Modelling of Jatropha Oil Hydrocracking in a Trickle-Bed Reactor to Produce Green Fuel

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr class="thead"><td class="align_left">Reaction rate</td><td class="align_center">Reaction stoichiometry</td><td class="align_center">Reaction rate coefficient</td><td class="align_center">Reaction rate formula</td></tr><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr><td class="align_left">r1</td><td class="align_center">TG + H2 ⟶ hexane + CO2</td><td class="align_center">k1</td><td class="align_center"><svg height="12.5794pt" id="M69" style="vertical-align:-3.29107pt" version="1.1" viewbox="-0.0498162 -9.28833 32.9152 12.5794" width="32.9152pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M480 416C480 431 465 448 438 448C388 448 312 383 252 330C217 299 188 273 155 237H153L257 680C262 700 263 712 253 712C240 712 183 684 97 674L92 648L126 647C166 646 172 645 163 606L23 -6L29 -12C51 -5 77 2 107 8C115 62 130 128 142 180C153 193 179 220 204 241C231 170 259 106 288 54C317 0 336 -12 358 -12C381 -12 423 2 477 80L460 100C434 74 408 54 398 54C385 54 374 65 351 107C326 154 282 241 263 299C296 332 351 377 403 377C424 377 436 372 445 368C449 366 456 368 462 375C472 386 480 402 480 416Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.474,3.132)"><path d="M389 0V32C297 38 291 46 291 118V635C234 613 175 595 109 583V556L161 554C203 552 207 547 207 497V118C207 46 201 38 110 32V0H389Z"></path></g><g transform="matrix(.013,0,0,-0.013,11.42,0)"><path d="M645 631C614 643 545 666 457 666C215 666 23 519 23 283C23 90 158 -16 337 -16C412 -16 489 2 522 10C543 39 590 127 606 167L580 181C519 89 459 18 348 18C201 18 122 136 122 287C122 464 244 632 435 632C544 632 602 595 608 472L639 475C643 526 645 581 645 631Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,20.04,3.132)"><path d="M655 676H628C608 656 600 650 571 650H156C118 650 114 651 102 676H77C63 615 45 548 24 485L60 486C81 531 97 562 114 580C134 603 148 611 252 611H308L217 127C201 41 196 38 105 32L98 0H384L393 32C300 38 288 41 304 127L393 611H466C553 611 571 604 582 580C592 559 597 530 595 485L630 489C636 548 645 624 655 676Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,25.912,3.132)"><path d="M722 297H451L442 267C561 257 561 253 547 182L531 98C521 44 465 24 390 24C228 24 130 134 130 296C130 482 252 628 465 628C592 628 657 579 656 458L692 461C695 540 699 605 702 631C664 642 590 667 492 667C203 667 24 502 24 285C24 93 170 -17 368 -17C464 -17 543 11 617 28C613 43 612 68 620 106L635 182C649 255 652 258 716 268L722 297Z"></path></g></svg></td></tr><tr><td class="align_left">r2</td><td class="align_center">TG + H2 ⟶ nonane + CO2</td><td class="align_center">k2</td><td class="align_center"><svg height="12.5794pt" id="M70" style="vertical-align:-3.29107pt" version="1.1" viewbox="-0.0498162 -9.28833 32.9152 12.5794" width="32.9152pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M480 416C480 431 465 448 438 448C388 448 312 383 252 330C217 299 188 273 155 237H153L257 680C262 700 263 712 253 712C240 712 183 684 97 674L92 648L126 647C166 646 172 645 163 606L23 -6L29 -12C51 -5 77 2 107 8C115 62 130 128 142 180C153 193 179 220 204 241C231 170 259 106 288 54C317 0 336 -12 358 -12C381 -12 423 2 477 80L460 100C434 74 408 54 398 54C385 54 374 65 351 107C326 154 282 241 263 299C296 332 351 377 403 377C424 377 436 372 445 368C449 366 456 368 462 375C472 386 480 402 480 416Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.474,3.132)"><path