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International Journal of Electrochemistry
Volume 2012, Article ID 237689, 12 pages
http://dx.doi.org/10.1155/2012/237689
Review Article

Graphene: A Rising Star on the Horizon of Materials Science

Department of Chemistry, Behala College, University of Calcutta, Kolkata 700060, India

Received 22 June 2012; Accepted 23 August 2012

Academic Editor: Balaprasad Ankamwar

Copyright © 2012 Ujjal Kumar Sur. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, and R. E. Smalley, “C60: Buckminsterfullerene,” Nature, vol. 318, no. 6042, pp. 162–163, 1985. View at Publisher · View at Google Scholar · View at Scopus
  2. S. Iijima, “Helical microtubules of graphitic carbon,” Nature, vol. 354, no. 6348, pp. 56–58, 1991. View at Google Scholar · View at Scopus
  3. K. S. Novoselov, A. K. Geim, S. V. Morozov et al., “Electric field in atomically thin carbon films,” Science, vol. 306, no. 5696, pp. 666–669, 2004. View at Publisher · View at Google Scholar · View at Scopus
  4. A. K. Geim and K. S. Novoselov, “The rise of graphene,” Nature Materials, vol. 6, no. 3, pp. 183–191, 2007. View at Publisher · View at Google Scholar · View at Scopus
  5. C. N. R. Rao, A. K. Sood, K. S. Subrahmanyam, and A. Govindaraj, “Graphene: the new two-dimensional nanomaterial,” Angewandte Chemie, vol. 48, no. 42, pp. 7752–7777, 2009. View at Publisher · View at Google Scholar · View at Scopus
  6. K. S. Novoselov, Z. Jiang, Y. Zhang et al., “Room-temperature quantum hall effect in graphene,” Science, vol. 315, no. 5817, p. 1379, 2007. View at Publisher · View at Google Scholar · View at Scopus
  7. A. K. Geim, “Graphene: status and prospects,” Science, vol. 324, no. 5934, pp. 1530–1534, 2009. View at Publisher · View at Google Scholar · View at Scopus
  8. Y. Wang, Z. Shi, Y. Huang et al., “Supercapacitor devices based on graphene materials,” Journal of Physical Chemistry C, vol. 113, no. 30, pp. 13103–13107, 2009. View at Publisher · View at Google Scholar · View at Scopus
  9. D. V. Kosynkin, A. L. Higginbotham, A. Sinitskii et al., “Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons,” Nature, vol. 458, no. 7240, pp. 872–876, 2009. View at Publisher · View at Google Scholar · View at Scopus
  10. D. B. Shinde, J. Debgupta, A. Kushwaha, M. Aslam, and V. K. Pillai, “Electrochemical unzipping of multi-walled carbon nanotubes for facile synthesis of high-quality graphene nanoribbons,” Journal of the American Chemical Society, vol. 133, no. 12, pp. 4168–4171, 2011. View at Publisher · View at Google Scholar · View at Scopus
  11. X. Li, G. Zhang, X. Bai et al., “Highly conducting graphene sheets and Langmuir-Blodgett films,” Nature Nanotechnology, vol. 3, no. 9, pp. 538–542, 2008. View at Publisher · View at Google Scholar · View at Scopus
  12. V. C. Tung, M. J. Allen, Y. Yang, and R. B. Kaner, “High-throughput solution processing of large-scale graphene,” Nature Nanotechnology, vol. 4, no. 1, pp. 25–29, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. M. Choucair, P. Thordarson, and J. A. Stride, “Gram-scale production of graphene based on solvothermal synthesis and sonication,” Nature Nanotechnology, vol. 4, no. 1, pp. 30–33, 2009. View at Publisher · View at Google Scholar · View at Scopus
  14. X. Yang, X. Dou, A. Rouhanipour, L. Zhi, H. J. Räder, and K. Müllen, “Two-dimensional graphene nanoribbons,” Journal of the American Chemical Society, vol. 130, no. 13, pp. 4216–4217, 2008. View at Publisher · View at Google Scholar · View at Scopus
