Research Article

A Solid Binding Matrix/Mimic Receptor-Based Sensor System for Trace Level Determination of Iron Using Potential Measurements

Table 3

Analytical features of the present method reported in the literature.

Technique/methodPrinciple of the methodDetection limit (mg/L)Linear Range (mg/L)Repeatability (%)ApplicationSample preparationRef.

UV/VisIron complex with 1-nitroso-2-naphhtol (446 nm)1.7  × 10−3 –0.122.57Industrial waste water(SPE)[2]
Catalytic spectrophotometric flow injection (514 nm)20 × 10−3Up to Real water samplesFiltered water samples were acidified to 0.1 M hydrochloric acid)[3]
Adaptation of the ferrozine method (560 nm)58501755 to 234002In situ analysisNo[7]
Reaction betwen hydroquinone and chromate in acidic media (350 nm)0.05No[8]

ChemiluminescenceNeutralisation reaction0.562.8–560Fresh water samplesReduction of iron(III) with[13]
5.85 × 10−514625 to 87750Fresh water samplesHydroxylammonium chloride[14]

HPLCPhotometric detection (550 nm)0.2  × 10−3 to 10Spiked tap waterNo [55]

Potentiometry/ISEChiral 2,6-bis-(carboxamide methyl ester)pyridine derivative sensor, PVC membrane0.25–56.0Drug formulations [56]
IIP sensor in a PVC selective membrane4.450.0142.4Pharmaceutical formulation samplesNoThis method