International Journal of Electrochemistry / 2013 / Article / Fig 13

Research Article

Buoyancy Effect of Ionic Vacancy on the Change of the Partial Molar Volume in Ferricyanide-Ferrocyanide Redox Reaction under a Vertical Gravity Field

Figure 13

Plot of the effective partial molar volume of ionic vacancy in the oxidation of FERRO ion against the molality of FERRO ion. ∘, the measured values; broken line, the average value. The measured effective partial molar volume, m3 mol−1; the expected partial molar volume of ionic vacancy with −1 unit charge, m3 mol−1.