  15. Y. Hernandez, V. Nicolosi, M. Lotya et al., “High-yield production of graphene by liquid-phase exfoliation of graphite,” Nature Nanotechnology, vol. 3, no. 9, pp. 563–568, 2008. View at Publisher · View at Google Scholar · View at Scopus
  16. A. Reina, X. Jia, J. Ho et al., “Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition,” Nano Letters, vol. 9, no. 1, pp. 30–35, 2009. View at Publisher · View at Google Scholar · View at Scopus
  17. K. V. Emtsev, A. Bostwick, K. Horn et al., “Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide,” Nature Materials, vol. 8, no. 3, pp. 203–207, 2009. View at Publisher · View at Google Scholar · View at Scopus
  18. S. Park and R. S. Ruoff, “Chemical methods for the production of graphenes,” Nature Nanotechnology, vol. 4, no. 4, pp. 217–224, 2009. View at Publisher · View at Google Scholar · View at Scopus
  19. D. Li, M. B. Müller, S. Gilje, R. B. Kaner, and G. G. Wallace, “Processable aqueous dispersions of graphene nanosheets,” Nature Nanotechnology, vol. 3, no. 2, pp. 101–105, 2008. View at Publisher · View at Google Scholar · View at Scopus
  20. S. Stankovich, D. A. Dikin, G. H. B. Dommett et al., “Graphene-based composite materials,” Nature, vol. 442, no. 7100, pp. 282–286, 2006. View at Publisher · View at Google Scholar · View at Scopus
  21. S. Gilje, S. Han, M. Wang, K. L. Wang, and R. B. Kaner, “A chemical route to graphene for device applications,” Nano Letters, vol. 7, no. 11, pp. 3394–3398, 2007. View at Publisher · View at Google Scholar · View at Scopus
  22. S. Stankovich, D. A. Dikin, R. D. Piner et al., “Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide,” Carbon, vol. 45, no. 7, pp. 1558–1565, 2007. View at Publisher · View at Google Scholar · View at Scopus
  23. Y. Si and E. T. Samulski, “Synthesis of water soluble graphene,” Nano Letters, vol. 8, no. 6, pp. 1679–1682, 2008. View at Publisher · View at Google Scholar · View at Scopus
  24. W. Chen, L. Yan, and P. R. Bangal, “Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves,” Carbon, vol. 48, no. 4, pp. 1146–1152, 2010. View at Publisher · View at Google Scholar · View at Scopus
  25. D. A. Sokolov, K. R. Shepperd, and T. M. Orlando, “Formation of graphene features from direct laser-induced reduction of graphite oxide,” Journal of Physical Chemistry Letters, vol. 1, no. 18, pp. 2633–2636, 2010. View at Publisher · View at Google Scholar · View at Scopus
  26. M. Baraket, S. G. Walton, Z. Wei, E. H. Lock, J. T. Robinson, and P. Sheehan, “Reduction of graphene oxide by electron beam generated plasmas produced in methane/argon mixtures,” Carbon, vol. 48, no. 12, pp. 3382–3390, 2010. View at Publisher · View at Google Scholar · View at Scopus
  27. K. Vinodgopal, B. Neppolian, I. V. Lightcap, F. Grieser, M. Ashokkumar, and P. V. Kamat, “Sonolytic design of graphene-Au nanocomposites. simultaneous and sequential reduction of graphene oxide and Au(III),” Journal of Physical Chemistry Letters, vol. 1, no. 13, pp. 1987–1993, 2010. View at Publisher · View at Google Scholar · View at Scopus
  28. Y. Zhou, Q. Bao, L. A. L. Tang, Y. Zhong, and K. P. Loh, “Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties,” Chemistry of Materials, vol. 21, no. 13, pp. 2950–2956, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. W. Li, M. Zhao, X. Zhao, Y. Xia, and Y. Mu, “Hydrogen saturation stabilizes vacancy-induced ferromagnetic ordering in graphene,” Physical Chemistry Chemical Physics, vol. 12, no. 41, pp. 13699–13706, 2010. View at Publisher · View at Google Scholar · View at Scopus
