Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction

Figure 3

SWV of reactions (1) and (2). 𝐸⁰₂=𝐸⁰₁, 𝜆₁=10, 𝜆₂=0.01, and 𝐸_st−𝐸⁰₁=0.4 V (a) and −0.4 V (b). All other data are as in Figure 1. Irreversible reduction of the intermediate is marked by 2*.

(a)

(b)