Research Article

Oxygen-Containing Nanoclusters on the Surface of Pt-Electrodes and Oxygen Reduction Reaction in Alkaline Medium

Table 4

Parameter for oxygen-containing structures on the surface of Pt-electrodes in nitrogen atmosphere.

Structure, kJ⋅mol−1
Pt(111) 
()
Pt(100) 
()
Pt(110) 
()
Pt smooth

calculation according to reaction (7)−162−162−179−179−208−194−169(−178)
Calculation according to reaction (8)−298−303−320−324−373−300−300(−309)

value of parameters on Pt(hkl) monocrystals.