  30. Z. Wang, X. Zhou, J. Zhang, F. Boey, and H. Zhang, “Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase,” Journal of Physical Chemistry C, vol. 113, no. 32, pp. 14071–14075, 2009. View at Publisher · View at Google Scholar · View at Scopus
  31. G. Wang, B. Wang, J. Park, Y. Wang, B. Sun, and J. Yao, “Highly efficient and large-scale synthesis of graphene by electrolytic exfoliation,” Carbon, vol. 47, no. 14, pp. 3242–3246, 2009. View at Publisher · View at Google Scholar · View at Scopus
  32. S. Liu, J. Ou, J. Wang, X. Liu, and S. Yang, “A simple two-step electrochemical synthesis of graphene sheets film on the ITO electrode as supercapacitors,” Journal of Applied Electrochemistry, pp. 1–4, 2011. View at Publisher · View at Google Scholar · View at Scopus
  33. N. Liu, F. Luo, H. Wu, Y. Liu, C. Zhang, and J. Chen, “One-step ionic-liquid-assisted electrochemical synthesis of ionic-liquid-functionalized graphene sheets directly from graphite,” Advanced Functional Materials, vol. 18, no. 10, pp. 1518–1525, 2008. View at Publisher · View at Google Scholar · View at Scopus
  34. G. Ruan, Z. Sun, Z. Peng, and J. M. Tour, “Growth of graphene from food, insects, and waste,” ACS Nano, vol. 5, no. 9, pp. 7601–7607, 2011. View at Publisher · View at Google Scholar · View at Scopus
  35. P. R. Wallace, “The band theory of graphite,” Physical Review, vol. 71, pp. 622–634, 1947. View at Google Scholar
  36. R. E. Peierls, “Quelques proprietes typiques des corpses solides,” Annales de l'Institut Henri Poincaré, vol. 5, pp. 177–222, 1935. View at Google Scholar
  37. L. D. Landau, “Zur Theorie der phasenumwandlungen II,” Physikalische Zeitschrift der Sowjetunion, vol. 11, pp. 26–35, 1937. View at Google Scholar
  38. J. W. Evans, P. A. Thiel, and M. C. Bartelt, “Morphological evolution during epitaxial thin film growth: formation of 2D islands and 3D mounds,” Surface Science Reports, vol. 61, no. 1-2, pp. 1–128, 2006. View at Publisher · View at Google Scholar · View at Scopus
  39. K. S. Novoselov, D. Jiang, F. Schedin et al., “Two-dimensional atomic crystals,” Proceedings of the National Academy of Sciences of the United States of America, vol. 102, no. 30, pp. 10451–10453, 2005. View at Publisher · View at Google Scholar · View at Scopus
  40. K. A. Ritter and J. W. Lyding, “Characterization of nanometer-sized, mechanically exfoliated graphene on the H-passivated Si(100) surface using scanning tunneling microscopy,” Nanotechnology, vol. 19, no. 1, Article ID 015704, 2008. View at Publisher · View at Google Scholar · View at Scopus
  41. P. W. Sutter, J. I. Flege, and E. A. Sutter, “Epitaxial graphene on ruthenium,” Nature Materials, vol. 7, no. 5, pp. 406–411, 2008. View at Publisher · View at Google Scholar · View at Scopus
  42. K. S. Kim, Y. Zhao, H. Jang et al., “Large-scale pattern growth of graphene films for stretchable transparent electrodes,” Nature, vol. 457, no. 7230, pp. 706–710, 2009. View at Publisher · View at Google Scholar · View at Scopus
  43. J. Wang, M. Zhu, R. A. Outlaw, X. Zhao, D. M. Manos, and B. C. Holloway, “Synthesis of carbon nanosheets by inductively coupled radio-frequency plasma enhanced chemical vapor deposition,” Carbon, vol. 42, no. 14, pp. 2867–2872, 2004. View at Publisher · View at Google Scholar · View at Scopus
