Integrated Study of the Dinitrobenzene Electroreduction Mechanism by Electroanalytical and Computational Methods

Figure 3

Dependence of values of rate constants of protonation of RA and DA by phenol in DMF on the difference of formal potentials of proton donor and substrate reduction. Rate constants data sources: RA naphthalene, phenathrene, chrysene, 1,2-benzanthracene and anthracene [44], RA of nitrobenzene [45], and DA of 1,4-DNB, 1,3-DNB, and 1,2-DNB and RA of 1,2-DNB in this work.