27]
Adsorption (CuO NPs)Aqueous solutions97%High efficiency[42]
Adsorption (Earth modified alumina)Aqueous solutionsAdsorption capacity of F: 26.45 mg·g−1Easy utilization and high efficiencyLimited yield and long exposure time[46]
Adsorption (fungus hyphae-supported alumina)Aqueous solutionsNearly 90%Economical and effective techniqueLong exposure time[85]
Freezing temperatureWater solutionsDeionized water spiked with fluoride 85% and salinity 75%High efficiency and little contaminationMore susceptible to the freezing temperature[73]
Adsorption (diatomite modified with aluminum hydroxide)Aqueous solution and natural groundwater89%Low-costLeak of soluble alumina[86]
Adsorption (zirconium onto tea powder)Drinking waterAdsorption capacity of 12.43 mg/gEffective, and safe biosorbentA slight functional pH span[87]
Adsorption (activated carbon: banana peel and coffee husk)Aqueous solution80% to 84%Cheap, simple, and environment friendlyLimited efficiency and long exposure time[88]
Adsorption (single-walled carbon nanotubes)Aqueous solution87%–100%Low costGeneration of toxic waste[89]
Adsorption (Mg/Ce/Mn oxide-modified diatomaceous Earth)Aqueous solution>93%Low cost and simple operationHigh yield often demands adjustment of pH[90]
Adsorption (aegle marmelos)Aqueous solution52%Low costLow efficiency[91]
Precipitation/coagulation (lime and alum)Aqueous solution-Simple process and little energy requirementHigh cost of maintenance and production of hazardous waste[1]
MOFsAqueous solutionAdsorption capacity of 41.36 mg/gHigh surface area and high porous[92]

EC: electrocoagulation; NPs: nanoparticles; NF: nanofiltration; MOFs: metal organic frameworks.