  44. W. S. Hummers and R. E. Offeman, “Preparation of graphitic oxide,” Journal of the American Chemical Society, vol. 80, no. 6, p. 1339, 1958. View at Google Scholar · View at Scopus
  45. N. I. Kovtyukhova, “Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations,” Chemistry of Materials, vol. 11, no. 3, pp. 771–778, 1999. View at Google Scholar · View at Scopus
  46. G. Wang, J. Yang, J. Park et al., “Facile synthesis and characterization of graphene nanosheets,” Journal of Physical Chemistry C, vol. 112, no. 22, pp. 8192–8195, 2008. View at Publisher · View at Google Scholar · View at Scopus
  47. C. N. R. Rao, K. Biswas, K. S. Subrahmanyam, and A. Govindaraj, “Graphene, the new nanocarbon,” Journal of Materials Chemistry, vol. 19, no. 17, pp. 2457–2469, 2009. View at Publisher · View at Google Scholar · View at Scopus
  48. J. Zhang, H. Yang, G. Shen, P. Cheng, J. Zhang, and S. Guo, “Reduction of graphene oxide vial-ascorbic acid,” Chemical Communications, vol. 46, no. 7, pp. 1112–1114, 2010. View at Publisher · View at Google Scholar · View at Scopus
  49. C. Zhu, S. Guo, Y. Fang, and S. Dong, “Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets,” ACS Nano, vol. 4, no. 4, pp. 2429–2437, 2010. View at Publisher · View at Google Scholar · View at Scopus
  50. E. C. Salas, Z. Sun, A. Lüttge, and J. M. Tour, “Reduction of graphene oxide via bacterial respiration,” ACS Nano, vol. 4, no. 8, pp. 4852–4856, 2010. View at Publisher · View at Google Scholar · View at Scopus
  51. O. E. Andersson, B. L. V. Prasad, H. Sato et al., “Structure and electronic properties of graphite nanoparticles,” Physical Review B, vol. 58, no. 24, pp. 16387–16395, 1998. View at Google Scholar · View at Scopus
  52. B. L. V. Prasad, H. Sato, T. Enoki et al., “Heat-treatment effect on the nanosized graphite π-electron system during diamond to graphite conversion,” Physical Review B, vol. 62, no. 16, pp. 11209–11218, 2000. View at Publisher · View at Google Scholar · View at Scopus
  53. K. S. Subrahmanyam, L. S. Panchakarla, A. Govindaraj, and C. N. R. Rao, “Simple method of preparing graphene flakes by an arc-discharge method,” Journal of Physical Chemistry C, vol. 113, no. 11, pp. 4257–4259, 2009. View at Publisher · View at Google Scholar · View at Scopus
  54. W. Gao, L. B. Alemany, L. Ci, and P. M. Ajayan, “New insights into the structure and reduction of graphite oxide,” Nature Chemistry, vol. 1, no. 5, pp. 403–408, 2009. View at Publisher · View at Google Scholar · View at Scopus
  55. P. K. Ang, S. Wang, Q. Bao, J. T. L. Thong, and K. P. Loh, “High-throughput synthesis of graphene by intercalation-exfoliation of graphite oxide and study of ionic screening in graphene transistor,” ACS Nano, vol. 3, no. 11, pp. 3587–3594, 2009. View at Publisher · View at Google Scholar · View at Scopus
  56. M. Lotya, Y. Hernandez, P. J. King et al., “Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions,” Journal of the American Chemical Society, vol. 131, no. 10, pp. 3611–3620, 2009. View at Publisher · View at Google Scholar · View at Scopus
  57. C. N. R. Rao, K. S. Subrahmanyam, H. S. S. Ramakrishna Matte, and A. Govindaraj, “Graphene: synthesis, functionalization and properties,” Modern Physics Letters B, vol. 25, no. 7, pp. 427–451, 2011. View at Publisher · View at Google Scholar · View at Scopus