d="M414 144C384 79 371 75 317 75H135L276 221C367 316 408 376 408 465C408 570 327 635 237 635C179 635 131 609 100 575L42 494L67 471C94 510 138 565 205 565C277 565 321 517 321 435C321 348 258 270 195 195C146 137 88 81 33 26V0H411C423 44 433 88 446 135L414 144Z"></path></g><g transform="matrix(.013,0,0,-0.013,11.42,0)"><path d="M645 631C614 643 545 666 457 666C215 666 23 519 23 283C23 90 158 -16 337 -16C412 -16 489 2 522 10C543 39 590 127 606 167L580 181C519 89 459 18 348 18C201 18 122 136 122 287C122 464 244 632 435 632C544 632 602 595 608 472L639 475C643 526 645 581 645 631Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,20.04,3.132)"><path d="M655 676H628C608 656 600 650 571 650H156C118 650 114 651 102 676H77C63 615 45 548 24 485L60 486C81 531 97 562 114 580C134 603 148 611 252 611H308L217 127C201 41 196 38 105 32L98 0H384L393 32C300 38 288 41 304 127L393 611H466C553 611 571 604 582 580C592 559 597 530 595 485L630 489C636 548 645 624 655 676Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,25.912,3.132)"><path d="M722 297H451L442 267C561 257 561 253 547 182L531 98C521 44 465 24 390 24C228 24 130 134 130 296C130 482 252 628 465 628C592 628 657 579 656 458L692 461C695 540 699 605 702 631C664 642 590 667 492 667C203 667 24 502 24 285C24 93 170 -17 368 -17C464 -17 543 11 617 28C613 43 612 68 620 106L635 182C649 255 652 258 716 268L722 297Z"></path></g></svg></td></tr><tr><td class="align_left">r3</td><td class="align_center">TG + H2 ⟶ diesel + propane + CO2</td><td class="align_center">k3</td><td class="align_center"><svg height="12.5794pt" id="M71" style="vertical-align:-3.29107pt" version="1.1" viewbox="-0.0498162 -9.28833 32.9152 12.5794" width="32.9152pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M480 416C480 431 465 448 438 448C388 448 312 383 252 330C217 299 188 273 155 237H153L257 680C262 700 263 712 253 712C240 712 183 684 97 674L92 648L126 647C166 646 172 645 163 606L23 -6L29 -12C51 -5 77 2 107 8C115 62 130 128 142 180C153 193 179 220 204 241C231 170 259 106 288 54C317 0 336 -12 358 -12C381 -12 423 2 477 80L460 100C434 74 408 54 398 54C385 54 374 65 351 107C326 154 282 241 263 299C296 332 351 377 403 377C424 377 436 372 445 368C449 366 456 368 462 375C472 386 480 402 480 416Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.474,3.132)"><path d="M290 377C321 398 342 415 358 430C378 450 389 473 389 502C389 578 329 635 238 635H237C184 635 137 610 109 578L64 515L88 493C112 529 154 573 208 573S303 542 303 482C303 409 233 370 141 341L149 308C165 313 190 319 215 319C272 319 341 283 341 193C342 98 292 43 222 43C163 43 122 72 96 94C88 101 79 100 70 94C61 87 47 73 46 60C44 47 48 37 62 23C76 10 118 -12 165 -12C238 -12 430 62 430 223C430 297 379 359 290 375V377Z"></path></g><g transform="matrix(.013,0,0,-0.013,11.42,0)"><path d="M645 631C614 643 545 666 457 666C215 666 23 519 23 283C23 90 158 -16 337 -16C412 -16 489 2 522 10C543 39 590 127 606 167L580 181C519 89 459 18 348 18C201 18 122 136 122 287C122 464 244 632 435 632C544 632 602 595 608 472L639 475C643 526 645 581 645 631Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,20.04,3.132)"><path d="M655 676H628C608 656 600 650 571 650H156C118 650 114 651 102 676H77C63 615 45 548 24 485L60 486C81 531 97 562 114 580C134 603 148 611 252 611H308L217 127C201 41 196 38 105 32L98 0H384L393 32C300 38 288 41 304 127L393 611H466C553 611 571 604 582 580C592 559 597 530 595 485L630 489C636 548 645 624 655 676Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,25.912,3.132)"><path d="M722 297H451L442 267C561 257 561 253 547 182L531 98C521 44 465 24 390 24C228 24 130 134 130 296C130 482 252 628 465 628C592 628 657 579 656 458L692 461C695 540 699 605 702 631C664 642 590 667 492 667C203 667 24 502 24 285C24 93 170 -17 368 -17C464 -17 543 11 617 28C613 43 612 68 620 106L635 182C649 255 652 258 716 268L722 297Z"></path></g></svg></td></tr><tr><td class="align_left">r4</td><td class="align_center">TG + H2 ⟶ wax + CO2</td><td class="align_center">k4</td><td class="align_center"><svg height="12.5794pt" id="M72" style="vertical-align:-3.29107pt" version="1.1" viewbox="-0.0498162 -9.28833 32.9152 12.5794" width="32.9152pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M480 416C480 431 465 448 438 448C388 448 312 383 252 330C217 299 188 273 155 237H153L257 680C262 700 263 712 253 712C240 712 183 684 97 674L92 648L126 647C166 646 172 645 163 606L23 -6L29 -12C51 -5 77 2 107 8C115 62 130 128 142 180C153 193 179 220 204 241C231 170 259 106 288 54C317 0 336 -12 358 -12C381 -12 423 2 477 80L460 100C434 74 408 54 398 54C385 54 374 65 351 107C326 154 282 241 263 299C296 332 351 377 403 377C424 377 436 372 445 368C449 366 456 368 462 375C472 386 480 402 480 416Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,6.474,3.132)"><path d="M462 177V227H365V632H320C217 496 116 350 21 208V177H284V109C284 43 280 38 190 31V0H451V31C369 38 365 43 365 108V177H462ZM284 227H88C155 336 218 430 282 519H284V227Z"></path></g><g transform="matrix(.013,0,0,-0.013,11.42,0)"><path d="M645 631C614 643 545 666 457 666C215 666 23 519 23 283C23 90 158 -16 337 -16C412 -16 489 2 522 10C543 39 590 127 606 167L580 181C519 89 459 18 348 18C201 18 122 136 122 287C122 464 244 632 435 632C544 632 602 595 608 472L639 475C643 526 645 581 645 631Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,20.04,3.132)"><path d="M655 676H628C608 656 600 650 571 650H156C118 650 114 651 102 676H77C63 615 45 548 24 485L60 486C81 531 97 562 114 580C134 603 148 611 252 611H308L217 127C201 41 196 38 105 32L98 0H384L393 32C300 38 288 41 304 127L393 611H466C553 611 571 604 582 580C592 559 597 530 595 485L630 489C636 548 645 624 655 676Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,25.912,3.132)"><path d="M722 297H451L442 267C561 257 561 253 547 182L531 98C521 44 465 24 390 24C228 24 130 134 130 296C130 482 252 628 465 628C592 628 657 579 656 458L692 461C695 540 699 605 702 631C664 642 590 667 492 667C203 667 24 502 24 285C24 93 170 -17 368 -17C464 -17 543 11 617 28C613 43 612 68 620 106L635 182C649 255 652 258 716 268L722 297Z"></path></g></svg></td></tr><tr><td class="align_left">r5</td><td class="align_center">Diesel + H2 ⟶ nonane + octane</td><td class="align_center">k5</td><td class="align_center">k5CC17</td></tr><tr><td class="align_left">r6</td><td class="align_center">Nonane + H2 ⟶ hexane + propane</td><td class="align_center">k6</td><td class="align_center">k6CC9</td></tr><tr><td class="align_left">r7</td><td class="align_center">Diesel + H2 ⟶ hexane + undecane</td><td class="align_center">k7</td><td class="align_center">k7CC17</td></tr><tr class="table-tr"><td colspan="4"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>Hydrocracking reactions and their reaction rate coefficients’ formula.</div>

International Journal of Chemical Engineering

tab2

Table 2

Table 2: Modelling of Jatropha Oil Hydrocracking in a Trickle-Bed Reactor to Produce Green Fuel 