International Journal of Electrochemistry / 2013 / Article / Fig 3

Research Article

Buoyancy Effect of Ionic Vacancy on the Change of the Partial Molar Volume in Ferricyanide-Ferrocyanide Redox Reaction under a Vertical Gravity Field

Figure 3

Comparison of experimental data on the radius of ionic vacancy with theoretical calculations in copper electrodeposition [5, 6]. •, CuSO4 100 mol m−3 H2SO4 solution; ∘, CuCl2+ 100 mol m−3 KCl solution; , the charge number of ionic vacancy; broken line, the theoretical value of the radius; R*, the radius of ionic vacancy; , the molality of the cupric salt.