  58. S. Niyogi, E. Bekyarova, M. E. Itkis, J. L. McWilliams, M. A. Hamon, and R. C. Haddon, “Solution properties of graphite and graphene,” Journal of the American Chemical Society, vol. 128, no. 24, pp. 7720–7721, 2006. View at Publisher · View at Google Scholar · View at Scopus
  59. K. A. Worsley, P. Ramesh, S. K. Mandal, S. Niyogi, M. E. Itkis, and R. C. Haddon, “Soluble graphene derived from graphite fluoride,” Chemical Physics Letters, vol. 445, no. 1–3, pp. 51–56, 2007. View at Publisher · View at Google Scholar · View at Scopus
  60. A. Ghosh, K. V. Rao, S. J. George, and C. N. R. Rao, “Noncovalent functionalization, exfoliation, and solubilization of graphene in water by employing a fluorescent coronene carboxylate,” Chemistry, vol. 16, no. 9, pp. 2700–2704, 2010. View at Publisher · View at Google Scholar · View at Scopus
  61. K. S. Subrahmanyam, S. R. C. Vivekchand, A. Govindaraj, and C. N. R. Rao, “A study of graphenes prepared by different methods: characterization, properties and solubilization,” Journal of Materials Chemistry, vol. 18, no. 13, pp. 1517–1523, 2008. View at Publisher · View at Google Scholar · View at Scopus
  62. C. Chen, Q. H. Yang, Y. Yang et al., “Self-assembled free-standing graphite oxide membrane,” Advanced Materials, vol. 21, no. 29, pp. 3007–3011, 2009. View at Publisher · View at Google Scholar · View at Scopus
  63. Y. K. Kim and D. H. Min, “Durable large-area thin films of graphene/carbon nanotube double layers as a transparent electrode,” Langmuir, vol. 25, no. 19, pp. 11302–11306, 2009. View at Publisher · View at Google Scholar · View at Scopus
  64. G. K. Ramesha and N. S. Sampath, “Electrochemical reduction of oriented Graphene oxide films: an in situ Raman spectroelectrochemical study,” Journal of Physical Chemistry C, vol. 113, no. 19, pp. 7985–7989, 2009. View at Publisher · View at Google Scholar · View at Scopus
  65. Y. Xu, K. Sheng, C. Li, and G. Shi, “Self-assembled graphene hydrogel via a one-step hydrothermal process,” ACS Nano, vol. 4, no. 7, pp. 4324–4330, 2010. View at Publisher · View at Google Scholar · View at Scopus
  66. A. Ghosh, K. S. Subrahmanyam, K. S. Krishna et al., “Uptake of H2 and CO2 by graphene,” Journal of Physical Chemistry C, vol. 112, no. 40, pp. 15704–15707, 2008. View at Publisher · View at Google Scholar · View at Scopus
  67. G. Gundiah, A. Govindaraj, N. Rajalakshmi, K. S. Dhathathreyan, and C. N. R. Rao, “Hydrogen storage in carbon nanotubes and related materials,” Journal of Materials Chemistry, vol. 13, no. 2, pp. 209–213, 2003. View at Publisher · View at Google Scholar · View at Scopus
  68. D. J. Collins and H. C. Zhou, “Hydrogen storage in metal-organic frameworks,” Journal of Materials Chemistry, vol. 17, no. 30, pp. 3154–3160, 2007. View at Publisher · View at Google Scholar · View at Scopus
  69. Y. Xu, L. Zhao, H. Bai, W. Hong, C. Li, and G. Shi, “Chemically converted graphene induced molecular flattening of 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin and its application for optical detection of cadmium(II) ions,” Journal of the American Chemical Society, vol. 131, no. 37, pp. 13490–13497, 2009. View at Publisher · View at Google Scholar · View at Scopus
  70. H. S. S. Ramakrishna Matte, K. S. Subrahmanyam, K. Venkata Rao, S. J. George, and C. N. R. Rao, “Quenching of fluorescence of aromatic molecules by graphene due to electron transfer,” Chemical Physics Letters, vol. 506, no. 4–6, pp. 260–264, 2011. View at Publisher · View at Google Scholar · View at Scopus
