Exchange Interaction in Complex Bis[(1,3-Dithiole-2-Thione-4,5-Dithiolato)-di-(Carbonyl)-Cyclopentadienyl Iron(II)]

Table 1

Basic parameters of the Mössbauer spectra of complex (𝐈). Symbols: 𝛿-value of isomer shift; ▵-value of quadrupole splitting; Γ_1/2-halfwidth of the line; S-relative probability of the effect.

𝑇, K	Center	𝛿 mm/s	▵ mm/s	Γ1/2 mm/s	𝑆 %
300	Fe	0.39(1)	1.09(1)	0.26(1)	48.8(1)
	Fe^∗	0.40(1)	0.64(1)	0.41(1)	51.2(1)
77	Fe	0.46(1)	1.11(1)	0.31(1)	50.8(1)
	Fe^∗	0.50(1)	0.69(1)	0.41(1)	49.2(1)