Research Article
Oxygen-Containing Nanoclusters on the Surface of Pt-Electrodes and Oxygen Reduction Reaction in Alkaline Medium
Table 4
Parameter
for oxygen-containing structures on the surface of Pt-electrodes in nitrogen atmosphere.
| Structure | , kJ⋅mol−1 | Pt(111) () | Pt(100) () | Pt(110) () | Pt smooth | | | | | | | | |
| calculation according to reaction (7) | −162 | −162 | −179 | −179 | −208 | −194 | −169 | (−178) | Calculation according to reaction (8) | −298 | −303 | −320 | −324 | −373 | −300 | −300 | (−309) |
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value of parameters on Pt(hkl) monocrystals. |