  71. M. Fleischmann, P. J. Hendra, and A. J. McQuillan, “Raman spectra of pyridine adsorbed at a silver electrode,” Chemical Physics Letters, vol. 26, no. 2, pp. 163–166, 1974. View at Google Scholar · View at Scopus
  72. X. Ling, L. Xie, Y. Fang et al., “Can graphene be used as a substrate for Raman enhancement?” Nano Letters, vol. 10, no. 2, pp. 553–561, 2010. View at Publisher · View at Google Scholar · View at Scopus
  73. A. K. Manna and S. K. Pati, “Tuning the electronic structure of graphene by molecular charge transfer: a computational study,” Chemistry, vol. 4, no. 6, pp. 855–860, 2009. View at Publisher · View at Google Scholar · View at Scopus
  74. J. Xia, F. Chen, J. Li, and N. Tao, “Measurement of the quantum capacitance of graphene,” Nature Nanotechnology, vol. 4, no. 8, pp. 505–509, 2009. View at Publisher · View at Google Scholar · View at Scopus
  75. M. Maidhily, N. Rajalakshmi, and K. S. Dhathathreyan, “Electrochemical impedance diagnosis of micro porous layer in polymer electrolyte membrane fuel cell electrodes,” International Journal of Hydrogen Energy, vol. 36, no. 19, pp. 12352–12360, 2011. View at Publisher · View at Google Scholar · View at Scopus
  76. K. S. Subrahmanyam, P. Kumar, U. Maitra et al., “Chemical storage of hydrogen in few-layer graphene,” Proceedings of the National Academy of Sciences of the United States of America, vol. 108, no. 7, pp. 2674–2677, 2011. View at Publisher · View at Google Scholar · View at Scopus
  77. S. Park, J. An, J. W. Suk, and R. S. Ruoff, “Graphene-based actuators,” Small, vol. 6, no. 2, pp. 210–212, 2010. View at Publisher · View at Google Scholar · View at Scopus
  78. X. Xie, L. Qu, C. Zhou et al., “An asymmetrically surface-modified graphene film electrochemical actuator,” ACS Nano, vol. 4, no. 10, pp. 6050–6054, 2010. View at Publisher · View at Google Scholar · View at Scopus
  79. C. Wu, J. Feng, L. Peng et al., “Large-area graphene realizing ultrasensitive photothermal actuator with high transparency: new prototype robotic motions under infrared-light stimuli,” Journal of Materials Chemistry, vol. 21, no. 46, pp. 18584–18591, 2011. View at Publisher · View at Google Scholar · View at Scopus
  80. S. Talapatra, S. Kar, S. K. Pal et al., “Direct growth of aligned carbon nanotubes on bulk metals,” Nature Nanotechnology, vol. 1, no. 2, pp. 112–116, 2006. View at Publisher · View at Google Scholar · View at Scopus
  81. S. R. C. Vivekchand, C. S. Rout, K. S. Subrahmanyam, A. Govindaraj, and C. N. R. Rao, “Graphene-based electrochemical supercapacitors,” Journal of Chemical Sciences, vol. 120, no. 1, pp. 9–13, 2008. View at Publisher · View at Google Scholar · View at Scopus
  82. M. D. Stoller, S. Park, Z. Yanwu, J. An, and R. S. Ruoff, “Graphene-Based ultracapacitors,” Nano Letters, vol. 8, no. 10, pp. 3498–3502, 2008. View at Publisher · View at Google Scholar · View at Scopus
  83. D. W. Wang, F. Li, J. Zhao et al., “Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode,” ACS Nano, vol. 3, no. 7, pp. 1745–1752, 2009. View at Publisher · View at Google Scholar · View at Scopus
  84. M. J. Allen, V. C. Tung, and R. B. Kaner, “Honeycomb carbon: a review of graphene,” Chemical Reviews, vol. 110, no. 1, pp. 132–145, 2010. View at Publisher · View at Google Scholar · View at Scopus